MassBank Record: AU107604

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Methylprednisolone; LC-ESI-QTOF; MS2; CE: 40 eV; R=35000; [M+H]+
Mass Spectrum
Chemical Structure
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ACCESSION: AU107604
RECORD_TITLE: Methylprednisolone; LC-ESI-QTOF; MS2; CE: 40 eV; R=35000; [M+H]+
DATE: 2016.02.20
AUTHORS: Nikiforos Alygizakis, Reza Aalizadeh, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2016 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 1076

CH$NAME: Methylprednisolone CH$NAME: methylprednisolone CH$NAME: (6S,8S,9S,10R,11S,13S,14S,17R)-11,17-dihydroxy-17-(2-hydroxyacetyl)-6,10,13-trimethyl-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-one CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C22H30O5 CH$EXACT_MASS: 374.2093241 CH$SMILES: C[C@H]1C[C@H]2[C@@H]3CC[C@@]([C@]3(C[C@@H]([C@@H]2[C@@]4(C1=CC(=O)C=C4)C)O)C)(C(=O)CO)O CH$IUPAC: InChI=1S/C22H30O5/c1-12-8-14-15-5-7-22(27,18(26)11-23)21(15,3)10-17(25)19(14)20(2)6-4-13(24)9-16(12)20/h4,6,9,12,14-15,17,19,23,25,27H,5,7-8,10-11H2,1-3H3/t12-,14-,15-,17-,19+,20-,21-,22-/m0/s1 CH$LINK: CAS 83-43-2 CH$LINK: CHEBI 6888 CH$LINK: KEGG D00407 CH$LINK: LIPIDMAPS LMST02030178 CH$LINK: PUBCHEM CID:6741 CH$LINK: INCHIKEY VHRSUDSXCMQTMA-PJHHCJLFSA-N CH$LINK: CHEMSPIDER 6485 CH$LINK: COMPTOX DTXSID7023300
AC$INSTRUMENT: Bruker maXis Impact AC$INSTRUMENT_TYPE: LC-ESI-QTOF AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID AC$MASS_SPECTROMETRY: COLLISION_ENERGY 40 eV AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min AC$CHROMATOGRAPHY: RETENTION_TIME 8.591 min AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 375.2204 MS$FOCUSED_ION: PRECURSOR_M/Z 375.2166 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1 MS$DATA_PROCESSING: WHOLE RMassBank 1.99.10
PK$SPLASH: splash10-01p9-0960000000-ef914702163187cc80af PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 115.0552 C9H7+ 1 115.0542 8.51 116.0609 C9H8+ 1 116.0621 -10.28 117.0703 C9H9+ 1 117.0699 3.94 119.0865 C9H11+ 1 119.0855 8.04 120.0904 C9H12+ 1 120.0934 -24.42 121.0656 C8H9O+ 1 121.0648 6.76 121.1018 C9H13+ 1 121.1012 5.02 122.0685 C7[13]CH9O+ 1 122.0687 -1.57 123.0815 C8H11O+ 1 123.0804 8.19 125.0607 C7H9O2+ 1 125.0597 8.15 127.0545 C10H7+ 1 127.0542 2.53 128.0625 C10H8+ 1 128.0621 3.29 129.0704 C10H9+ 1 129.0699 4.4 130.0777 C10H10+ 1 130.0777 0.02 131.0496 C9H7O+ 1 131.0491 3.14 131.0861 C10H11+ 1 131.0855 4.5 132.0572 C9H8O+ 1 132.057 2.06 132.0897 C9[13]CH11+ 1 132.0894 2.07 133.0653 C9H9O+ 