ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP002432
RECORD_TITLE: (5R)-5-(TERT-BUTYLDIMETHYLSILOXY)-2-METHYL-1-OCTEN-7-YNE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: ITO S, DEPT. OF CHEM., TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: (5R)-5-(TERT-BUTYLDIMETHYLSILOXY)-2-METHYL-1-OCTEN-7-YNE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₅H₂₈OSi
CH$EXACT_MASS: 252.19094
CH$SMILES: C#CCC([H])(CCC(C)=C)O[Si](C)(C)C(C)(C)C
CH$IUPAC: InChI=1S/C15H28OSi/c1-9-10-14(12-11-13(2)3)16-17(7,8)15(4,5)6/h1,14H,2,10-12H2,3-8H3/t14-/m0/s1
CH$LINK: INCHIKEY GCIMFTUZRIVFQX-AWEZNQCLSA-N

AC$INSTRUMENT: HITACHI M-52
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 25 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-003r-9200000000-995aa3e6d9778fd74e2e
PK$NUM_PEAK: 27
PK$PEAK: m/z int. rel.int.
  41 2.2 22
  43 2.2 22
  56 1.7 17
  69 0.2 2
  73 15.7 157
  75 54.2 542
  76 3.7 37
  78 0.17 2
  81 99.99 999
  82 7 70
  97 21.5 215
  98 0.26 3
  99 1.9 19
  101 2.5 25
  105 2.1 21
  115 0.22 2
  119 4.6 46
  127 1.7 17
  139 2.3 23
  155 4.1 41
  156 6.2 62
  157 2.2 22
  177 4.6 46
  183 0.18 2
  194 13.2 132
  195 2.4 24
  196 1.7 17
//