ACCESSION: MSBNK-RIKEN_NPDepo-NGA02746
RECORD_TITLE: 10-hydroxycamptothecin; LC-ESI-QQQ; MS2; Frag=135.0V CID@10.0; [M+H]+
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: SubCategory_DNP: : Alkaloids derived from anthranilic acid, Quinoline alkaloids

CH$NAME: 10-hydroxycamptothecin
CH$COMPOUND_CLASS: Alkaloids
CH$FORMULA: C₂₀H₁₆N₂O₅
CH$EXACT_MASS: 364.3609
CH$SMILES: CCC1(O)C(=O)OCc2c1cc1n(c2=O)Cc2cc3cc(O)ccc3nc2-1
CH$IUPAC: InChI=1S/C20H16N2O5/c1-2-20(26)14-7-16-17-11(5-10-6-12(23)3-4-15(10)21-17)8-22(16)18(24)13(14)9-27-19(20)25/h3-7,23,26H,2,8-9H2,1H3
CH$LINK: CAS 19685-09-7
CH$LINK: CHEMSPIDER 87754 3534982 19979630
CH$LINK: INCHIKEY HAWSQZCWOQZXHI-UHFFFAOYSA-N
CH$LINK: PUBCHEM CID:4330531

AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE

MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+

PK$SPLASH: splash10-014i-0009000000-05cf33542d9301917f2a
PK$NUM_PEAK: 24
PK$PEAK: m/z int. rel.int.
  320.7 1.98 1
  320.8 3.08 3
  320.9 4.35 4
  321.0 5.56 5
  321.1 6.53 6
  321.2 7.13 7
  321.3 6.96 6
  321.4 5.59 5
  321.5 3.26 3
  364.3 0.94 0
  364.4 3.18 3
  364.5 7.5 7
  364.6 14.88 14
  364.7 27.14 27
  364.8 45.34 45
  364.9 67.02 66
  365.0 86.32 86
  365.1 98.02 97
  365.2 100.0 99
  365.3 90.93 90
  365.4 69.73 69
  365.5 40.41 40
  365.6 13.62 13
  365.7 0.0 0
//