ACCESSION: MSBNK-LCSB-LU047406
RECORD_TITLE: 4-(2,5-Diethoxy-4-nitrophenyl)morpholine; LC-ESI-QFT; MS2; CE: 90; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 474
COMMENT: DATASET 20200303_ENTACT_RP_MIX506
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 8955
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 8953
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: 4-(2,5-Diethoxy-4-nitrophenyl)morpholine
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C14H20N2O5
CH$EXACT_MASS: 296.1372
CH$SMILES: CCOC1=CC(=C(OCC)C=C1N1CCOCC1)[N+]([O-])=O
CH$IUPAC: InChI=1S/C14H20N2O5/c1-3-20-13-10-12(16(17)18)14(21-4-2)9-11(13)15-5-7-19-8-6-15/h9-10H,3-8H2,1-2H3
CH$LINK: CAS
86-16-8
CH$LINK: PUBCHEM
CID:66571
CH$LINK: INCHIKEY
KNHGNICBXADRMC-UHFFFAOYSA-N
CH$LINK: CHEMSPIDER
59941
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 90
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 17.266 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0212
MS$FOCUSED_ION: PRECURSOR_M/Z 297.1445
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 7338459.0625
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-0f8c-5900000000-d1b3d6ff7a702ba8a13f
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
52.0182 C3H2N+ 1 52.0182 0.34
52.0309 C4H4+ 1 52.0308 2.93
53.0022 C3HO+ 1 53.0022 0.02
53.0386 C4H5+ 1 53.0386 0.15
54.0338 C3H4N+ 1 54.0338 -0.15
55.0178 C3H3O+ 1 55.0178 0.04
55.0417 C3H5N+ 1 55.0417 0.7
56.0495 C3H6N+ 1 56.0495 0.17
57.0573 C3H7N+ 1 57.0573 0.79
58.0652 C3H8N+ 1 58.0651 0.87
64.0181 C4H2N+ 1 64.0182 -0.87
65.026 C4H3N+ 1 65.026 0.37
65.0385 C5H5+ 1 65.0386 -0.61
66.0338 C4H4N+ 1 66.0338 -0.5
66.0464 C5H6+ 1 66.0464 0.04
67.0178 C4H3O+ 1 67.0178 -0.69
67.0416 C4H5N+ 1 67.0417 -0.55
67.0542 C5H7+ 1 67.0542 -0.59
68.013 C3H2NO+ 1 68.0131 -0.69
68.0256 C4H4O+ 1 68.0257 -0.28
68.0494 C4H6N+ 1 68.0495 -0.59
68.9971 C3HO2+ 1 68.9971 -0.64
69.0335 C4H5O+ 1 69.0335 -0.21
69.0574 C4H7N+ 1 69.0573 0.82
70.0287 C3H4NO+ 1 70.0287 0.13
70.0651 C4H8N+ 1 70.0651 -1.08
71.0127 C3H3O2+ 1 71.0128 -0.35
72.0444 C3H6NO+ 1 72.0444 0.19
72.0808 C4H10N+ 1 72.0808 0.39
74.0964 C4H12N+ 1 74.0964 -0.72
77.0384 C6H5+ 1 77.0386 -1.82
78.0338 C5H4N+ 1 78.0338 -0.52
78.0464 C6H6+ 1 78.0464 0.42
79.0179 C5H3O+ 1 79.0178 0.19
79.0416 C5H5N+ 1 79.0417 -0.65
79.0542 C6H7+ 1 79.0542 -0.21
80.0495 C5H6N+ 1 80.0495 -0.31
81.0335 C5H5O+ 1 81.0335 -0.16
81.0448 C4H5N2+ 1 81.0447 0.94
81.0573 C5H7N+ 1 81.0573 -0.42
81.0699 C6H9+ 1 81.0699 0.58
82.0287 C4H4NO+ 1 82.0287 0.02
82.0414 C5H6O+ 1 82.0413 0.73
82.0651 C5H8N+ 1 82.0651 -0.64
83.0128 C4H3O2+ 1 83.0128 0.23
83.0366 C4H5NO+ 1 83.0366 0.25
83.0493 C5H7O+ 1 83.0491 2.42
84.0444 C4H6NO+ 1 84.0444 0.38
85.0523 C4H7NO+ 1 85.0522 1.4
86.06 C4H8NO+ 1 86.06 -0.72
88.0757 C4H10NO+ 1 88.0757 -0.06
90.0337 C6H4N+ 1 90.0338 -1.5
91.0416 C6H5N+ 1 91.0417 -0.37
