MassBank Record: MSBNK-RIKEN_NPDepo-NGA03570
ACCESSION: MSBNK-RIKEN_NPDepo-NGA03570
RECORD_TITLE: Kokanidin; LC-ESI-QQQ; MS2; Frag=135.0V CID@15.0; [M+HCOO]-
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant, Coumarins, Coumarin terpenoids
CH$NAME: Kokanidin
CH$COMPOUND_CLASS: Benzopyranoids
CH$FORMULA: C26H34O6
CH$EXACT_MASS: 442.5573
CH$SMILES: CC(=O)OC1CC[C@]2(C)C(CC[C@@](C)(O)[C@H]2COc2ccc3ccc(=O)oc3c2)C1(C)C
CH$IUPAC: InChI=1S/C26H34O6/c1-16(27)31-22-11-12-25(4)20(24(22,2)3)10-13-26(5,29)21(25)15-30-18-8-6-17-7-9-23(28)32-19(17)14-18/h6-9,14,20-22,29H,10-13,15H2,1-5H3/t20?,21-,22?,25+,26+/m0/s1
CH$LINK: INCHIKEY
RIPKCRCUFJSKKD-FBQVDBQASA-N
CH$LINK: PUBCHEM
CID:126961508
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+HCOO]-
PK$SPLASH: splash10-0f6x-4889880000-1f3c4cd388761b790ff1
PK$NUM_PEAK: 4280
PK$PEAK: m/z int. rel.int.
50.8 7.59 7
50.9 14.59 14
51.0 19.82 19
51.1 19.18 19
51.2 13.52 13
51.4 9.4 9
51.5 16.45 16
51.6 23.09 23
51.7 23.0 22
51.8 16.19 16
52.0 6.31 6
52.1 11.1 11
52.2 18.59 18
52.3 21.89 21
52.4 17.79 17
52.5 10.06 10
52.7 8.51 8
52.8 14.7 14
52.9 18.59 18
53.0 17.39 17
53.3 12.18 12
53.4 18.14 18
53.5 22.76 22
53.6 21.18 21
53.7 13.76 13
53.9 4.52 4
54.0 9.45 9
54.1 16.68 16
54.2 20.57 20
54.3 18.17 18
54.4 11.4 11
54.6 7.52 7
54.7 15.2 15
54.8 22.24 22
54.9 22.1 22
55.0 14.96 14
55.2 5.04 5
55.3 9.61 9
55.4 16.61 16
55.5 20.76 20
55.6 19.18 19
55.7 13.67 13
55.9 9.38 9
56.0 13.76 13
56.1 18.1 18
56.2 18.4 18
56.3 14.44 14
56.5 10.77 10
56.6 16.56 16
56.7 22.88 22
56.8 24.39 24
56.9 20.36 20
57.1 14.47 14
57.2 18.5 18
57.3 23.04 23
57.4 23.09 23
57.5 17.84 17
57.6 11.17 11
57.8 9.5 9
57.9 13.85 13
58.0 16.97 16
58.1 16.38 16
58.4 12.7 12
58.5 18.21 18
58.6 23.26 23
58.7 23.8 23
58.8 18.76 18
58.9 11.4 11
59.1 9.28 9
59.2 15.27 15
59.3 19.7 19
59.4 18.83 18
59.5 13.88 13
59.7 9.28 9
59.8 13.95 13
59.9 19.98 19
60.0 22.5 22
60.1 19.02 19
60.2 11.97 11
60.4 7.23 7
60.5 11.9 11
60.6 16.23 16
60.7 16.47 16
60.8 12.82 12
61.0 9.59 9
61.1 13.57 13
61.2 17.01 16
61.3 16.21 16
61.4 11.29 11
61.6 6.01 6
61.7 11.26 11
61.8 17.65 17
61.9 19.11 19
62.0 13.69 13
62.3 6.67 6
62.4 14.33 14
62.5 18.64 18
62.6 16.49 16
62.7 10.67 10
62.9 7.99 7
63.0 14.18 14
63.1 20.45 20
63.2 21.7 21
63.3 16.94 16
63.4 10.23 10
63.6 7.94 7
63.7 13.17 13
63.8 18.05 18
63.9 18.36 18
64.0 13.69 13
64.2 9.24 9
64.3 14.92 14
64.4 20.83 20
64.5 21.61 21
64.6 16.54 16
64.8 9.05 9
64.9 14.21 14
65.0 21.09 21
65.1 23.33 23
65.2 19.09 19
65.3 12.09 12
65.5 10.06 10
65.6 16.02 16
65.7 20.9 20
65.8 20.08 20
65.9 13.69 13
66.1 6.72 6
66.2 12.98 12
66.3 19.77 19
66.4 20.12 20
66.5 13.36 13
66.7 4.36 4
66.8 10.08 10
66.9 17.7 17
