MassBank Record: MSBNK-RIKEN_NPDepo-NGA01616
ACCESSION: MSBNK-RIKEN_NPDepo-NGA01616
RECORD_TITLE: Lapidin; LC-ESI-QQQ; MS2; Frag=135.0V CID@25.0; [M+Na]+
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant
COMMENT: SubCategory_DNP: Sesquiterpenoids
CH$NAME: Lapidin
CH$COMPOUND_CLASS: Terpenoids
CH$FORMULA: C20H30O4
CH$EXACT_MASS: 334.4597
CH$SMILES: C/C=C(\C)C(=O)O[C@H]1CC(C)=CC(=O)[C@@]2(C)CC[C@@](O)(C(C)C)[C@H]12
CH$IUPAC: InChI=1S/C20H30O4/c1-7-14(5)18(22)24-15-10-13(4)11-16(21)19(6)8-9-20(23,12(2)3)17(15)19/h7,11-12,15,17,23H,8-10H2,1-6H3/b14-7+/t15-,17+,19+,20+/m0/s1
CH$LINK: CAS
79863-24-4
CH$LINK: CHEMSPIDER
4944881
CH$LINK: INCHIKEY
YMWBTMBPEHUMBA-FAKHFBMMSA-N
CH$LINK: PUBCHEM
CID:11872435
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+Na]+
PK$SPLASH: splash10-03di-4988800000-156c330abad14609d972
PK$NUM_PEAK: 2189
PK$PEAK: m/z int. rel.int.
50.8 6.37 6
50.9 6.62 6
51.0 7.17 7
51.1 8.12 8
51.2 8.53 8
51.3 7.97 7
51.4 7.1 7
51.5 6.72 6
52.3 3.48 3
52.4 6.91 6
52.5 9.47 9
52.6 8.31 8
53.6 3.6 3
53.7 4.83 4
53.8 6.43 6
53.9 8.27 8
54.0 10.28 10
54.1 11.12 11
54.2 9.63 9
55.7 6.54 6
55.8 8.19 8
55.9 8.92 8
56.0 7.58 7
56.1 6.01 6
56.2 5.84 5
56.9 5.54 5
57.0 6.25 6
57.1 8.65 8
57.2 9.88 9
57.3 8.15 8
57.4 5.24 5
57.6 4.75 4
57.7 6.06 6
57.8 6.73 6
57.9 6.63 6
58.0 5.95 5
58.1 5.51 5
58.2 6.56 6
58.3 8.92 8
58.4 10.4 10
58.5 9.47 9
59.4 4.04 4
59.5 5.09 5
59.6 6.65 6
59.7 7.37 7
59.8 6.69 6
59.9 6.01 6
60.0 6.23 6
60.1 6.39 6
60.2 5.64 5
60.3 5.24 5
60.4 6.03 6
60.5 6.6 6
60.6 5.58 5
60.7 4.43 4
60.8 5.67 5
60.9 8.6 8
61.0 9.6 9
61.1 7.36 7
63.0 4.49 4
63.1 6.99 6
63.2 8.54 8
63.3 8.51 8
63.4 8.16 8
63.5 8.01 8
63.6 7.72 7
63.7 7.57 7
63.8 7.93 7
63.9 8.16 8
64.0 7.39 7
64.1 6.82 6
64.2 8.29 8
64.3 10.77 10
64.4 10.87 10
64.5 7.66 7
66.9 4.47 4
67.0 5.79 5
67.1 6.55 6
67.2 7.1 7
67.3 7.77 7
67.4 7.6 7
67.5 6.39 6
67.6 6.32 6
67.7 8.53 8
67.8 10.67 10
67.9 10.01 9
68.0 7.68 7
69.4 5.57 5
69.5 7.8 7
69.6 9.0 8
69.7 8.32 8
69.8 7.53 7
69.9 7.82 7
70.0 7.82 7
70.1 6.58 6
70.2 5.35 5
70.3 5.23 5
70.4 5.19 5
71.4 3.35 3
71.5 4.35 4
71.6 5.41 5
71.7 5.26 5
71.8 4.64 4
71.9 5.17 5
72.0 6.65 6
72.1 7.44 7
72.2 7.07 7
72.3 6.58 6
72.4 6.69 6
72.5 7.1 7
72.6 7.27 7
72.7 7.32 7
72.8 7.77 7
72.9 8.06 8
74.1 4.49 4
74.2 6.16 6
74.3 7.47 7
74.4 8.73 8
74.5 10.67 10
74.6 11.78 11
74.7 10.14 10
