MassBank Record: MSBNK-RIKEN_NPDepo-NGA02180
ACCESSION: MSBNK-RIKEN_NPDepo-NGA02180
RECORD_TITLE: Vanilloside; LC-ESI-QQQ; MS2; Frag=135.0V CID@25.0; [M+Na]+
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant, Glycosides, Benzaldehydes
CH$NAME: Vanilloside
CH$COMPOUND_CLASS: Carbohydrates
CH$FORMULA: C14H18O8
CH$EXACT_MASS: 314.2948
CH$SMILES: COc1cc(C=O)ccc1O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O
CH$IUPAC: InChI=1S/C14H18O8/c1-20-9-4-7(5-15)2-3-8(9)21-14-13(19)12(18)11(17)10(6-16)22-14/h2-5,10-14,16-19H,6H2,1H3/t10-,11+,12+,13-,14-/m1/s1
CH$LINK: CAS
494-08-6
CH$LINK: CHEMSPIDER
4954574
CH$LINK: INCHIKEY
LPRNQMUKVDHCFX-MBJXGIAVSA-N
CH$LINK: PUBCHEM
CID:5293141
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+Na]+
PK$SPLASH: splash10-00di-0950700000-401b64ab300ad45caf42
PK$NUM_PEAK: 1170
PK$PEAK: m/z int. rel.int.
102.4 2.51 2
102.5 3.95 3
102.6 4.82 4
102.7 5.36 5
102.8 5.56 5
102.9 5.01 5
103.0 3.91 3
103.1 3.25 3
103.2 3.42 3
103.3 3.72 3
103.4 3.55 3
103.5 3.4 3
103.6 3.77 3
103.7 4.21 4
103.8 4.02 4
103.9 3.67 3
104.0 3.89 3
104.1 4.47 4
104.2 4.82 4
104.3 5.01 5
104.4 5.17 5
104.5 4.81 4
104.6 3.79 3
104.7 2.99 2
104.8 3.12 3
104.9 3.64 3
105.0 3.81 3
105.1 3.85 3
105.2 4.2 4
105.3 4.59 4
105.4 4.38 4
105.5 3.62 3
105.6 3.13 3
105.7 3.43 3
105.8 4.01 4
105.9 4.07 4
106.0 3.6 3
106.1 3.3 3
106.2 3.52 3
106.3 3.86 3
106.4 3.97 3
106.5 4.08 4
106.6 4.24 4
106.7 3.85 3
106.8 2.6 2
106.9 1.46 1
107.0 1.6 1
107.1 2.69 2
107.2 3.63 3
107.3 4.07 4
107.4 4.49 4
107.5 5.01 5
107.6 5.43 5
107.7 5.76 5
107.8 5.87 5
107.9 5.28 5
108.0 4.06 4
108.1 3.11 3
108.2 3.17 3
108.3 3.99 3
108.4 4.82 4
108.5 5.28 5
108.6 5.46 5
108.7 5.42 5
108.8 4.9 4
108.9 3.89 3
109.0 3.14 3
109.1 3.64 3
109.2 5.13 5
109.3 6.15 6
109.4 5.77 5
109.5 4.77 4
109.6 4.21 4
109.7 3.95 3
109.8 3.44 3
109.9 3.0 2
110.0 3.1 3
110.1 3.26 3
110.2 2.98 2
110.3 2.75 2
110.4 3.17 3
110.5 3.89 3
110.6 4.17 4
110.7 4.21 4
110.8 4.68 4
110.9 5.48 5
111.0 5.7 5
111.1 4.99 4
111.2 4.2 4
111.3 4.05 4
111.4 4.09 4
111.5 3.67 3
111.6 3.17 3
111.7 3.29 3
111.8 4.0 3
111.9 4.79 4
112.0 5.41 5
112.1 5.74 5
112.2 5.5 5
112.3 4.79 4
112.4 4.26 4
112.5 4.43 4
112.6 4.98 4
112.7 5.18 5
112.8 4.84 4
112.9 4.56 4
113.0 4.56 4
113.1 4.36 4
113.2 3.65 3
113.3 3.05 3
113.4 3.17 3
113.5 3.5 3
113.6 3.21 3
113.7 2.52 2
113.8 2.36 2
113.9 2.98 2
114.0 3.69 3
114.1 3.98 3
114.2 3.87 3
114.3 3.58 3
114.4 3.36 3
114.5 3.56 3
114.6 4.17 4
114.7 4.66 4
114.8 4.68 4
114.9 4.61 4
