AICAR monophosphate, ZMP, Z-nucleotide, 5'-Phospho-ribosyl-5-amino-4-imidazole carboxamide, 1-(5'-Phosphoribosyl)-5-amino-4-imidazolecarboxamide, 5'-Phosphoribosyl-5-amino-4-imidazolecarboxamide, AICAR, AICAriboside 5'-monophosphate, [(2R,3S,4R,5R)-5-(5-amino-4-carbamoylimidazol-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl dihydrogen phosphate, 5-Aminoimidazole-4-carboxamide-1-beta-D-ribofuranosyl 5'-monophosphate, N1-(beta-D-5'-Phosphoribofuranosyl)-5-aminoimidazole-4-carboxamide, 5-Phosphoribosyl-4-carbamoyl-5-aminoimidazole; LC-ESI-QTOF; MS2

Mass Spectrum

Chemical Structure

ACCESSION: MSBNK-RIKEN_ReSpect-PT106620
RECORD_TITLE: AICAR monophosphate, ZMP, Z-nucleotide, 5'-Phospho-ribosyl-5-amino-4-imidazole carboxamide, 1-(5'-Phosphoribosyl)-5-amino-4-imidazolecarboxamide, 5'-Phosphoribosyl-5-amino-4-imidazolecarboxamide, AICAR, AICAriboside 5'-monophosphate, [(2R,3S,4R,5R)-5-(5-amino-4-carbamoylimidazol-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl dihydrogen phosphate, 5-Aminoimidazole-4-carboxamide-1-beta-D-ribofuranosyl 5'-monophosphate, N1-(beta-D-5'-Phosphoribofuranosyl)-5-aminoimidazole-4-carboxamide, 5-Phosphoribosyl-4-carbamoyl-5-aminoimidazole; LC-ESI-QTOF; MS2
DATE: 2008.07.28
AUTHORS: Matsuda F, Suzuki M, Sawada Y, Plant Science Center, RIKEN.
LICENSE: CC BY-NC
COPYRIGHT: Copyright(C) 2009 Plant Science Center, RIKEN
COMMENT: Build 1 2009/06/24
COMMENT: Acquisition and generation of the data is financially supported in part by CREST/JST.

CH$NAME: AICAR monophosphate
CH$NAME: ZMP
CH$NAME: Z-nucleotide
CH$NAME: 5'-Phospho-ribosyl-5-amino-4-imidazole carboxamide
CH$NAME: 1-(5'-Phosphoribosyl)-5-amino-4-imidazolecarboxamide
CH$NAME: 5'-Phosphoribosyl-5-amino-4-imidazolecarboxamide
CH$NAME: AICAR
CH$NAME: AICAriboside 5'-monophosphate
CH$NAME: [(2R,3S,4R,5R)-5-(5-amino-4-carbamoylimidazol-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl dihydrogen phosphate
CH$NAME: 5-Aminoimidazole-4-carboxamide-1-beta-D-ribofuranosyl 5'-monophosphate
CH$NAME: N1-(beta-D-5'-Phosphoribofuranosyl)-5-aminoimidazole-4-carboxamide
CH$NAME: 5-Phosphoribosyl-4-carbamoyl-5-aminoimidazole
CH$COMPOUND_CLASS: CLASS1 Other CLASS2 Nucleotide CLASS3 Ribonucleotide
CH$FORMULA: C₉H₁₅N₄O₈P
CH$EXACT_MASS: 338.215
CH$SMILES: C1=NC(=C(N1C2C(C(C(O2)COP(=O)(O)O)O)O)N)C(=O)N
CH$IUPAC: InChI=1S/C9H15N4O8P/c10-7-4(8(11)16)12-2-13(7)9-6(15)5(14)3(21-9)1-20-22(17,18)19/h2-3,5-6,9,14-15H,1,10H2,(H2,11,16)(H2,17,18,19)
CH$LINK: CAS 3031-94-5
CH$LINK: INCHIKEY NOTGFIUVDGNKRI-UHFFFAOYSA-N

AC$INSTRUMENT: Q-Tof Premier, Waters
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: COLLISION_ENERGY Ramp 5-45 V
AC$MASS_SPECTROMETRY: CAPILLARY_VOLTAGE 3.0 kV
AC$CHROMATOGRAPHY: SOLVENT CH3CN/H2O

MS$FOCUSED_ION: ION_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_M/Z 339.07055

PK$SPLASH: splash10-03di-2900000000-f0dad518d8c8a1fa40e2
PK$NUM_PEAK: 5
PK$PEAK: m/z int. rel.int.
  97.0287 261.6 394
  110.0355 663.6 999
  127.0618 220.6 332
  206.0571 82.46 124
  339.0706 96.67 146
//