ACCESSION: MSBNK-RIKEN_NPDepo-NGA00313
RECORD_TITLE: Dihydrolycorine; LC-ESI-QQQ; MS2; Frag=135.0V CID@5.0; [M+H]+
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant
COMMENT: SubCategory_DNP: Isoquinoline alkaloids, Amaryllidaceae alkaloids, Lycorine alkaloids

CH$NAME: Dihydrolycorine
CH$COMPOUND_CLASS: Alkaloids
CH$FORMULA: C₁₆H₁₉NO₄
CH$EXACT_MASS: 289.3341
CH$SMILES: O[C@H]1CC2CCN3Cc4cc5c(cc4[C@H]([C@@H]1O)[C@@H]23)OCO5
CH$IUPAC: InChI=1S/C16H19NO4/c18-11-3-8-1-2-17-6-9-4-12-13(21-7-20-12)5-10(9)14(15(8)17)16(11)19/h4-5,8,11,14-16,18-19H,1-3,6-7H2/t8?,11-,14-,15+,16+/m0/s1
CH$LINK: CAS 6271-21-2
CH$LINK: CHEMSPIDER 432333 10050463 28426276
CH$LINK: INCHIKEY VJILFEGOWCJNIK-WIOQNRRMSA-N
CH$LINK: PUBCHEM CID:235311

AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE

MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+

PK$SPLASH: splash10-0006-0090000000-5645e0cd2f8c0529a799
PK$NUM_PEAK: 15
PK$PEAK: m/z int. rel.int.
  289.3 1.45 1
  289.4 3.05 3
  289.5 5.72 5
  289.6 11.07 11
  289.7 21.84 21
  289.8 39.51 39
  289.9 61.78 61
  290.0 82.94 82
  290.1 97.03 96
  290.2 100.0 99
  290.3 89.68 89
  290.4 66.84 66
  290.5 37.78 37
  290.6 12.84 12
  290.7 0.36 0
//