1 133.0648 3.98 133.102 C10H13+ 1 133.1012 5.96 134.07 C9H10O+ 1 134.0726 -19.38 134.1053 C9[13]CH13+ 1 134.1051 1.45 135.0813 C9H11O+ 1 135.0804 6.52 136.0845 C8[13]CH11O+ 1 136.0843 1.18 137.0607 C8H9O2+ 1 137.0597 7.15 137.0972 C9H13O+ 1 137.0961 8.1 138.0649 C8H10O2+ 1 138.0675 -19.2 139.0766 C8H11O2+ 1 139.0754 8.61 141.0708 C11H9+ 1 141.0699 6.85 142.0783 C11H10+ 1 142.0777 4.2 143.0862 C11H11+ 1 143.0855 4.72 144.0573 C10H8O+ 1 144.057 2.04 144.0916 C11H12+ 1 144.0934 -12.2 145.0653 C10H9O+ 1 145.0648 3.76 145.1021 C11H13+ 1 145.1012 6.3 146.0733 C10H10O+ 1 146.0726 4.81 146.1058 C10[13]CH13+ 1 146.1051 4.79 147.0809 C10H11O+ 1 147.0804 3.41 147.1169 C11H15+ 1 147.1168 0.39 148.0855 C9[13]CH11O+ 1 148.0843 8.05 148.1226 C11H16+ 1 148.1247 -13.74 149.0968 C10H13O+ 1 149.0961 4.79 150.1002 C10H14O+ 1 150.1039 -24.96 151.0765 C9H11O2+ 1 151.0754 7.3 151.1127 C10H15O+ 1 151.1117 6.38 152.0636 C12H8+ 1 152.0621 10.25 153.0712 C12H9+ 1 153.0699 8.65 154.0782 C12H10+ 1 154.0777 3.36 155.0859 C12H11+ 1 155.0855 2.65 156.0933 C12H12+ 1 156.0934 -0.62 157.0654 C11H9O+ 1 157.0648 4.04 157.1023 C12H13+ 1 157.1012 7.08 158.0734 C11H10O+ 1 158.0726 5.01 158.1063 C11[13]CH13+ 1 158.1051 7.62 159.0811 C11H11O+ 1 159.0804 4.1 159.1183 C12H15+ 1 159.1168 9.41 160.0869 C11H12O+ 1 160.0883 -8.71 160.1218 C12H16+ 1 160.1247 -17.64 161.0972 C11H13O+ 1 161.0961 6.73 162.1004 C10[13]CH13O+ 1 162.1 2.51 163.0759 C10H11O2+ 1 163.0754 3.47 163.1062 C10[13]CH14O+ 1 163.1078 -9.71 163.1132 C11H15O+ 1 163.1117 9.15 165.0713 C13H9+ 1 165.0699 8.44 165.0923 C10H13O2+ 1 165.091 8.09 166.0792 C13H10+ 1 166.0777 9.12 167.0864 C13H11+ 1 167.0855 5.34 168.0593 C12H8O+ 1 168.057 13.63 168.0928 C13H12+ 1 168.0934 -3.49 169.0658 C12H9O+ 1 169.0648 5.69 169.1019 C13H13+ 1 169.1012 4.57 170.0734 C12H10O+ 1 170.0726 4.52 170.1092 C13H14+ 1 170.109 1.25 171.0813 C12H11O+ 1 171.0804 5.09 171.1179 C13H15+ 1 171.1168 6.47 172.0888 C12H12O+ 1 172.0883 3.17 172.1204 C13H16+ 1 172.1247 -24.5 173.0968 C12H13O+ 1 173.0961 4.32 173.1329 C13H17+ 1 173.1325 2.27 174.1017 C11[13]CH13O+ 1 174.1 10.07 175.0763 C11H11O2+ 1 175.0754 5.59 175.1126 C12H15O+ 1 175.1117 4.97 176.1161 C12H16O+ 1 176.1196 -19.79 177.0923 C11H13O2+ 1 177.091 7.07 177.1278 C12H17O+ 1 177.1274 2.23 178.0788 C14H10+ 1 178.0777 6.31 178.0945 C11H14O2+ 1 178.0988 -24.42 179.086 C14H11+ 1 179.0855 2.61 179.1082 C11H15O2+ 1 179.1067 8.86 180.0937 C14H12+ 1 180.0934 2.04 181.0663 C13H9O+ 1 181.0648 8.34 181.1016 C14H13+ 1 181.1012 2.13 182.0733 C13H10O+ 1 