67.0 20.64 20
67.1 16.75 16
67.4 9.68 9
67.5 16.45 16
67.6 20.99 20
67.7 20.15 20
67.8 15.01 14
68.0 9.43 9
68.1 14.59 14
68.2 20.69 20
68.3 21.47 21
68.4 15.46 15
68.6 6.27 6
68.7 11.31 11
68.8 18.8 18
68.9 23.09 23
69.0 21.39 21
69.1 15.17 15
69.3 9.07 9
69.4 15.62 15
69.5 23.77 23
69.6 26.3 26
69.7 20.71 20
69.8 11.78 11
70.0 8.6 8
70.1 14.33 14
70.2 17.67 17
70.3 15.13 15
70.5 6.55 6
70.6 11.52 11
70.7 21.39 21
70.8 28.13 28
70.9 25.78 25
71.0 16.26 16
71.2 6.81 6
71.3 13.45 13
71.4 21.61 21
71.5 25.0 24
71.6 21.42 21
71.7 13.88 13
71.9 11.33 11
72.0 19.09 19
72.1 24.67 24
72.2 22.48 22
72.3 14.16 14
72.5 7.54 7
72.6 14.7 14
72.7 21.87 21
72.8 23.07 23
72.9 18.03 18
73.1 9.31 9
73.2 12.96 12
73.3 19.37 19
73.4 22.5 22
73.5 18.69 18
73.6 9.99 9
73.8 3.56 3
73.9 10.82 10
74.0 18.66 18
74.1 20.9 20
74.2 16.23 16
74.5 9.59 9
74.6 17.06 17
74.7 21.77 21
74.8 19.42 19
74.9 12.25 12
75.1 9.92 9
75.2 17.13 17
75.3 21.96 21
75.4 19.58 19
75.5 11.88 11
75.7 5.35 5
75.8 11.33 11
75.9 18.12 18
76.0 20.48 20
76.1 16.78 16
76.3 7.82 7
76.4 11.97 11
76.5 20.05 20
76.6 24.67 24
76.7 21.28 21
76.8 12.98 12
77.0 10.13 10
77.1 17.79 17
77.2 23.75 23
77.3 22.69 22
77.4 14.89 14
77.6 3.51 3
77.7 9.28 9
77.8 18.36 18
77.9 22.57 22
78.0 18.64 18
78.1 11.12 11
78.3 9.31 9
78.4 14.56 14
78.5 18.52 18
78.6 18.92 18
78.7 15.76 15
78.9 9.66 9
79.0 12.87 12
79.1 18.73 18
79.2 21.91 21
79.3 19.51 19
79.5 12.91 12
79.6 17.11 17
79.7 23.02 22
79.8 24.1 24
79.9 18.52 18
80.1 9.47 9
80.2 14.42 14
80.3 21.94 21
80.4 26.18 26
80.5 24.58 24
80.6 18.85 18
81.5 7.05 7
81.6 12.37 12
81.7 16.59 16
81.8 17.11 17
82.1 13.81 13
82.2 17.44 17
82.3 20.55 20
82.4 19.6 19
82.5 14.11 14
82.7 6.53 6
82.8 11.24 11
82.9 18.36 18
83.0 22.36 22
83.1 20.1 20
83.2 13.15 13
83.4 7.05 7
83.5 13.22 13
83.6 19.89 19
83.7 21.04 21
83.8 16.19 16
84.0 8.6 8
84.1 12.54 12
84.2 18.03 18
84.3 19.7 19
84.4 16.02 16
84.6 8.29 8
84.7 11.78 11
84.8 17.72 17
84.9 20.33 20
85.0 16.64 16
85.3 9.38 9
85.4 16.45 16
85.5 21.14 21
85.6 19.18 19
85.7 12.18 12
85.9 6.31 6
86.0 12.16 12
86.1 18.59 18
86.2 20.22 20
86.3 15.46 15
86.6 7.05 7
86.7 15.5 15
86.8 22.71 22
86.9 23.59 23
87.0 18.45 18
87.1 12.04 12
87.3 10.53 10
87.4 14.56 14
87.5 17.7 17
87.6 17.74 17
87.7 14.87 14
87.9 11.9 11
88.0 15.53 15
88.1 19.34 19
88.2 19.13 19
88.3 14.66 14
88.5 10.25 10
88.6 14.8 14
88.7 19.25 19
88.8 18.54 18
88.9 12.21 12
89.1 4.43 4
89.2 11.12 11
89.3 20.52 20
89.4 24.74 24
89.5 19.65 19
89.6 9.21 9
89.8 5.87 5
89.9 15.74 15
90.0 23.3 23
90.1 22.24 22
90.2 14.33 14
90.4 7.3 7
90.5 14.61 14
90.6 22.31 22
90.7 23.59 23
90.8 17.79 17
91.0 8.13 8
91.1 12.84 12
91.2 20.43 20
91.3 24.03 24
91.4 19.93 19
91.5 10.98 10
