MassBank Record: SM873501



 Triamcinolone; LC-ESI-QFT; MS2; CE: 35 NCE; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure


ACCESSION: SM873501
RECORD_TITLE: Triamcinolone; LC-ESI-QFT; MS2; CE: 35 NCE; R=35000; [M+H]+
DATE: 2016.12.12
AUTHORS: Krauss M, Schymanski EL, Weidauer C, Schupke H, UFZ and Eawag
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2016 UFZ/Eawag
PUBLICATION: Schymanski, EL et al. Critical Assessment of Small Molecule Identification 2016 - Automated Methods. Submitted.
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 8735

CH$NAME: Triamcinolone CH$NAME: 9-Fluoro-11,16,17,21-tetrahydroxypregna-1,4-diene-3,20-dione CH$NAME: 9-fluoro-11,16,17-trihydroxy-17-(2-hydroxyacetyl)-10,13-dimethyl-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-3-one CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C21H27FO6 CH$EXACT_MASS: 394.17917 CH$SMILES: CC12CC(O)C3(F)C(CCC4=CC(=O)C=CC34C)C1CC(O)C2(O)C(=O)CO CH$IUPAC: InChI=1S/C21H27FO6/c1-18-6-5-12(24)7-11(18)3-4-13-14-8-15(25)21(28,17(27)10-23)19(14,2)9-16(26)20(13,18)22/h5-7,13-16,23,25-26,28H,3-4,8-10H2,1-2H3 CH$LINK: CAS 124-94-7 CH$LINK: PUBCHEM CID:5544 CH$LINK: INCHIKEY GFNANZIMVAIWHM-UHFFFAOYSA-N CH$LINK: CHEMSPIDER 5343
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 35 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME Kinetex C18 EVO 2.6 um, 2.1x50 mm, precolumn 2.1x5 mm, Phenomenex AC$CHROMATOGRAPHY: FLOW_GRADIENT 95/5 at 0 min, 95/5 at 1 min, 0/100 at 13 min, 0/100 at 24 min AC$CHROMATOGRAPHY: FLOW_RATE 300 uL/min AC$CHROMATOGRAPHY: RETENTION_TIME 8.040 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 395.1863 MS$FOCUSED_ION: PRECURSOR_M/Z 395.1864 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 2.3.1
PK$SPLASH: splash10-05dj-1796000000-9f348b03b37624d18d74 PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 53.0388 C4H5+ 1 53.0386 4.13 55.0181 C3H3O+ 1 55.0178 4.11 55.0544 C4H7+ 1 55.0542 3.05 57.0336 C3H5O+ 1 57.0335 1.56 59.0493 C3H7O+ 1 59.0491 1.99 67.0543 C5H7+ 1 67.0542 1.18 69.0336 C4H5O+ 1 69.0335 0.96 69.07 C5H9+ 1 69.0699 1.17 71.0492 C4H7O+ 1 71.0491 0.55 73.0284 C3H5O2+ 1 73.0284 -0.22 77.0386 C6H5+ 1 77.0386 0.72 79.0542 C6H7+ 1 79.0542 0.05 81.0334 C5H5O+ 1 81.0335 -1.22 81.0699 C6H9+ 1 81.0699 0.09 83.0491 C5H7O+ 1 83.0491 -0.85 85.0649 C5H9O+ 1 85.0648 1.48 87.044 C4H7O2+ 1 87.0441 -0.2 91.0542 C7H7+ 1 91.0542 -0.09 93.0699 C7H9+ 1 93.0699 -0.2 95.0491 C6H7O+ 1 95.0491 -0.21 95.0855 