74.8 6.93 6
75.9 8.26 8
76.0 9.18 9
76.1 9.47 9
76.2 10.21 10
76.3 10.48 10
76.4 8.24 8
78.2 3.51 3
78.3 5.14 5
78.4 8.5 8
78.5 9.82 9
78.8 6.96 6
78.9 9.13 9
79.0 9.83 9
79.1 8.56 8
79.2 6.68 6
80.6 3.65 3
80.7 4.55 4
80.8 4.35 4
80.9 4.79 4
81.0 6.74 6
81.1 8.68 8
81.2 9.01 9
81.3 8.03 8
81.4 6.78 6
81.7 5.29 5
81.8 7.53 7
81.9 9.45 9
82.0 9.2 9
82.1 7.67 7
82.2 6.84 6
82.3 6.37 6
82.5 4.29 4
82.6 5.9 5
82.7 8.53 8
82.8 8.85 8
82.9 6.98 6
83.0 6.4 6
83.1 8.02 8
83.2 8.59 8
83.3 6.36 6
83.5 4.97 4
83.6 7.16 7
83.7 7.41 7
83.8 5.81 5
83.9 5.24 5
84.0 6.68 6
84.1 8.34 8
84.2 8.71 8
84.3 8.14 8
84.4 7.16 7
84.7 4.85 4
84.8 7.47 7
84.9 9.42 9
85.0 8.8 8
85.1 6.98 6
85.5 5.57 5
85.6 6.41 6
85.7 8.65 8
85.8 9.73 9
85.9 8.72 8
86.0 7.35 7
86.1 6.72 6
87.3 4.55 4
87.4 6.45 6
87.5 7.23 7
87.6 5.77 5
87.7 4.69 4
87.8 6.17 6
87.9 8.47 8
88.0 8.96 8
88.1 8.04 8
88.2 7.8 7
88.3 8.35 8
88.4 8.22 8
88.5 6.99 6
88.6 5.7 5
88.7 4.62 4
88.9 2.8 2
89.0 4.41 4
89.1 6.96 6
89.2 7.48 7
90.3 4.07 4
90.4 5.97 5
90.5 7.84 7
90.6 7.72 7
90.7 6.35 6
90.8 5.22 5
91.0 3.99 3
91.1 5.07 5
91.2 7.33 7
91.3 8.09 8
92.0 3.83 3
92.1 6.35 6
92.2 8.07 8
92.3 7.66 7
92.4 7.02 7
92.5 7.49 7
92.6 7.96 7
92.7 7.23 7
92.8 6.12 6
93.2 5.83 5
93.3 7.05 7
93.4 8.18 8
93.5 8.32 8
93.6 8.04 8
93.7 8.19 8
93.8 8.37 8
93.9 7.53 7
97.3 3.79 3
97.4 5.37 5
97.5 6.82 6
97.6 7.97 7
97.7 7.52 7
97.8 5.25 5
98.0 4.04 4
98.1 5.95 5
98.2 6.65 6
98.3 6.53 6
98.4 7.57 7
98.5 9.02 9
98.6 8.3 8
99.4 2.81 2
99.5 4.12 4
99.6 5.51 5
99.7 6.89 6
99.8 7.36 7
99.9 7.11 7
100.0 7.8 7
100.1 9.39 9
100.2 9.69 9
101.1 4.98 4
101.2 5.63 5
101.3 6.58 6
101.4 8.29 8
101.5 8.66 8
101.6 6.11 6
101.8 3.79 3
101.9 7.14 7
102.0 8.94 8
102.1 7.67 7
102.2 6.42 6
102.3 7.45 7
102.4 8.88 8
102.5 8.32 8
102.6 7.03 7
102.7 7.54 7
102.8 9.4 9
102.9 10.04 10
103.0 9.13 9
105.3 4.78 4
105.4 6.12 6
105.5 7.49 7
105.6 8.63 8
105.7 8.68 8
106.0 6.38 6
106.1 8.76 8
106.2 10.16 10
106.3 9.32 9
106.4 8.1 8
106.5 8.17 8
106.6 8.33 8
106.7 6.85 6
107.4 4.54 4
107.5 7.88 7
107.6 9.5 9
107.7 8.57 8
107.8 6.55 6
107.9 4.38 4
108.1 2.13 2
108.2 3.84 3
108.3 5.53 5
108.6 1.63 1
108.7 5.29 5
108.8 9.13 9
108.9 9.83 9
109.0 8.53 8
109.1 8.54 8
109.2 10.02 10
109.3 10.46 10
109.4 8.91 8
109.5 7.19 7
109.8 6.27 6
109.9 7.48 7
110.0 8.72 8
110.1 7.91 7
110.3 5.06 5
110.4 7.29 7
110.5 9.33 9