115.0 4.75 4
115.1 4.8 4
115.2 4.53 4
115.3 4.31 4
115.4 4.65 4
115.5 5.42 5
115.6 6.0 5
115.7 5.81 5
115.8 5.12 5
115.9 4.69 4
116.0 4.7 4
116.1 4.52 4
116.2 3.97 3
116.3 3.81 3
116.4 4.31 4
116.5 4.61 4
116.6 4.07 4
116.7 3.48 3
116.8 3.79 3
116.9 4.72 4
117.0 5.31 5
117.1 5.31 5
117.2 5.12 5
117.3 5.02 5
117.4 4.88 4
117.5 4.45 4
117.6 3.7 3
117.7 3.03 3
117.8 3.06 3
117.9 4.06 4
118.0 5.58 5
118.1 6.68 6
118.2 6.57 6
118.3 5.31 5
143.6 2.03 2
143.7 3.76 3
143.8 5.48 5
143.9 5.81 5
144.0 4.76 4
144.1 3.65 3
144.2 3.52 3
144.3 4.11 4
144.4 4.54 4
144.5 4.52 4
144.6 4.28 4
144.7 3.93 3
144.8 3.49 3
144.9 3.23 3
145.0 3.46 3
145.1 3.8 3
145.2 3.7 3
145.3 3.33 3
145.4 3.23 3
145.5 3.53 3
145.6 3.93 3
145.7 4.43 4
145.8 5.15 5
145.9 5.51 5
146.0 4.94 4
146.1 3.82 3
146.2 3.25 3
146.3 3.52 3
146.4 4.06 4
146.5 4.34 4
146.6 4.45 4
146.7 4.65 4
146.8 4.99 4
146.9 5.38 5
147.0 5.51 5
147.1 5.14 5
147.2 4.33 4
147.3 3.61 3
147.4 3.44 3
147.5 3.74 3
147.6 3.9 3
147.7 3.71 3
147.8 3.74 3
147.9 4.38 4
148.0 4.84 4
148.1 4.09 4
148.2 2.57 2
148.3 2.0 1
148.4 2.96 2
148.5 4.26 4
148.6 4.81 4
148.7 4.99 4
148.8 5.49 5
148.9 5.9 5
149.0 5.58 5
149.1 5.03 5
149.2 5.0 4
149.3 5.18 5
149.4 4.73 4
149.5 3.76 3
149.6 3.05 3
149.7 2.93 2
149.8 3.14 3
149.9 3.71 3
150.0 4.82 4
150.1 5.99 5
150.2 6.24 6
150.3 5.46 5
150.4 4.47 4
150.5 3.98 3
150.6 3.71 3
150.7 3.14 3
150.8 2.39 2
150.9 2.45 2
151.0 3.78 3
151.1 5.5 5
151.2 6.15 6
151.3 5.48 5
151.4 4.36 4
151.5 3.49 3
151.6 3.08 3
151.7 3.42 3
151.8 4.39 4
151.9 4.92 4
152.0 4.39 4
152.1 3.65 3
152.2 3.7 3
152.3 4.11 4
152.4 4.07 4
152.5 3.78 3
152.6 3.95 3
152.7 4.59 4
152.8 4.95 4
152.9 4.79 4
153.0 4.63 4
153.1 4.83 4
153.2 4.94 4
153.3 4.52 4
153.4 4.03 4
153.5 4.11 4
153.6 4.42 4
153.7 4.3 4
153.8 4.04 4
153.9 4.4 4
154.0 5.02 5
154.1 4.83 4
154.2 4.02 4
154.3 3.92 3
154.4 4.75 4
154.5 4.95 4
174.4 2.85 2
174.5 4.36 4
174.6 13.71 13
174.7 34.67 34
174.8 58.37 58
174.9 66.28 66
175.0 50.22 50
175.1 23.31 23
175.2 4.76 4
184.6 2.26 2
184.7 4.52 4
184.8 6.52 6
184.9 6.58 6
185.0 5.56 5
185.1 5.16 5
185.2 5.34 5
185.3 4.98 4
185.4 4.08 4
185.5 3.63 3
185.6 3.92 3
185.7 4.11 4
185.8 3.8 3
185.9 3.44 3
186.0 3.33 3
186.1 3.26 3
186.2 3.26 3
186.3 3.7 3
186.4 4.45 4
186.5 4.65 4
186.6 4.1 4
186.7 3.67 3
186.8 3.93 3
186.9 4.17 4
187.0 3.69 3
187.1 3.18 3
187.2 3.52 3
187.3 4.22 4
187.4 4.16 4
187.5 3.68 3
187.6 4.0 3
187.7 5.04 5
187.8 5.43 5
187.9 4.93 4
188.0 4.73 4
188.1 5.36 5
188.2 5.71 5
188.3 5.05 5
188.4 4.31 4