182.0726 3.81 182.1078 C14H14+ 1 182.109 -6.48 183.0816 C13H11O+ 1 183.0804 6.27 183.1178 C14H15+ 1 183.1168 5.58 184.0896 C13H12O+ 1 184.0883 7.23 184.122 C14H16+ 1 184.1247 -14.22 185.0976 C13H13O+ 1 185.0961 7.94 186.101 C12[13]CH13O+ 1 186.1 5.13 187.1127 C13H15O+ 1 187.1117 5.32 188.1165 C12[13]CH15O+ 1 188.1156 4.67 189.0924 C12H13O2+ 1 189.091 7.25 189.1294 C13H17O+ 1 189.1274 10.79 190.079 C15H10+ 2 190.0777 6.97 190.0962 C11[13]CH13O2+ 1 190.0949 6.64 191.086 C15H11+ 1 191.0855 2.32 191.1446 C13H19O+ 1 191.143 7.98 192.0947 C15H12+ 2 192.0934 6.83 193.1023 C15H13+ 2 193.1012 5.9 194.0735 C14H10O+ 1 194.0726 4.42 194.1085 C15H14+ 1 194.109 -2.81 195.082 C14H11O+ 1 195.0804 8.18 195.1185 C15H15+ 2 195.1168 8.62 196.0892 C14H12O+ 1 196.0883 4.56 197.0967 C14H13O+ 1 197.0961 3.19 197.1334 C15H17+ 2 197.1325 4.85 198.1031 C14H14O+ 1 198.1039 -3.93 199.1131 C14H15O+ 1 199.1117 6.67 200.1179 C13[13]CH15O+ 1 200.1156 11.26 201.0939 C13H13O2+ 1 201.091 14.35 201.1285 C14H17O+ 1 201.1274 5.64 202.0791 C16H10+ 2 202.0777 7.06 202.1317 C14H18O+ 1 202.1352 -17.45 203.087 C16H11+ 2 203.0855 7.32 203.1432 C14H19O+ 1 203.143 0.71 204.0931 C16H12+ 1 204.0934 -1.22 205.1036 C16H13+ 2 205.1012 11.95 206.109 C16H14+ 1 206.109 -0.02 207.0834 C15H11O+ 1 207.0804 14.3 207.1169 C16H15+ 1 207.1168 0.56 208.0894 C15H12O+ 1 208.0883 5.51 208.1272 C16H16+ 2 208.1247 12.42 209.0973 C15H13O+ 1 209.0961 5.82 209.1345 C16H17+ 2 209.1325 9.59 210.1039 C15H14O+ 1 210.1039 0.09 211.1134 C15H15O+ 1 211.1117 7.88 212.118 C14[13]CH15O+ 1 212.1156 11.23 213.0924 C14H13O2+ 1 213.091 6.53 213.1291 C15H17O+ 1 213.1274 8.05 214.1344 C14[13]CH17O+ 1 214.1313 14.28 215.0858 C17H11+ 1 215.0855 1.24 215.109 C14H15O2+ 1 215.1067 10.76 216.0934 C17H12+ 1 216.0934 0.05 217.1014 C17H13+ 1 217.1012 0.87 218.1098 C17H14+ 2 218.109 3.46 219.0822 C16H11O+ 1 219.0804 8.07 219.1182 C17H15+ 2 219.1168 6.19 220.0895 C16H12O+ 1 220.0883 5.47 220.1255 C17H16+ 2 220.1247 3.75 221.0989 C16H13O+ 1 221.0961 12.57 221.1326 C17H17+ 1 221.1325 0.38 222.1049 C16H14O+ 1 222.1039 4.63 222.1379 C17H18+ 1 222.1403 -10.94 223.1125 C16H15O+ 1 223.1117 3.36 223.1491 C17H19+ 2 223.1481 4.21 224.1204 C16H16O+ 1 224.1196 3.54 225.129 C16H17O+ 1 225.1274 7.07 225.1664 C17H21+ 2 225.1638 11.69 226.1335 C16H18O+ 1 226.1352 -7.48 227.1105 C15H15O2+ 1 227.1067 16.89 227.1448 C16H19O+ 1 227.143 7.53 228.1491 C16H20O+ 1 228.1509 -7.8 229.1026 C18H13+ 2 229.1012 6.07 229.125 C15H17O2+ 1 229.1223 11.69 230.1094 C18H14+ 2 230.109 1.66 231.0836 C17H11O+ 1 