110.6 8.51 8
112.5 5.28 5
112.6 7.57 7
112.7 8.29 8
113.8 5.7 5
113.9 9.03 9
114.0 10.42 10
114.1 9.71 9
114.2 9.05 9
114.3 8.65 8
114.4 7.02 7
115.0 3.59 3
115.1 5.28 5
115.2 7.4 7
115.3 7.48 7
115.4 6.28 6
115.5 6.24 6
115.6 7.21 7
115.7 7.43 7
115.8 7.02 7
115.9 7.54 7
116.0 8.7 8
116.1 8.56 8
116.4 5.72 5
116.5 7.44 7
116.6 9.08 9
116.7 9.32 9
116.8 7.57 7
116.9 4.59 4
117.1 3.09 3
117.2 6.36 6
117.3 9.41 9
117.4 9.44 9
117.5 6.55 6
117.6 3.16 3
117.8 1.81 1
117.9 3.88 3
118.0 6.86 6
118.1 9.03 9
118.2 8.6 8
118.3 5.96 5
118.7 5.64 5
118.8 5.36 5
118.9 6.2 6
119.0 7.71 7
119.1 7.84 7
119.2 6.72 6
119.3 6.42 6
119.4 6.85 6
119.5 5.76 5
119.7 2.97 2
119.8 5.37 5
119.9 7.04 7
120.0 5.73 5
120.1 4.08 4
120.2 5.21 5
120.3 7.87 7
120.4 9.19 9
120.5 8.91 8
120.6 8.64 8
120.7 8.7 8
120.8 8.65 8
120.9 8.66 8
121.0 8.91 8
121.1 8.73 8
121.2 7.71 7
121.3 6.53 6
121.4 5.81 5
121.5 4.83 4
121.7 1.55 1
121.8 3.39 3
121.9 7.71 7
122.0 10.09 10
122.1 7.88 7
123.6 3.94 3
123.7 6.13 6
123.8 6.79 6
123.9 6.68 6
124.0 7.75 7
124.1 9.09 9
124.2 8.63 8
124.3 7.31 7
124.4 7.76 7
124.5 9.61 9
124.6 9.47 9
125.6 2.22 2
125.7 3.84 3
125.8 6.74 6
125.9 7.7 7
126.0 6.13 6
126.1 5.19 5
126.2 6.74 6
126.3 8.35 8
126.4 7.47 7
126.5 5.39 5
126.6 4.59 4
126.9 3.83 3
127.0 6.23 6
127.1 9.24 9
127.2 9.05 9
127.5 6.39 6
127.6 8.8 8
127.7 9.24 9
127.8 8.57 8
127.9 8.23 8
128.0 7.68 7
128.3 6.26 6
128.4 7.39 7
128.5 7.42 7
128.6 6.95 6
128.7 7.24 7
128.8 7.78 7
128.9 7.02 7
129.5 5.9 5
129.6 7.42 7
129.7 8.58 8
131.1 7.4 7
131.2 8.48 8
131.3 9.89 9
131.4 10.49 10
131.5 9.32 9
131.6 7.43 7
131.7 6.69 6
133.4 3.63 3
133.5 6.41 6
133.6 8.12 8
133.7 7.04 7
133.8 5.87 5
133.9 6.37 6
134.0 6.66 6
134.1 5.64 5
134.2 5.61 5
134.3 7.59 7
134.4 9.25 9
134.5 8.91 8
134.6 8.02 8
134.7 8.15 8
134.8 8.29 8
134.9 6.91 6
136.0 4.13 4
136.1 5.28 5
136.2 5.19 5
136.3 5.25 5
136.4 7.41 7
136.5 10.15 10
136.6 10.48 10
136.7 8.7 8
137.0 7.54 7
137.1 7.58 7
137.2 10.3 10
137.3 14.55 14
137.4 15.83 15
137.5 12.73 12
137.6 9.09 9
138.9 4.21 4
139.0 6.54 6
139.1 8.9 8
139.2 8.73 8
139.3 7.29 7
139.4 6.66 6
139.7 5.11 5
139.8 7.21 7
139.9 9.3 9
140.0 8.49 8
140.1 5.88 5
140.6 5.43 5
140.7 7.84 7
140.8 9.97 9
140.9 9.16 9
141.2 7.1 7
141.3 8.5 8
141.4 8.76 8
141.5 8.45 8
141.6 7.77 7
143.9 5.09 5
144.0 5.5 5
144.1 6.83 6
144.2 7.34 7
144.3 5.89 5
146.2 4.56 4