C7H11+ 1 95.0855 -0.29 97.0285 C5H5O2+ 1 97.0284 0.97 97.0648 C6H9O+ 1 97.0648 0.5 99.0439 C5H7O2+ 1 99.0441 -1.28 103.0543 C8H7+ 1 103.0542 1.09 105.0699 C8H9+ 1 105.0699 0.12 107.0492 C7H7O+ 1 107.0491 0.63 107.0855 C8H11+ 1 107.0855 0.13 109.0648 C7H9O+ 1 109.0648 0.07 111.0439 C6H7O2+ 1 111.0441 -1.01 111.0804 C7H11O+ 1 111.0804 0.02 113.0597 C6H9O2+ 1 113.0597 -0.37 115.039 C5H7O3+ 1 115.039 0.31 115.0542 C9H7+ 1 115.0542 0.01 117.0545 C5H9O3+ 1 117.0546 -0.72 117.0699 C9H9+ 1 117.0699 0.6 119.049 C8H7O+ 1 119.0491 -1.12 119.0855 C9H11+ 1 119.0855 -0.36 121.0648 C8H9O+ 1 121.0648 -0.21 123.0443 C7H7O2+ 1 123.0441 1.68 123.0804 C8H11O+ 1 123.0804 -0.06 125.0597 C7H9O2+ 1 125.0597 -0.23 127.0389 C6H7O3+ 1 127.039 -0.51 127.0753 C7H11O2+ 1 127.0754 -0.58 128.0619 C10H8+ 1 128.0621 -1.02 129.0699 C10H9+ 1 129.0699 0.4 131.0855 C10H11+ 1 131.0855 0.13 132.0569 C9H8O+ 1 132.057 -0.51 133.0648 C9H9O+ 1 133.0648 0.28 133.1011 C10H13+ 1 133.1012 -0.58 135.0804 C9H11O+ 1 135.0804 -0.31 137.0597 C8H9O2+ 1 137.0597 -0.19 139.0753 C8H11O2+ 1 139.0754 -0.69 141.0547 C7H9O3+ 1 141.0546 0.8 141.0697 C11H9+ 1 141.0699 -1.13 142.0777 C11H10+ 1 142.0777 0.01 143.0855 C11H11+ 1 143.0855 -0.37 144.0569 C10H8O+ 1 144.057 -0.68 145.0647 C10H9O+ 1 145.0648 -0.41 145.1008 C11H13+ 1 145.1012 -2.78 146.0726 C10H10O+ 1 146.0726 -0.35 147.0804 C10H11O+ 1 147.0804 -0.42 149.0598 C9H9O2+ 1 149.0597 0.85 151.0389 C8H7O3+ 1 151.039 -0.15 151.0753 C9H11O2+ 1 151.0754 -0.1 153.0548 C8H9O3+ 1 153.0546 1.21 153.0699 C12H9+ 1 153.0699 0.03 153.091 C9H13O2+ 1 153.091 0.06 155.0605 C10H7N2+ 1 155.0604 0.51 155.0701 C8H11O3+ 1 155.0703 -1.32 155.0854 C12H11+ 1 155.0855 -0.71 156.0932 C12H12+ 1 156.0934 -0.88 157.0648 C11H9O+ 1 157.0648 0.08 157.1011 C12H13+ 1 157.1012 -0.65 158.0726 C11H10O+ 1 158.0726 -0.19 159.0804 C11H11O+ 1 159.0804 -0.26 160.0883 C11H12O+ 1 160.0883 0.14 161.0597 C10H9O2+ 1 161.0597 -0.25 161.0961 C11H13O+ 1 161.0961 -0.21 163.0754 C10H11O2+ 1 163.0754 0.45 165.0546 C9H9O3+ 1 165.0546 -0.2 165.07 C13H9+ 1 165.0699 0.74 165.0912 C10H13O2+ 1 165.091 1.23 166.0778 C13H10+ 1 166.0777 0.85 167.0703 C9H11O3+ 1 167.0703 -0.06 167.0855 C13H11+ 1 167.0855 0.14 168.0929 C13H12+ 1 168.0934 -2.75 169.0648 C12H9O+ 1 169.0648 -0.13 169.1011 C13H13+ 1 169.1012 -0.54 170.0724 C12H10O+ 1 170.0726 -1.18 171.0804 C12H11O+ 1 171.0804 -0.35 171.1168 C13H15+ 1 171.1168 -0.04 172.0883 C12H12O+ 1 172.0883 0.12 173.0807 C8H13O4+ 1 173.0808 -0.58 173.0961 