231.0804 13.7 231.1186 C18H15+ 2 231.1168 7.69 231.139 C15H19O2+ 1 231.138 4.55 232.0901 C17H12O+ 1 232.0883 7.69 232.1252 C18H16+ 2 232.1247 2.41 233.0975 C17H13O+ 1 233.0961 6.07 233.133 C18H17+ 2 233.1325 2.17 234.1052 C17H14O+ 1 234.1039 5.44 234.1406 C18H18+ 2 234.1403 1.45 235.1136 C17H15O+ 1 235.1117 8.02 235.148 C18H19+ 1 235.1481 -0.66 236.1203 C17H16O+ 1 236.1196 3.31 236.1533 C18H20+ 1 236.156 -11.3 237.1287 C17H17O+ 1 237.1274 5.57 238.1363 C17H18O+ 1 238.1352 4.36 239.1062 C16H15O2+ 1 239.1067 -1.88 239.144 C17H19O+ 1 239.143 4.03 240.1509 C17H20O+ 1 240.1509 -0.06 241.1246 C16H17O2+ 1 241.1223 9.57 241.1596 C17H21O+ 1 241.1587 3.61 242.1641 C17H22O+ 1 242.1665 -10.05 243.1179 C19H15+ 2 243.1168 4.45 245.0976 C18H13O+ 1 245.0961 6.3 245.1346 C19H17+ 2 245.1325 8.67 246.1052 C18H14O+ 1 246.1039 5.31 246.1401 C19H18+ 2 246.1403 -0.71 247.1157 C18H15O+ 1 247.1117 15.84 247.1523 C12H23O5+ 2 247.154 -7 248.1217 C18H16O+ 1 248.1196 8.76 249.1289 C18H17O+ 1 249.1274 6.03 250.1375 C18H18O+ 1 250.1352 8.95 251.1086 C17H15O2+ 1 251.1067 7.87 251.1453 C18H19O+ 1 251.143 8.86 252.1126 C17H16O2+ 1 252.1145 -7.33 252.1493 C17[13]CH19O+ 1 252.1469 9.3 253.1262 C17H17O2+ 1 253.1223 15.53 253.1606 C18H21O+ 1 253.1587 7.39 254.1637 C17[13]CH21O+ 1 254.1626 4.2 255.1125 C20H15+ 1 255.1168 -17.08 255.1402 C17H19O2+ 1 255.138 8.89 255.175 C18H23O+ 1 255.1743 2.51 259.1143 C19H15O+ 1 259.1117 9.78 259.1502 C20H19+ 2 259.1481 7.98 260.1222 C19H16O+ 1 260.1196 10.2 261.129 C19H17O+ 1 261.1274 6.27 261.1663 C20H21+ 2 261.1638 9.82 262.1367 C19H18O+ 1 262.1352 5.49 263.1115 C18H15O2+ 1 263.1067 18.32 263.1448 C19H19O+ 1 263.143 6.63 263.1829 C13H27O5+ 2 263.1853 -9.19 264.1151 C18H16O2+ 1 264.1145 2.44 264.1506 C19H20O+ 1 264.1509 -0.99 265.1224 C18H17O2+ 1 265.1223 0.36 265.1609 C19H21O+ 1 265.1587 8.2 266.131 C18H18O2+ 1 266.1301 3.29 266.1643 C19H22O+ 1 266.1665 -8.19 267.1403 C18H19O2+ 1 267.138 8.67 267.1698 C18[13]CH22O+ 1 267.1704 -2.49 268.1471 C18H20O2+ 1 268.1458 4.98 269.151 C18H21O2+ 1 269.1536 -9.87 273.1308 C20H17O+ 1 273.1274 12.65 274.1363 C20H18O+ 1 274.1352 3.85 275.1471 C20H19O+ 1 275.143 14.68 276.1536 C20H20O+ 1 276.1509 9.76 277.1274 C19H17O2+ 1 277.1223 18.33 277.1621 C20H21O+ 1 277.1587 12.2 278.167 C20H22O+ 1 278.1665 1.64 279.1403 C19H19O2+ 1 279.138 8.57 279.1774 C20H23O+ 1 279.1743 10.97 280.1477 C19H20O2+ 1 280.1458 6.71 280.1838 C20H24O+ 1 280.1822 5.93 281.1888 C20H25O+ 1 281.19 -4.39 282.1919 C19[13]CH25O+ 1 282.1939 -7.05 287.1438 C21H19O+ 1 287.143 2.58 288.1525 