146.3 7.25 7
146.4 8.71 8
146.5 7.41 7
147.5 2.8 2
147.6 4.49 4
147.7 6.46 6
147.8 7.68 7
147.9 8.43 8
148.0 8.62 8
148.1 7.38 7
148.9 6.6 6
149.0 8.26 8
149.1 10.35 10
149.2 12.02 12
149.3 11.73 11
149.4 8.62 8
150.1 5.53 5
150.2 7.39 7
150.3 8.76 8
150.4 9.16 9
150.5 9.16 9
150.6 8.7 8
150.7 7.71 7
154.3 3.73 3
154.4 5.08 5
154.5 5.89 5
154.6 5.48 5
154.7 5.17 5
154.8 5.6 5
154.9 5.74 5
155.0 5.27 5
155.1 5.64 5
155.2 7.43 7
155.3 8.98 8
155.4 9.03 9
155.5 8.53 8
155.6 8.6 8
155.7 8.79 8
155.8 8.45 8
155.9 8.01 8
156.0 7.43 7
156.1 5.71 5
156.3 2.11 2
156.4 4.1 4
156.5 7.29 7
156.6 8.84 8
156.7 8.17 8
156.8 6.96 6
157.1 5.53 5
157.2 7.11 7
157.3 9.63 9
157.4 10.71 10
157.5 9.21 9
157.6 6.86 6
158.0 6.03 6
158.1 6.57 6
158.2 8.55 8
158.3 9.62 9
158.4 8.26 8
159.4 5.57 5
159.5 8.71 8
159.6 11.05 11
159.7 10.54 10
159.8 8.29 8
159.9 6.26 6
160.1 5.43 5
160.2 6.74 6
160.3 8.04 8
160.4 7.3 7
160.6 1.55 1
160.7 3.93 3
160.8 11.95 11
160.9 21.7 21
161.0 28.7 28
161.1 30.65 30
161.2 26.39 26
161.3 16.83 16
161.4 6.84 6
161.6 3.61 3
161.7 6.1 6
161.8 6.98 6
161.9 7.11 7
162.0 7.25 7
162.3 5.63 5
162.4 7.18 7
162.5 7.92 7
163.5 2.98 2
163.6 4.25 4
163.7 7.44 7
163.8 10.6 10
163.9 10.81 10
164.0 8.3 8
164.6 6.43 6
164.7 7.88 7
164.8 7.96 7
164.9 7.57 7
165.0 8.62 8
165.1 10.19 10
165.2 9.98 9
165.3 8.03 8
166.3 5.81 5
166.4 7.32 7
166.5 8.16 8
166.6 8.43 8
166.7 8.6 8
166.8 7.99 7
167.4 5.75 5
167.5 6.81 6
167.6 8.81 8
167.7 9.37 9
167.8 8.12 8
167.9 6.94 6
168.2 6.22 6
168.3 7.04 7
168.4 9.21 9
168.5 10.04 10
168.6 7.73 7
168.7 4.36 4
168.9 3.96 3
169.0 4.77 4
169.1 5.47 5
169.2 7.28 7
169.3 9.36 9
169.4 9.44 9
169.5 7.38 7
169.6 5.5 5
170.6 4.14 4
170.7 5.45 5
170.8 5.52 5
170.9 5.26 5
171.0 5.9 5
171.1 7.05 7
171.2 7.72 7
171.3 7.61 7
171.4 6.76 6
171.7 4.28 4
171.8 6.24 6
171.9 8.31 8
172.0 9.11 9
172.1 9.09 9
172.2 9.3 9
172.3 9.2 9
172.4 7.54 7
172.6 3.79 3
172.7 5.93 5
172.8 8.91 8
172.9 9.73 9
173.0 8.43 8
173.1 6.82 6
173.2 5.24 5
173.4 2.46 2
173.5 4.21 4
173.6 6.91 6
173.7 7.45 7
173.8 5.92 5
173.9 5.29 5
174.0 6.63 6
174.1 7.45 7
175.4 5.15 5
175.5 5.21 5
175.6 6.43 6
175.7 8.42 8
175.8 9.37 9
175.9 9.13 9
176.0 8.99 8
176.1 9.42 9
176.2 9.32 9
176.3 8.08 8
176.4 6.65 6
176.5 5.76 5
176.8 4.66 4
176.9 7.21 7
177.0 9.09 9
177.1 7.92 7
177.7 4.17 4
177.8 6.63 6
177.9 9.24 9
178.0 9.33 9