91.7 4.45 4
91.8 10.44 10
91.9 17.11 17
92.0 19.72 19
92.1 17.22 17
92.3 11.5 11
92.4 14.54 14
92.5 18.69 18
92.6 19.82 19
92.7 16.68 16
92.8 11.33 11
93.0 9.45 9
93.1 15.5 15
93.2 21.04 21
93.3 21.25 21
93.4 16.19 16
93.6 10.82 10
93.7 16.14 16
93.8 22.57 22
93.9 24.25 24
94.0 18.83 18
94.1 9.85 9
94.3 6.9 6
94.4 14.23 14
94.5 19.27 19
94.6 17.93 17
94.9 12.37 12
95.0 17.7 17
95.1 20.66 20
95.2 18.4 18
95.3 12.58 12
95.5 7.94 7
95.6 13.6 13
95.7 20.81 20
95.8 24.25 24
95.9 21.44 21
96.0 14.99 14
96.2 11.38 11
96.3 16.61 16
96.4 20.69 20
96.5 19.11 19
96.6 12.61 12
96.8 5.84 5
96.9 10.7 10
97.0 17.15 17
97.1 20.66 20
97.2 18.71 18
97.3 12.42 12
97.5 6.13 6
97.6 11.78 11
97.7 18.47 18
97.8 19.86 19
97.9 14.56 14
98.1 6.79 6
98.2 12.72 12
98.3 19.77 19
98.4 21.56 21
98.5 17.62 17
98.6 12.61 12
99.3 9.5 9
99.4 12.49 12
99.5 17.72 17
99.6 21.96 21
99.7 21.42 21
99.8 15.81 15
100.0 9.9 9
100.1 15.25 15
100.2 20.9 20
100.3 21.39 21
100.4 16.09 16
100.5 8.98 8
100.7 6.74 6
100.8 12.46 12
100.9 17.55 17
101.0 17.65 17
101.1 12.51 12
101.3 5.28 5
101.4 8.88 8
101.5 13.55 13
101.6 15.06 15
101.7 12.54 12
101.9 7.42 7
102.0 10.7 10
102.1 16.33 16
102.2 19.11 19
102.3 15.81 15
102.5 6.46 6
102.6 11.0 10
102.7 19.46 19
102.8 24.58 24
102.9 22.29 22
103.0 15.06 15
103.2 7.35 7
103.3 11.45 11
103.4 16.94 16
103.5 19.18 19
103.6 16.66 16
103.8 11.52 11
103.9 14.59 14
104.0 18.85 18
104.1 20.0 19
104.2 16.68 16
104.4 9.61 9
104.5 12.94 12
104.6 19.25 19
104.7 23.54 23
104.8 22.2 22
104.9 15.9 15
105.0 9.1 9
105.2 8.51 8
105.3 13.6 13
105.4 17.25 17
105.5 16.52 16
105.6 12.39 12
105.8 10.2 10
105.9 15.15 15
106.0 20.26 20
106.1 21.58 21
106.2 17.74 17
106.3 11.29 11
106.5 9.45 9
106.6 13.74 13
106.7 15.88 15
106.8 14.82 14
107.0 12.51 12
107.1 15.15 15
107.2 20.17 20
107.3 23.82 23
107.4 22.01 21
107.5 14.84 14
107.7 6.29 6
107.8 11.29 11
107.9 17.81 17
108.0 19.49 19
108.1 13.76 13
108.3 3.02 3
108.4 9.28 9
108.5 19.04 19
108.6 23.96 23
108.7 20.03 20
108.8 10.63 10
109.0 3.82 3
109.1 10.65 10
109.2 17.55 17
109.3 19.3 19
109.4 15.72 15
109.6 9.24 9
109.7 13.85 13
109.8 21.65 21
109.9 26.01 25
110.0 22.83 22
110.1 14.99 14
110.3 11.43 11
110.4 18.64 18
110.5 24.55 24
110.6 23.16 23
110.7 14.63 14
110.9 4.41 4
111.0 10.74 10
111.1 18.57 18
111.2 21.23 21
111.3 17.62 17
111.5 10.16 10
111.6 13.83 13
111.7 19.53 19
111.8 21.37 21
111.9 17.08 17
112.8 4.74 4
112.9 11.57 11
113.0 19.11 19
113.1 20.97 20
113.2 15.72 15
113.4 6.22 6
113.5 11.78 11
113.6 20.29 20
113.7 23.89 23
113.8 19.2 19
113.9 10.41 10
114.1 7.78 7
114.2 16.0 15
114.3 23.02 22
114.4 22.97 22
114.5 16.31 16
114.7 7.19 7
114.8 11.78 11
114.9 18.24 18
115.0 20.62 20