C12H13O+ 1 173.0961 0.05 175.0754 C11H11O2+ 1 175.0754 0.14 177.0912 C11H13O2+ 1 177.091 1.21 178.0777 C14H10+ 1 178.0777 -0.26 179.0703 C10H11O3+ 1 179.0703 0.26 179.0856 C14H11+ 1 179.0855 0.19 180.0933 C14H12+ 1 180.0934 -0.38 181.0646 C13H9O+ 1 181.0648 -1.07 181.101 C14H13+ 1 181.1012 -1.03 182.0726 C13H10O+ 1 182.0726 -0.21 182.1091 C14H14+ 1 182.109 0.42 183.0805 C13H11O+ 1 183.0804 0.23 183.1168 C14H15+ 1 183.1168 -0.32 184.0884 C13H12O+ 1 184.0883 0.91 185.0961 C13H13O+ 1 185.0961 0.1 187.0754 C12H11O2+ 1 187.0754 0.02 187.1116 C13H15O+ 1 187.1117 -0.92 189.0707 C12H10FO+ 2 189.071 -1.81 189.0909 C12H13O2+ 1 189.091 -0.42 190.0778 C15H10+ 1 190.0777 0.54 191.0857 C15H11+ 1 191.0855 0.88 192.0932 C15H12+ 1 192.0934 -1.01 193.0862 C11H13O3+ 2 193.0859 1.53 193.1011 C15H13+ 1 193.1012 -0.27 194.0727 C14H10O+ 1 194.0726 0.42 194.1094 C15H14+ 2 194.109 2.26 195.0805 C14H11O+ 1 195.0804 0.52 195.1169 C15H15+ 1 195.1168 0.39 196.0882 C14H12O+ 1 196.0883 -0.4 197.0809 C10H13O4+ 1 197.0808 0.23 197.0961 C14H13O+ 1 197.0961 -0.14 197.1322 C15H17+ 1 197.1325 -1.58 198.1039 C14H14O+ 1 198.1039 0.11 199.0752 C13H11O2+ 1 199.0754 -0.9 199.1118 C14H15O+ 1 199.1117 0.05 201.091 C13H13O2+ 1 201.091 0.14 202.0773 C16H10+ 1 202.0777 -1.9 203.0855 C16H11+ 1 203.0855 -0.06 203.1069 C13H15O2+ 2 203.1067 1.38 204.0933 C16H12+ 1 204.0934 -0.04 205.1012 C16H13+ 1 205.1012 -0.01 206.0729 C15H10O+ 2 206.0726 1.16 206.1089 C16H14+ 1 206.109 -0.51 207.0803 C15H11O+ 1 207.0804 -0.44 207.1168 C16H15+ 1 207.1168 0.03 208.0882 C15H12O+ 1 208.0883 -0.49 209.0961 C15H13O+ 1 209.0961 -0.03 209.1324 C16H17+ 1 209.1325 -0.36 210.1039 C15H14O+ 1 210.1039 -0.08 211.1117 C15H15O+ 1 211.1117 -0.05 212.1194 C15H16O+ 1 212.1196 -0.67 213.0911 C14H13O2+ 2 213.091 0.47 213.1273 C15H17O+ 1 213.1274 -0.29 215.0857 C17H11+ 2 215.0855 0.71 215.1067 C14H15O2+ 1 215.1067 0.16 215.1433 C15H19O+ 2 215.143 1.32 216.0938 C17H12+ 2 216.0934 2.07 217.1011 C17H13+ 1 217.1012 -0.45 218.0726 C16H10O+ 1 218.0726 -0.17 218.109 C17H14+ 1 218.109 -0.07 219.0803 C16H11O+ 1 219.0804 -0.63 219.117 C17H15+ 2 219.1168 0.65 220.0879 C16H12O+ 1 220.0883 -1.65 221.0961 C16H13O+ 1 221.0961 -0.03 221.1324 C17H17+ 1 221.1325 -0.2 222.1039 C16H14O+ 1 222.1039 0 223.1117 C16H15O+ 1 223.1117 -0.18 224.1196 C16H16O+ 1 224.1196 0.05 225.1273 C16H17O+ 1 225.1274 -0.27 226.0984 C15H14O2+ 1 226.0988 -1.89 226.1347 C16H18O+ 1 226.1352 -2.2 227.0855 C18H11+ 1 227.0855 -0.2 227.1065 C15H15O2+ 1 