178.1 7.83 7
178.2 7.19 7
178.3 7.38 7
178.6 6.08 6
178.7 7.83 7
178.8 9.06 9
178.9 8.53 8
179.3 7.68 7
179.4 8.31 8
179.5 9.23 9
179.6 9.33 9
179.7 7.97 7
180.5 5.08 5
180.6 6.11 6
180.7 7.68 7
180.8 8.47 8
180.9 7.37 7
182.3 4.94 4
182.4 5.68 5
182.5 8.01 8
182.6 9.21 9
182.7 7.89 7
182.8 6.67 6
182.9 7.98 7
183.0 10.32 10
183.1 10.73 10
183.2 9.42 9
183.3 8.84 8
183.4 9.4 9
183.5 8.65 8
183.8 5.05 5
183.9 7.63 7
184.0 8.68 8
184.1 7.99 7
184.2 6.81 6
184.3 5.15 5
184.5 2.78 2
184.6 5.35 5
184.7 8.49 8
184.8 9.17 9
184.9 8.26 8
185.0 8.46 8
185.1 9.38 9
185.2 8.31 8
190.8 4.13 4
190.9 6.4 6
191.0 9.54 9
191.1 10.5 10
191.2 8.14 8
191.9 6.66 6
192.0 8.16 8
192.1 8.8 8
192.2 8.68 8
192.3 8.72 8
192.4 8.59 8
192.5 7.72 7
192.9 7.26 7
193.0 7.99 7
193.1 9.45 9
193.2 9.93 9
193.5 5.79 5
193.6 9.93 9
193.7 12.53 12
193.8 11.09 11
193.9 8.25 8
194.0 7.23 7
194.1 7.26 7
194.4 4.17 4
194.5 6.56 6
194.6 8.39 8
194.7 7.55 7
194.8 5.55 5
196.1 5.53 5
196.2 6.98 6
196.3 8.27 8
196.4 8.46 8
196.5 8.45 8
196.6 8.9 8
196.7 8.88 8
196.8 7.49 7
196.9 5.5 5
199.5 5.53 5
199.6 6.56 6
199.7 7.24 7
199.8 7.23 7
199.9 7.2 7
200.0 7.17 7
200.1 6.44 6
200.7 5.83 5
200.8 6.99 6
200.9 8.59 8
201.0 8.43 8
201.1 6.49 6
201.4 6.38 6
201.5 6.63 6
201.6 7.48 7
201.7 9.84 9
201.8 11.53 11
201.9 10.02 10
202.0 6.71 6
202.1 5.11 5
203.7 6.78 6
203.8 8.34 8
203.9 9.84 9
204.0 9.63 9
204.1 7.38 7
204.2 4.8 4
205.1 2.18 2
205.2 6.0 5
205.3 8.21 8
205.4 7.85 7
205.5 7.0 6
205.6 6.24 6
205.9 4.46 4
206.0 7.47 7
206.1 10.07 10
206.2 10.7 10
206.3 9.83 9
206.4 8.53 8
206.7 5.65 5
206.8 7.55 7
206.9 9.86 9
207.0 10.18 10
207.1 8.51 8
207.2 6.91 6
208.1 3.51 3
208.2 5.99 5
208.3 8.81 8
208.4 10.22 10
208.5 9.5 9
208.6 6.94 6
208.7 3.8 3
208.9 2.61 2
209.0 4.96 4
209.1 6.72 6
209.2 7.03 7
209.3 7.06 7
209.4 7.14 7
210.1 5.77 5
210.2 8.19 8
210.3 10.46 10
210.4 9.23 9
211.6 7.17 7
211.7 7.2 7
211.8 7.56 7
211.9 8.71 8
212.0 8.91 8
212.1 6.61 6
212.3 3.73 3
212.4 6.82 6
212.5 9.02 9
212.6 7.94 7
213.6 5.18 5
213.7 7.09 7
213.8 8.38 8
213.9 8.15 8
214.0 8.51 8
214.1 10.29 10
214.2 11.09 11
214.3 9.65 9
215.1 5.83 5
215.2 7.02 7
215.3 8.39 8
215.4 8.85 8
215.5 7.81 7
215.6 6.35 6
215.7 5.9 5
215.8 5.77 5
216.0 2.99 2
216.1 4.01 4
216.2 7.88 7
216.3 10.77 10
216.4 9.89 9
216.5 7.18 7
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//
