ACCESSION: MSBNK-Athens_Univ-AU248503
RECORD_TITLE: (Methoxymethyl)triphenylphosphonium; LC-ESI-QTOF; MS2; CE: 30 eV; R=35000; [M+H]+
DATE: 2019.04.08
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2485

CH$NAME: (Methoxymethyl)triphenylphosphonium
CH$NAME: methoxymethyl(triphenyl)phosphanium
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C₂₀H₂₀OP⁺
CH$EXACT_MASS: 307.1251769
CH$SMILES: COC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
CH$IUPAC: InChI=1S/C20H20OP/c1-21-17-22(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-16H,17H2,1H3/q+1
CH$LINK: PUBCHEM CID:2723799
CH$LINK: INCHIKEY SDMCZCALYDCRBH-UHFFFAOYSA-N
CH$LINK: CHEMSPIDER 2005990

AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 30 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 6.403 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate

MS$FOCUSED_ION: BASE_PEAK 307.1232
MS$FOCUSED_ION: PRECURSOR_M/Z 308.1325
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1

PK$SPLASH: splash10-0a4r-0869000000-5f9e16a137bb368957e4
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
  183.0354 C12H8P+ 1 183.0358 -2.16
  185.051 C12H10P+ 1 185.0515 -2.77
  262.0882 C18H15P+ 1 262.0906 -9.22
  277.1117 C19H18P+ 1 277.1141 -8.64
  307.1243 C20H20OP+ 1 307.1246 -1.04
PK$NUM_PEAK: 5
PK$PEAK: m/z int. rel.int.
  183.0354 308 221
  185.051 1036 745
  262.0882 420 302
  277.1117 576 414
  307.1243 1388 999
//