227.1067 -0.79 227.1431 C16H19O+ 2 227.143 0.25 228.093 C18H12+ 1 228.0934 -1.44 229.1009 C18H13+ 1 229.1012 -1.08 230.1096 C18H14+ 2 230.109 2.4 231.0805 C17H11O+ 2 231.0804 0.2 231.1168 C18H15+ 1 231.1168 -0.16 232.088 C17H12O+ 1 232.0883 -1.35 232.1245 C18H16+ 1 232.1247 -0.73 233.096 C17H13O+ 1 233.0961 -0.21 233.1322 C18H17+ 1 233.1325 -1.23 234.1038 C17H14O+ 1 234.1039 -0.38 235.1117 C17H15O+ 1 235.1117 -0.16 236.1194 C17H16O+ 1 236.1196 -0.91 237.091 C16H13O2+ 1 237.091 -0.2 237.1274 C17H17O+ 2 237.1274 -0.11 238.0987 C16H14O2+ 1 238.0988 -0.37 239.1067 C16H15O2+ 2 239.1067 0.17 239.143 C17H19O+ 2 239.143 -0.06 241.1016 C19H13+ 2 241.1012 1.59 241.1223 C16H17O2+ 2 241.1223 0.15 241.1583 C17H21O+ 1 241.1587 -1.53 242.1089 C19H14+ 1 242.109 -0.41 243.1037 C12H16FO4+ 1 243.1027 4.13 243.1167 C19H15+ 1 243.1168 -0.32 243.1378 C16H19O2+ 1 243.138 -0.49 245.0962 C18H13O+ 2 245.0961 0.57 245.1324 C19H17+ 1 245.1325 -0.46 246.104 C18H14O+ 2 246.1039 0.22 247.112 C18H15O+ 2 247.1117 1.11 247.1485 C19H19+ 2 247.1481 1.32 248.1196 C18H16O+ 2 248.1196 0.02 249.1273 C18H17O+ 2 249.1274 -0.2 250.1353 C18H18O+ 2 250.1352 0.37 251.1068 C17H15O2+ 2 251.1067 0.73 251.143 C18H19O+ 2 251.143 -0.09 252.114 C17H16O2+ 1 252.1145 -1.73 252.151 C18H20O+ 2 252.1509 0.42 253.1222 C17H17O2+ 2 253.1223 -0.37 253.1588 C18H21O+ 2 253.1587 0.44 255.1176 C17H16FO+ 2 255.118 -1.59 255.1379 C17H19O2+ 2 255.138 -0.15 257.1324 C20H17+ 2 257.1325 -0.18 258.1039 C19H14O+ 2 258.1039 -0.18 259.1119 C19H15O+ 2 259.1117 0.6 260.1195 C19H16O+ 2 260.1196 -0.37 260.1326 C15H17FN2O+ 1 260.1319 2.49 261.0914 C18H13O2+ 2 261.091 1.49 261.1274 C19H17O+ 2 261.1274 0.06 262.0991 C18H14O2+ 2 262.0988 0.87 262.1351 C19H18O+ 2 262.1352 -0.33 263.1068 C18H15O2+ 2 263.1067 0.71 263.143 C19H19O+ 2 263.143 -0.13 264.1141 C18H16O2+ 1 264.1145 -1.41 265.1224 C18H17O2+ 2 265.1223 0.17 265.1587 C19H21O+ 2 265.1587 0.03 267.1382 C18H19O2+ 2 267.138 0.9 269.1174 C17H17O3+ 2 269.1172 0.62 269.1537 C18H21O2+ 2 269.1536 0.25 270.1033 C20H14O+ 1 270.1039 -2.2 271.1327 C17H19O3+ 2 271.1329 -0.46 273.1273 C20H17O+ 2 273.1274 -0.16 275.143 C20H19O+ 2 275.143 -0.22 276.1149 C19H16O2+ 2 276.1145 1.65 277.1225 C19H17O2+ 2 277.1223 0.62 277.158 C20H21O+ 1 277.1587 -2.39 278.1302 C19H18O2+ 2 278.1301 0.14 279.102 C18H15O3+ 2 279.1016 1.67 279.138 C19H19O2+ 2 279.138 0.11 280.1457 C19H20O2+ 2 280.1458 -0.37 281.1173 C18H17O3+ 2 281.1172 0.28 281.1536 C19H21O2+ 2 281.1536 0.14 283.1335 