115.1 16.52 16
115.2 8.53 8
115.4 3.42 3
115.5 10.72 10
115.6 18.76 18
115.7 21.35 21
115.8 16.75 16
115.9 9.19 9
116.1 7.87 7
116.2 14.23 14
116.3 17.18 17
116.4 13.03 13
116.7 5.33 5
116.8 12.16 12
116.9 16.52 16
117.0 15.17 15
117.3 9.45 9
117.4 15.1 15
117.5 19.46 19
117.6 18.94 18
117.7 13.31 13
117.9 3.35 3
118.0 7.33 7
118.1 14.94 14
118.2 20.08 20
118.3 19.02 19
118.4 12.96 12
118.6 7.85 7
118.7 14.63 14
118.8 20.9 20
118.9 20.48 20
119.0 14.63 14
119.2 9.66 9
119.3 14.07 14
119.4 18.76 18
119.5 19.2 19
119.6 14.09 14
119.8 6.46 6
119.9 11.31 11
120.0 17.48 17
120.1 19.6 19
120.2 16.12 16
120.3 9.99 9
120.5 7.85 7
120.6 13.38 13
120.7 17.58 17
120.8 16.94 16
120.9 12.91 12
121.1 10.86 10
121.2 15.79 15
121.3 20.66 20
121.4 21.37 21
121.5 16.94 16
121.8 10.58 10
121.9 16.87 16
122.0 21.25 21
122.1 20.0 19
122.2 13.69 13
122.4 5.89 5
122.5 11.12 11
122.6 18.21 18
122.7 20.57 20
122.8 16.07 16
123.1 8.72 8
123.2 15.55 15
123.3 20.48 20
123.4 19.77 19
123.5 14.42 14
123.7 8.15 8
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123.9 17.11 17
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124.1 14.99 14
124.3 9.52 9
124.4 13.52 13
124.5 19.49 19
124.6 22.17 22
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124.8 11.07 11
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125.1 13.12 13
125.2 16.97 16
125.3 15.5 15
125.6 10.16 10
125.7 15.88 15
125.8 21.07 21
125.9 21.8 21
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126.3 9.99 9
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126.5 24.65 24
126.6 26.37 26
126.7 20.57 20
127.5 6.46 6
127.6 13.67 13
127.7 21.56 21
127.8 23.16 23
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128.2 8.13 8
128.3 15.62 15
128.4 19.72 19
128.5 17.39 17
128.6 10.65 10
128.8 3.91 3
128.9 9.26 9
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129.2 15.25 15
130.1 7.35 7
130.2 12.75 12
130.3 17.55 17
130.4 17.48 17
130.5 12.23 12
130.7 5.25 5
130.8 10.49 10
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131.0 21.75 21
131.1 19.49 19
131.2 13.97 13
131.4 11.73 11
131.5 16.28 16
131.6 19.98 19
131.7 19.37 19
131.8 14.26 14
132.0 7.23 7
132.1 13.12 13
132.2 21.84 21
132.3 26.01 25
132.4 21.72 21
132.5 12.61 12
132.7 9.0 8
132.8 16.94 16
132.9 22.48 22
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133.3 9.35 9
133.4 16.71 16
133.5 23.54 23
133.6 24.69 24
133.7 19.37 19
133.8 11.71 11
134.0 10.79 10
134.1 17.34 17
134.2 21.77 21
134.3 21.37 21
134.4 17.77 17
134.6 14.26 14
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134.8 18.73 18
134.9 16.94 16
135.2 10.2 10
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135.8 6.5 6