188.5 4.58 4
188.6 5.29 5
188.7 5.45 5
188.8 5.18 5
188.9 5.15 5
189.0 5.17 5
189.1 4.58 4
189.2 3.73 3
189.3 3.59 3
189.4 4.02 4
189.5 4.07 4
189.6 3.58 3
189.7 3.43 3
189.8 4.04 4
189.9 4.72 4
190.0 4.94 4
190.1 5.08 5
190.2 5.33 5
190.3 5.07 5
190.4 4.07 4
190.5 3.29 3
190.6 3.73 3
190.7 4.91 4
190.8 5.69 5
190.9 5.72 5
191.0 5.58 5
191.1 5.7 5
191.2 5.79 5
191.3 5.55 5
191.4 5.07 5
191.5 4.65 4
191.6 4.35 4
191.7 4.19 4
191.8 4.51 4
191.9 5.28 5
192.0 5.69 5
192.1 5.08 5
192.2 4.14 4
192.3 4.04 4
192.4 4.76 4
192.5 5.17 5
192.6 4.91 4
192.7 4.68 4
192.8 4.75 4
192.9 4.47 4
193.0 3.67 3
193.1 3.33 3
193.2 3.99 3
193.3 4.82 4
193.4 4.91 4
193.5 4.48 4
193.6 4.3 4
193.7 4.32 4
193.8 4.09 4
193.9 3.67 3
194.0 3.62 3
194.1 4.2 4
194.2 4.89 4
194.3 5.16 5
194.4 5.09 5
194.5 4.87 4
194.6 4.39 4
194.7 3.81 3
194.8 3.98 3
194.9 5.17 5
195.0 6.23 6
195.1 5.97 5
195.2 4.92 4
195.3 4.57 4
195.4 5.07 5
195.5 5.16 5
195.6 4.31 4
195.7 3.54 3
195.8 3.57 3
195.9 3.86 3
196.0 3.87 3
196.1 3.98 3
196.2 4.38 4
196.3 4.52 4
196.4 4.24 4
196.5 4.22 4
196.6 4.86 4
196.7 5.31 5
196.8 4.73 4
196.9 3.68 3
197.0 3.49 3
197.1 4.35 4
197.2 5.02 5
197.3 4.74 4
197.4 4.3 4
197.5 4.68 4
197.6 5.38 5
197.7 5.44 5
197.8 5.02 5
197.9 4.89 4
198.0 5.03 5
198.1 4.75 4
198.2 3.97 3
198.3 3.27 3
198.4 3.01 3
198.5 3.21 3
198.6 3.96 3
198.7 5.1 5
198.8 5.75 5
198.9 5.18 5
199.0 4.07 4
199.1 3.83 3
199.2 4.65 4
199.3 5.33 5
199.4 5.11 5
199.5 4.42 4
199.6 3.85 3
199.7 3.47 3
199.8 3.36 3
199.9 3.83 3
200.0 4.69 4
200.1 4.99 4
200.2 4.33 4
200.3 3.64 3
200.4 4.07 4
200.5 5.2 5
200.6 5.69 5
200.7 5.2 5
200.8 4.64 4
200.9 4.46 4
201.0 4.01 4
201.1 2.9 2
201.2 2.12 2
201.3 2.66 2
201.4 3.99 3
201.5 4.63 4
201.6 4.2 4
201.7 3.7 3
201.8 3.9 3
201.9 4.28 4
202.0 4.24 4
202.1 4.1 4
202.2 4.15 4
202.3 4.1 4
202.4 3.65 3
202.5 3.16 3
202.6 3.08 3
202.7 3.36 3
202.8 3.68 3
202.9 3.93 3
203.0 4.11 4
203.1 4.09 4
203.2 3.83 3
203.3 3.58 3
203.4 3.55 3
203.5 3.59 3
203.6 3.47 3
203.7 3.34 3
203.8 3.65 3
203.9 4.29 4
204.0 4.63 4
204.1 4.42 4
204.2 4.06 4
204.3 4.02 4
204.4 4.1 4
204.5 4.2 4
204.6 4.61 4
204.7 5.31 5
204.8 5.41 5
204.9 4.5 4
205.0 3.54 3
205.1 3.59 3
205.2 4.32 4
205.3 4.82 4
205.4 4.85 4
205.5 4.53 4
205.6 3.82 3
205.7 2.86 2
205.8 2.31 2
205.9 2.68 2
206.0 3.71 3
206.1 4.67 4
206.2 5.06 5
206.3 4.74 4
206.4 3.86 3
206.5 2.97 2
206.6 2.65 2
206.7 2.94 2
206.8 3.5 3
206.9 4.15 4
207.0 4.74 4
207.1 5.01 5
207.2 4.82 4
207.3 4.32 4
207.4 3.79 3
207.5 3.56 3
207.6 4.0 3