C21H20O+ 1 288.1509 5.66 289.1583 C21H21O+ 1 289.1587 -1.2 290.1662 C21H22O+ 1 290.1665 -1.04 291.1381 C20H19O2+ 1 291.138 0.35 291.1767 C21H23O+ 1 291.1743 7.97 292.1798 C21H24O+ 1 292.1822 -7.98 293.1546 C20H21O2+ 1 293.1536 3.52 293.1915 C21H25O+ 1 293.19 5.08 294.164 C20H22O2+ 1 294.1614 8.74 294.1949 C21H26O+ 1 294.1978 -9.85 295.1691 C20H23O2+ 1 295.1693 -0.4 297.1535 C19H21O3+ 1 297.1485 16.92 303.176 C22H23O+ 1 303.1743 5.36 304.1839 C22H24O+ 1 304.1822 5.74 306.1641 C21H22O2+ 1 306.1614 8.87 308.1802 C21H24O2+ 1 308.1771 9.96 309.1862 C21H25O2+ 1 309.1849 4.25 311.1678 C20H23O3+ 1 311.1642 11.61 321.1874 C22H25O2+ 1 321.1849 7.65 322.194 C22H26O2+ 1 322.1927 3.85 339.1981 C22H27O3+ 1 339.1955 7.6 PK$NUM_PEAK: 261 PK$PEAK: m/z int. rel.int. 115.0552 4092 67 116.0609 548 9 117.0703 3132 51 119.0865 3808 62 120.0904 464 7 121.0656 17820 293 121.1018 1044 17 122.0685 1468 24 123.0815 1276 21 125.0607 844 13 127.0545 324 5 128.0625 4092 67 129.0704 3492 57 130.0777 1096 18 131.0496 1324 21 131.0861 7064 116 132.0572 748 12 132.0897 744 12 133.0653 1856 30 133.102 7372 121 134.07 420 6 134.1053 780 12 135.0813 42080 693 136.0845 3728 61 137.0607 2316 38 137.0972 972 16 138.0649 324 5 139.0766 884 14 141.0708 3064 50 142.0783 3192 52 143.0862 6016 99 144.0573 2300 37 144.0916 1276 21 145.0653 9808 161 145.1021 6556 108 146.0733 6204 102 146.1058 772 12 147.0809 8336 137 147.1169 1772 29 148.0855 1228 20 148.1226 340 5 149.0968 3384 55 150.1002 476 7 151.0765 504 8 151.1127 428 7 152.0636 816 13 153.0712 1088 17 154.0782 940 15 155.0859 2420 39 156.0933 1192 19 157.0654 1284 21 157.1023 4688 77 158.0734 6452 106 158.1063 708 11 159.0811 19260 317 159.1183 2648 43 160.0869 4344 71 160.1218 556 9 161.0972 60608 999 162.1004 7084 116 163.0759 368 6 163.1062 560 9 163.1132 600 9 165.0713 900 14 165.0923 1452 23 166.0792 1396 23 167.0864 1952 32 168.0593 336 5 168.0928 668 11 169.0658 1116 18 169.1019 2680 44 170.0734 1336 22 170.1092 992 16 171.0813 6208 102 171.1179 2132 35 172.0888 6388 105 172.1204 620 10 173.0968 13720 226 173.1329 1520 25 174.1017 1804 29 175.0763 404 6 175.1126 4100 67 176.1161 624 10 177.0923 2316 38 177.1278 328 5 178.0788 1516 24 178.0945 460 7 179.086 1716 28 179.1082 384 6 180.0937 856 14 181.0663 1396 23 181.1016 1812 29 182.0733 1012 16 182.1078 524 8 183.0816 2816 46 183.1178 1940 31 184.0896 1776 29 184.122 556 9 185.0976 44164 727 186.101 6572 108 187.1127 25944 427 188.1165 3336 54 189.0924 5476 90 189.1294 868 14 190.079 428 7 190.0962 776 12 