C15H20FO4+ 2 283.134 -1.89 283.1501 C19H20FO+ 1 283.1493 2.76 283.1694 C19H23O2+ 2 283.1693 0.5 285.1278 C21H17O+ 2 285.1274 1.57 285.1483 C18H21O3+ 2 285.1485 -0.93 288.1145 C20H16O2+ 2 288.1145 0.1 290.1297 C20H18O2+ 1 290.1301 -1.55 291.1379 C20H19O2+ 2 291.138 -0.32 293.1536 C20H21O2+ 2 293.1536 -0.07 295.1331 C19H19O3+ 2 295.1329 0.61 297.1486 C19H21O3+ 2 297.1485 0.33 303.1381 C21H19O2+ 2 303.138 0.38 308.1417 C17H21FO4+ 2 308.1418 -0.41 309.1485 C20H21O3+ 2 309.1485 0 311.1641 C20H23O3+ 2 311.1642 -0.36 313.1443 C16H22FO5+ 2 313.1446 -0.74 315.1221 C18H19O5+ 1 315.1227 -1.89 321.1486 C21H21O3+ 2 321.1485 0.17 327.1591 C20H23O4+ 2 327.1591 0.18 329.156 C20H22FO3+ 1 329.1547 3.72 329.1744 C20H25O4+ 2 329.1747 -1 339.1592 C21H23O4+ 2 339.1591 0.33 341.1552 C21H22FO3+ 1 341.1547 1.24 345.1698 C20H25O5+ 2 345.1697 0.51 357.1696 C21H25O5+ 2 357.1697 -0.05 359.1651 C21H24FO4+ 1 359.1653 -0.62 375.1803 C21H27O6+ 1 375.1802 0.25 377.1762 C21H26FO5+ 1 377.1759 0.91 395.1866 C21H28FO6+ 1 395.1864 0.45 PK$NUM_PEAK: 267 PK$PEAK: m/z int. rel.int. 53.0388 13442.5 2 55.0181 128861 23 55.0544 15452.2 2 57.0336 15900.7 2 59.0493 57005.6 10 67.0543 115842.7 21 69.0336 292052.2 54 69.07 55903.1 10 71.0492 122498.8 22 73.0284 22748.5 4 77.0386 11295 2 79.0542 164975.1 30 81.0334 106185.5 19 81.0699 206110.2 38 83.0491 140997.3 26 85.0649 19926.2 3 87.044 409486.3 76 91.0542 264632.1 49 93.0699 338736.4 62 95.0491 249906 46 95.0855 173949 32 97.0285 50833.8 9 97.0648 121139.9 22 99.0439 140938.2 26 103.0543 16242.2 3 105.0699 484722 90 107.0492 110709.5 20 107.0855 143101.3 26 109.0648 373424.2 69 111.0439 127452.2 23 111.0804 18298.5 3 113.0597 125014 23 115.039 74368.5 13 115.0542 30768.7 5 117.0545 21605.8 4 117.0699 172147.2 31 119.049 28047.4 5 119.0855 250108.9 46 121.0648 1248257.8 231 123.0443 92156.9 17 123.0804 111331.6 20 125.0597 183067.8 34 127.0389 20715.1 3 127.0753 19955.3 3 128.0619 142321 26 129.0699 131349.2 24 131.0855 168581.4 31 132.0569 19280.7 3 133.0648 215948.2 40 133.1011 22719.8 4 135.0804 405961.9 75 137.0597 332052.6 61 139.0753 85460 15 141.0547 103213.5 19 141.0697 96415.3 17 142.0777 69730.2 12 143.0855 522795.2 97 144.0569 18860.6 3 145.0647 417144.5 77 145.1008 87796.2 16 146.0726 27957.2 5 147.0804 2893321.8 537 149.0598 93885.3 17 151.0389 28731.7 5 151.0753 162520.8 30 153.0548 28691.2 5 153.0699 26531 4 153.091 72706 13 155.0605 15837.4 2 155.0701 153857.2 28 155.0854 193831.2 36 156.0932 16951.1 