207.7 4.85 4
207.8 5.23 5
207.9 4.78 4
208.0 4.41 4
208.1 4.88 4
208.2 5.55 5
208.3 5.24 5
208.4 4.16 4
208.5 3.53 3
208.6 3.66 3
208.7 3.73 3
208.8 3.55 3
208.9 4.02 4
209.0 5.31 5
209.1 6.09 6
209.2 5.41 5
209.3 3.97 3
209.4 3.11 3
209.5 3.25 3
209.6 3.82 3
209.7 4.25 4
209.8 4.28 4
209.9 3.87 3
210.0 3.29 3
210.1 3.08 3
210.2 3.57 3
210.3 4.31 4
210.4 4.39 4
210.5 3.8 3
210.6 3.53 3
210.7 4.07 4
210.8 4.53 4
210.9 4.23 4
211.0 3.8 3
211.1 4.04 4
211.2 4.53 4
211.3 4.72 4
211.4 4.79 4
211.5 4.96 4
211.6 4.6 4
211.7 3.39 3
211.8 2.31 2
211.9 2.57 2
212.0 3.8 3
212.1 4.52 4
212.2 4.2 4
212.3 3.86 3
212.4 4.4 4
212.5 5.16 5
212.6 4.94 4
212.7 4.08 4
212.8 3.99 3
212.9 4.86 4
213.0 5.43 5
213.1 5.03 5
213.2 4.4 4
213.3 4.39 4
213.4 4.74 4
213.5 4.96 4
213.6 4.98 4
213.7 4.68 4
213.8 4.04 4
213.9 3.62 3
214.0 3.94 3
214.1 4.51 4
214.2 4.52 4
214.3 4.24 4
214.4 4.53 4
214.5 5.29 5
214.6 5.41 5
214.7 4.47 4
214.8 3.35 3
214.9 2.98 2
215.0 3.24 3
215.1 3.56 3
215.2 3.93 3
215.3 4.65 4
215.4 5.38 5
215.5 5.15 5
215.6 3.93 3
215.7 2.97 2
215.8 3.27 3
215.9 4.15 4
216.0 4.45 4
216.1 4.38 4
216.2 4.7 4
216.3 5.04 5
216.4 4.44 4
216.5 3.32 3
216.6 2.89 2
216.7 3.14 3
216.8 3.13 3
216.9 2.84 2
217.0 3.33 3
217.1 4.66 4
217.2 5.63 5
217.3 5.45 5
217.4 4.63 4
217.5 3.76 3
217.6 2.88 2
217.7 2.23 2
217.8 2.49 2
217.9 3.66 3
218.0 4.87 4
218.1 5.46 5
218.2 5.75 5
218.3 6.14 6
218.4 6.23 6
218.5 5.47 5
218.6 4.36 4
218.7 4.04 4
218.8 4.75 4
218.9 5.5 5
219.0 5.38 5
219.1 4.74 4
219.2 4.33 4
219.3 4.19 4
219.4 3.94 3
219.5 3.86 3
219.6 4.48 4
219.7 5.29 5
219.8 5.02 5
219.9 3.65 3
220.0 2.56 2
220.1 2.63 2
220.2 3.15 3
220.3 3.22 3
220.4 3.01 3
220.5 3.08 3
220.6 3.43 3
220.7 3.76 3
220.8 4.0 3
220.9 4.29 4
221.0 4.53 4
221.1 4.51 4
221.2 4.26 4
221.3 4.13 4
221.4 4.26 4
221.5 4.25 4
221.6 3.9 3
221.7 3.93 3
221.8 4.72 4
221.9 5.23 5
222.0 4.5 4
222.1 3.51 3
222.2 3.74 3
222.3 4.72 4
222.4 4.82 4
222.5 3.98 3
222.6 3.71 3
222.7 4.48 4
222.8 5.13 5
222.9 4.87 4
223.0 4.45 4
223.1 4.75 4
223.2 5.31 5
223.3 5.2 5
223.4 4.38 4
223.5 3.41 3
223.6 2.69 2
223.7 2.47 2
223.8 2.92 2
223.9 3.76 3
224.0 4.26 4
224.1 4.16 4
224.2 3.98 3
224.3 4.18 4
224.4 4.53 4
224.5 4.58 4
224.6 4.5 4
224.7 4.72 4
224.8 5.32 5
224.9 5.74 5
225.0 5.47 5
225.1 4.81 4
225.2 4.37 4
225.3 4.36 4
225.4 4.57 4
225.5 4.95 4
225.6 5.4 5
225.7 5.51 5
225.8 5.11 5
225.9 4.81 4
226.0 4.99 4
226.1 5.25 5
226.2 4.94 4
226.3 4.28 4
226.4 3.97 3
226.5 4.07 4
226.6 3.87 3
226.7 3.1 3
226.8 2.55 2
226.9 3.1 3