191.086 876 14 191.1446 392 6 192.0947 792 13 193.1023 4548 74 194.0735 624 10 194.1085 1452 23 195.082 4864 80 195.1185 1780 29 196.0892 6932 114 197.0967 7736 127 197.1334 652 10 198.1031 2760 45 199.1131 8596 141 200.1179 1480 24 201.0939 600 9 201.1285 2456 40 202.0791 616 10 202.1317 460 7 203.087 720 11 203.1432 492 8 204.0931 920 15 205.1036 1368 22 206.109 1608 26 207.0834 692 11 207.1169 2096 34 208.0894 3396 55 208.1272 704 11 209.0973 12444 205 209.1345 1392 22 210.1039 7532 124 211.1134 38472 634 212.118 6452 106 213.0924 480 7 213.1291 7916 130 214.1344 1304 21 215.0858 412 6 215.109 348 5 216.0934 584 9 217.1014 664 10 218.1098 1316 21 219.0822 580 9 219.1182 1776 29 220.0895 1344 22 220.1255 2708 44 221.0989 2784 45 221.1326 1840 30 222.1049 7928 130 222.1379 476 7 223.1125 14428 237 223.1491 804 13 224.1204 6760 111 225.129 8360 137 225.1664 456 7 226.1335 2668 43 227.1105 784 12 227.1448 2640 43 228.1491 916 15 229.1026 340 5 229.125 376 6 230.1094 516 8 231.0836 500 8 231.1186 1376 22 231.139 1356 22 232.0901 556 9 232.1252 672 11 233.0975 1476 24 233.133 1452 23 234.1052 2048 33 234.1406 816 13 235.1136 6036 99 235.148 2036 33 236.1203 6292 103 236.1533 492 8 237.1287 11628 191 238.1363 10728 176 239.1062 560 9 239.144 6040 99 240.1509 2072 34 241.1246 364 5 241.1596 824 13 242.1641 348 5 243.1179 548 9 245.0976 1356 22 245.1346 404 6 246.1052 2292 37 246.1401 384 6 247.1157 1524 25 247.1523 368 6 248.1217 3144 51 249.1289 4960 81 250.1375 3056 50 251.1086 724 11 251.1453 11392 187 252.1126 712 11 252.1493 2520 41 253.1262 692 11 253.1606 12176 200 254.1637 2876 47 255.1125 324 5 255.1402 436 7 255.175 1208 19 259.1143 2396 39 259.1502 312 5 260.1222 1708 28 261.129 3512 57 261.1663 464 7 262.1367 2624 43 263.1115 460 7 263.1448 3336 54 263.1829 3080 50 264.1151 1208 19 264.1506 2136 35 265.1224 824 13 265.1609 16416 270 266.131 832 13 266.1643 3128 51 267.1403 2044 33 267.1698 448 7 268.1471 676 11 269.151 468 7 273.1308 2036 33 274.1363 1944 32 275.1471 1668 27 276.1536 948 15 277.1274 540 8 277.1621 1824 30 278.167 1912 31 279.1403 2652 43 279.1774 4804 79 280.1477 508 8 280.1838 9336 153 281.1888 2844 46 282.1919 428 7 287.1438 568 9 288.1525 1816 29 289.1583 684 11 290.1662 476 7 291.1381 492 8 291.1767 1588 26 292.1798 440 7 293.1546 904 14 293.1915 1360 22 294.164 352 5 294.1949 400 6 295.1691 520 8 297.1535 728 11 303.176 1228 20 304.1839 544 8 306.1641 524 8 308.1802 1220 20 309.1862 1172 19 311.1678 460 7 321.1874 540 8 322.194 364 5 339.1981 372 6 //