3 157.0648 68006.5 12 157.1011 168241 31 158.0726 137394 25 159.0804 842848.1 156 160.0883 17230.2 3 161.0597 95081.5 17 161.0961 409967.2 76 163.0754 177757.5 33 165.0546 13017.4 2 165.07 70106.9 13 165.0912 13338.4 2 166.0778 27685.2 5 167.0703 55770.4 10 167.0855 67555.9 12 168.0929 13904.5 2 169.0648 184597.6 34 169.1011 99691 18 170.0724 52906.4 9 171.0804 1519972.9 282 171.1168 98771.6 18 172.0883 23382.3 4 173.0807 78359.8 14 173.0961 501297.9 93 175.0754 388272.2 72 177.0912 14809 2 178.0777 78879.8 14 179.0703 66644.9 12 179.0856 151528.8 28 180.0933 78979.3 14 181.0646 28869.9 5 181.101 130782.1 24 182.0726 56305.1 10 182.1091 47182.1 8 183.0805 236762.4 44 183.1168 67611.8 12 184.0884 51661.3 9 185.0961 747421.9 138 187.0754 1024616.1 190 187.1116 185151.1 34 189.0707 25393 4 189.0909 92631 17 190.0778 73968.4 13 191.0857 123234.8 22 192.0932 161032.1 29 193.0862 14272.1 2 193.1011 169729.2 31 194.0727 55657.5 10 194.1094 12544.6 2 195.0805 253653.6 47 195.1169 186782 34 196.0882 193639.5 35 197.0809 67966.6 12 197.0961 546194 101 197.1322 98351.9 18 198.1039 67134.4 12 199.0752 24264.8 4 199.1118 356580.2 66 201.091 75202.3 13 202.0773 46818.7 8 203.0855 60286.5 11 203.1069 30498.8 5 204.0933 60255.5 11 205.1012 180234.5 33 206.0729 19961.2 3 206.1089 132359.6 24 207.0803 17685.1 3 207.1168 293387.8 54 208.0882 282453 52 209.0961 702235.6 130 209.1324 84045.3 15 210.1039 303247 56 211.1117 631254.2 117 212.1194 25086.4 4 213.0911 147830.1 27 213.1273 577531.8 107 215.0857 27362.9 5 215.1067 79552.9 14 215.1433 20982.2 3 216.0938 50432.4 9 217.1011 114946.7 21 218.0726 24388.1 4 218.109 62341.1 11 219.0803 72368.8 13 219.117 142183.5 26 220.0879 105527 19 221.0961 449730.2 83 221.1324 235091.7 43 222.1039 282241.3 52 223.1117 1320011 245 224.1196 303486.1 56 225.1273 2144805.5 398 226.0984 23491.9 4 226.1347 13519.9 2 227.0855 25702.6 4 227.1065 132815.5 24 227.1431 83368 15 228.093 53116.1 9 229.1009 51585.5 9 230.1096 95366.4 17 231.0805 78313.5 14 231.1168 61585 11 232.088 93979.9 17 232.1245 66747.4 12 233.096 236156.2 43 233.1322 136922.5 25 234.1038 201403 37 235.1117 710096 131 236.1194 93933.6 17 237.091 73498.9 13 237.1274 901800.6 167 238.0987 16576 3 239.1067 157774.5 29 239.143 363210.8 67 241.1016 24216.6 4 241.1223 233597 43 241.1583 16633 3 242.1089 89948.5 16 243.1037 15607.4 2 243.1167 125314.2 23 243.1378 63814.3 11 245.0962 218028 40 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