227.0 4.39 4
227.1 5.21 5
227.2 5.03 5
227.3 4.39 4
227.4 3.84 3
227.5 3.49 3
227.6 3.62 3
227.7 4.48 4
227.8 5.39 5
227.9 5.27 5
228.0 4.29 4
228.1 3.82 3
228.2 4.31 4
228.3 4.84 4
228.4 4.76 4
228.5 4.6 4
228.6 4.91 4
228.7 5.24 5
228.8 5.11 5
228.9 4.89 4
229.0 4.95 4
229.1 4.83 4
229.2 4.12 4
229.3 3.52 3
229.4 4.06 4
229.5 5.18 5
229.6 5.48 5
229.7 4.92 4
229.8 4.9 4
229.9 5.66 5
230.0 5.55 5
336.3 3.22 3
336.4 6.21 6
336.5 11.32 11
336.6 14.78 14
336.7 13.93 13
336.8 10.69 10
336.9 8.53 8
337.0 7.89 7
437.8 2.78 2
437.9 3.85 3
438.0 4.72 4
438.1 5.49 5
438.2 5.75 5
438.3 5.19 5
438.4 4.31 4
438.5 3.68 3
438.6 3.06 3
438.7 2.17 2
438.8 1.51 1
438.9 1.97 1
439.0 3.27 3
439.1 4.09 4
439.2 3.85 3
439.3 3.29 3
439.4 3.28 3
439.5 3.82 3
439.6 4.47 4
439.7 4.88 4
439.8 4.79 4
439.9 4.04 4
440.0 3.13 3
440.1 3.0 2
440.2 4.04 4
440.3 5.25 5
440.4 5.27 5
440.5 4.1 4
440.6 3.27 3
440.7 3.84 3
440.8 4.97 4
440.9 5.1 5
441.0 4.2 4
441.1 3.69 3
441.2 4.28 4
441.3 5.07 5
441.4 5.21 5
441.5 5.07 5
441.6 5.1 5
441.7 4.98 4
441.8 4.69 4
441.9 4.83 4
442.0 5.17 5
442.1 4.6 4
442.2 3.16 3
442.3 2.25 2
442.4 2.49 2
442.5 2.85 2
442.6 2.75 2
442.7 3.06 3
442.8 4.41 4
442.9 5.72 5
443.0 5.74 5
443.1 4.76 4
443.2 4.11 4
443.3 4.37 4
443.4 4.92 4
443.5 5.04 5
443.6 4.71 4
443.7 4.32 4
443.8 4.14 4
443.9 4.15 4
444.0 4.22 4
444.1 4.15 4
444.2 3.92 3
444.3 3.86 3
444.4 4.16 4
444.5 4.39 4
444.6 3.93 3
444.7 2.9 2
444.8 2.27 2
444.9 2.61 2
445.0 3.41 3
445.1 3.93 3
445.2 4.04 4
445.3 3.99 3
445.4 3.86 3
445.5 3.72 3
445.6 3.73 3
445.7 4.01 4
445.8 4.23 4
445.9 3.96 3
446.0 3.48 3
446.1 3.69 3
446.2 4.72 4
446.3 5.33 5
446.4 4.68 4
446.5 3.6 3
446.6 3.4 3
446.7 4.04 4
446.8 4.47 4
446.9 4.4 4
447.0 4.48 4
447.1 5.03 5
447.2 5.48 5
447.3 5.31 5
447.4 4.65 4
447.5 3.87 3
447.6 3.01 3
447.7 2.35 2
447.8 2.73 2
447.9 4.38 4
448.0 6.01 6
448.1 6.09 6
448.2 4.91 4
448.3 4.03 4
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448.6 3.92 3
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448.8 4.26 4
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449.1 3.66 3
449.2 4.16 4
449.3 4.61 4
449.4 4.17 4
449.5 3.41 3
449.6 3.3 3
449.7 3.59 3
449.8 3.72 3
449.9 4.24 4
450.0 5.56 5
450.1 6.42 6
450.2 5.43 5
450.3 3.66 3
450.4 3.36 3
450.5 4.78 4
450.6 5.93 5
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450.8 5.01 5
450.9 5.15 5
451.0 5.52 5
451.1 5.07 5
451.2 4.04 4
451.3 3.33 3
451.4 3.06 3
451.5 2.95 2
451.6 3.18 3
451.7 3.91 3
451.8 4.51 4
451.9 4.3 4