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136.6 15.9 15
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137.3 15.2 15
137.4 18.47 18
137.5 17.25 17
137.8 11.19 11
137.9 18.03 18
138.0 22.38 22
138.1 19.75 19
138.2 12.56 12
138.4 7.75 7
138.5 13.12 13
138.6 19.11 19
138.7 21.25 21
138.8 18.17 18
138.9 12.46 12
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139.2 12.21 12
139.3 14.23 14
139.4 12.61 12
139.5 8.11 8
139.7 4.64 4
139.8 9.9 9
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140.0 19.32 19
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140.9 5.33 5
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141.3 26.56 26
141.4 18.26 18
141.6 9.8 9
141.7 15.69 15
141.8 21.04 21
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142.3 15.41 15
142.4 21.09 21
142.5 23.59 23
142.6 20.76 20
142.7 14.82 14
142.9 11.9 11
143.0 15.83 15
143.1 18.36 18
143.2 16.68 16
143.3 11.12 11
143.5 1.81 1
143.6 5.94 5
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143.8 20.26 20
143.9 18.03 18
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144.3 13.95 13
144.4 18.21 18
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144.9 19.53 19
145.0 25.52 25
145.1 24.41 24
145.2 16.78 16
145.3 8.41 8
145.5 7.23 7
145.6 12.84 12
145.7 17.01 16
145.8 16.12 16
145.9 10.96 10
146.1 8.41 8
146.2 15.32 15
146.3 21.94 21
146.4 23.14 23
146.5 18.59 18
146.6 12.56 12
146.8 10.79 10
146.9 13.41 13
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147.1 13.03 13
147.3 8.39 8
147.4 10.53 10
147.5 15.83 15
147.6 20.29 20
147.7 19.89 19
147.8 14.89 14
148.0 9.47 9
148.1 14.26 14
148.2 19.44 19
148.3 20.12 20
148.4 16.0 15
148.6 9.35 9
148.7 13.03 13
148.8 19.44 19
148.9 23.21 23
149.0 20.71 20
149.1 13.97 13
149.3 9.87 9
149.4 15.74 15
149.5 21.11 21
149.6 21.39 21
149.7 16.99 16
150.5 8.79 8
150.6 10.93 10
150.7 15.67 15
150.8 19.04 19
150.9 18.0 17
151.0 13.55 13
151.2 10.11 10
151.3 14.82 14
151.4 19.18 19
151.5 18.07 18
151.6 11.43 11
151.8 5.3 5
151.9 12.32 12
152.0 20.76 20
152.1 23.96 23
152.2 19.63 19
152.3 11.38 11
152.5 7.78 7
152.6 13.81 13
152.7 18.66 18
152.8 18.97 18
152.9 15.36 15
153.2 10.01 9
153.3 15.32 15
153.4 19.91 19
153.5 19.09 19
153.6 13.01 12
153.8 6.72 6
153.9 12.18 12
154.0 18.5 18
154.1 20.24 20
154.2 15.83 15
154.5 8.67 8
154.6 14.99 14
154.7 17.98 17
154.8 14.94 14
155.1 9.92 9
155.2 15.53 15
155.3 18.99 18
155.4 17.74 17
155.5 12.89 12
155.7 8.18 8
155.8 13.15 13
155.9 19.72 19
156.0 22.13 22
156.1 17.48 17
156.4 8.44 8
156.5 18.03 18
156.6 24.65 24
156.7 22.46 22
156.8 13.83 13
157.0 6.31 6
157.1 12.42 12
157.2 19.09 19
157.3 20.81 20
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//