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452.1 3.03 3
452.2 3.37 3
452.3 4.0 3
452.4 4.22 4
452.5 4.13 4
452.6 4.12 4
452.7 4.08 4
452.8 3.81 3
452.9 3.66 3
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453.1 4.33 4
453.2 4.4 4
453.3 4.3 4
453.4 4.4 4
453.5 4.53 4
453.6 4.45 4
453.7 4.39 4
453.8 4.64 4
453.9 4.81 4
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454.2 3.23 3
454.3 3.84 3
454.4 4.57 4
454.5 4.7 4
454.6 4.61 4
454.7 4.88 4
454.8 5.1 5
454.9 4.53 4
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455.1 3.23 3
455.2 3.7 3
455.3 4.02 4
455.4 3.74 3
455.5 3.45 3
455.6 3.74 3
455.7 4.33 4
455.8 4.68 4
455.9 4.69 4
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456.4 4.62 4
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456.6 4.88 4
456.7 4.61 4
456.8 4.24 4
456.9 4.12 4
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457.3 4.92 4
457.4 5.13 5
457.5 4.37 4
457.6 3.51 3
457.7 3.72 3
457.8 4.54 4
457.9 4.72 4
458.0 4.1 4
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458.2 3.39 3
458.3 3.08 3
458.4 2.66 2
458.5 2.9 2
458.6 4.13 4
458.7 5.41 5
458.8 5.69 5
458.9 5.05 5
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459.5 4.42 4
459.6 5.09 5
459.7 5.28 5
459.8 5.11 5
459.9 4.76 4
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460.7 4.86 4
460.8 5.77 5
460.9 5.7 5
461.0 4.84 4
461.1 4.07 4
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461.4 3.83 3
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461.6 5.54 5
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461.8 4.82 4
461.9 4.03 4
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462.3 5.18 5
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462.5 5.39 5
462.6 5.42 5
462.7 5.18 5
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462.9 5.1 5
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463.5 5.13 5
463.6 5.02 5
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463.8 5.06 5
463.9 4.71 4
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464.3 4.81 4
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464.5 3.06 3
464.6 2.85 2
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464.8 3.19 3
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465.0 5.19 5
465.1 5.78 5
465.2 5.27 5
465.3 4.39 4
465.4 4.01 4
465.5 4.08 4
465.6 4.15 4
465.7 4.28 4
465.8 4.64 4
465.9 4.84 4
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466.1 3.92 3
466.2 4.26 4
466.3 5.19 5
466.4 5.38 5
466.5 4.43 4
466.6 3.52 3
466.7 3.73 3
466.8 4.51 4
466.9 4.83 4
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467.1 5.13 5
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467.3 5.58 5
467.4 5.0 4
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467.6 4.78 4
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467.8 3.58 3
467.9 2.88 2
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468.1 4.47 4
468.2 5.35 5
468.3 5.29 5
468.4 4.7 4
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468.6 4.44 4
468.7 4.89 4
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469.2 4.29 4
469.3 5.04 5
469.4 5.15 5
469.5 4.46 4
469.6 3.76 3
469.7 3.71 3
469.8 4.13 4
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470.3 3.79 3
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470.5 4.66 4
470.6 5.86 5
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470.8 5.39 5
470.9 4.66 4
471.0 4.84 4
471.1 5.32 5
471.2 5.09 5
471.3 4.29 4
471.4 3.78 3
471.5 3.87 3
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471.7 4.2 4
471.8 4.51 4
471.9 4.7 4
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472.1 3.53 3
472.2 3.07 3
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472.4 3.06 3
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472.6 4.23 4
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472.8 3.95 3
472.9 3.07 3
473.0 3.41 3
473.1 4.89 4
473.2 5.87 5
473.3 5.3 5
473.4 4.07 4
473.5 3.49 3
473.6 3.69 3
473.7 4.02 4
473.8 4.28 4
473.9 4.74 4
474.0 5.12 5
474.1 5.02 5
474.2 4.68 4
474.3 4.69 4
474.4 4.91 4
474.5 4.55 4
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474.8 3.55 3
474.9 4.29 4
475.0 4.43 4
475.1 4.24 4
475.2 4.38 4
475.3 4.66 4
475.4 4.41 4
475.5 3.84 3
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475.7 4.33 4
475.8 4.81 4
475.9 4.83 4
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476.1 4.55 4
476.2 4.45 4
476.3 4.25 4
476.4 4.14 4
476.5 4.32 4
476.6 4.52 4
476.7 4.28 4
476.8 3.64 3
476.9 3.21 3
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477.1 3.42 3
477.2 3.7 3
477.3 4.44 4
477.4 5.45 5
477.5 5.81 5
477.6 5.28 5
477.7 4.8 4
477.8 5.03 5
477.9 5.45 5
478.0 5.27 5
478.1 4.69 4
478.2 4.41 4
478.3 4.38 4
478.4 4.03 4
478.5 3.39 3
478.6 3.15 3
478.7 3.52 3
478.8 3.65 3
478.9 2.89 2
479.0 2.04 2
479.1 2.31 2
479.2 3.6 3
479.3 4.76 4
479.4 5.08 5
479.5 4.9 4
479.6 4.56 4
479.7 4.29 4
479.8 4.21 4
479.9 4.13 4
480.0 3.67 3
480.1 3.18 3
480.2 3.6 3
480.3 5.2 5
480.4 6.54 6
480.5 6.08 6
//