91.0543 C7H7+ 1 91.0542 0.35
92.0495 C6H6N+ 1 92.0495 0.07
93.0336 C6H5O+ 1 93.0335 1.13
93.0448 C5H5N2+ 1 93.0447 0.28
93.0573 C6H7N+ 1 93.0573 0.33
93.0698 C7H9+ 1 93.0699 -0.6
94.0288 C5H4NO+ 1 94.0287 0.2
94.0414 C6H6O+ 1 94.0413 0.9
94.0651 C6H8N+ 1 94.0651 0.19
95.0129 C5H3O2+ 1 95.0128 1.64
95.0366 C5H5NO+ 1 95.0366 -0.11
95.0492 C6H7O+ 1 95.0491 0.1
95.0603 C5H7N2+ 1 95.0604 -0.33
95.073 C6H9N+ 1 95.073 0.69
96.0444 C5H6NO+ 1 96.0444 0
96.0808 C6H10N+ 1 96.0808 0.55
97.0285 C5H5O2+ 1 97.0284 1.34
97.0523 C5H7NO+ 1 97.0522 0.88
98.0236 C4H4NO2+ 1 98.0237 -0.18
98.0602 C5H8NO+ 1 98.06 1.53
103.0542 C8H7+ 1 103.0542 -0.45
104.0495 C7H6N+ 1 104.0495 -0.02
105.0335 C7H5O+ 1 105.0335 0.15
105.0447 C6H5N2+ 1 105.0447 0.05
105.0573 C7H7N+ 1 105.0573 0.24
105.0701 C8H9+ 1 105.0699 1.74
106.0287 C6H4NO+ 1 106.0287 -0.15
106.0651 C7H8N+ 1 106.0651 0.06
107.0127 C6H3O2+ 1 107.0128 -0.56
107.0365 C6H5NO+ 1 107.0366 -0.26
107.0491 C7H7O+ 1 107.0491 -0.28
107.0603 C6H7N2+ 1 107.0604 -0.95
107.0729 C7H9N+ 1 107.073 -0.19
108.0205 C6H4O2+ 1 108.0206 -0.31
108.0444 C6H6NO+ 1 108.0444 -0.15
108.0807 C7H10N+ 1 108.0808 -0.51
109.0284 C6H5O2+ 1 109.0284 0.15
109.0522 C6H7NO+ 1 109.0522 -0.11
109.065 C7H9O+ 1 109.0648 1.47
109.0758 C6H9N2+ 1 109.076 -1.63
110.0238 C5H4NO2+ 1 110.0237 1.11
110.0363 C6H6O2+ 1 110.0362 0.53
110.0475 C5H6N2O+ 1 110.0475 0.65
110.06 C6H8NO+ 1 110.06 -0.28
111.0316 C5H5NO2+ 1 111.0315 1.07
111.044 C6H7O2+ 1 111.0441 -0.54
111.0553 C5H7N2O+ 1 111.0553 -0.22
111.0677 C6H9NO+ 1 111.0679 -1.69
112.0393 C5H6NO2+ 1 112.0393 0
112.0756 C6H10NO+ 1 112.0757 -1.02
114.0551 C5H8NO2+ 1 114.055 1.55
117.0448 C7H5N2+ 1 117.0447 0.95
117.0573 C8H7N+ 1 117.0573 0.21
117.0698 C9H9+ 1 117.0699 -0.53
118.0651 C8H8N+ 1 118.0651 -0.34
119.0367 C7H5NO+ 1 119.0366 0.99
119.0492 C8H7O+ 1 119.0491 0.77
119.0603 C7H7N2+ 1 119.0604 -0.86
119.0731 C8H9N+ 1 119.073 1.17
120.0444 C7H6NO+ 1 120.0444 0.19
120.0808 C8H10N+ 1 120.0808 0.37
121.0284 C7H5O2+ 1 121.0284 -0.43
121.0395 C6H5N2O+ 1 121.0396 -0.83
121.0523 C7H7NO+ 1 121.0522 0.72
121.0648 C8H9O+ 1 121.0648 0.26
121.0761 C7H9N2+ 1 121.076 0.61
122.0235 C6H4NO2+ 1 122.0237 -1.43
122.06 C7H8NO+ 1 122.06 -0.12
123.0314 C6H5NO2+ 1 123.0315 -0.64
123.044 C7H7O2+ 1 123.0441 -0.29
123.0552 C6H7N2O+ 1 123.0553 -0.62
123.0677 C7H9NO+ 1 123.0679 -1.33
123.0919 C7H11N2+ 1 123.0917 2.16
124.0393 C6H6NO2+ 1 124.0393 0.32
124.0635 C6H8N2O+ 1 124.0631 3.16
124.0758 C7H10NO+ 1 124.0757 0.5
125.0347 C5H5N2O2+ 1 125.0346 0.8
125.0472 C6H7NO2+ 1 125.0471 0.59
126.055 C6H8NO2+ 1 126.055 0.13
130.065 C9H8N+ 1 130.0651 -0.93
131.0491 C9H7O+ 1 131.0491 -0.04
131.0604 C8H7N2+ 1 131.0604 0.52
132.0444 C8H6NO+ 1 132.0444 0.01
132.0809 C9H10N+ 1 132.0808 0.87
133.0286 C8H5O2+ 1 133.0284 1.68
133.0398 C7H5N2O+ 1 133.0396 1.2
133.0522 C8H7NO+ 1 133.0522 -0.32
133.0759 C8H9N2+ 1 133.076 -0.7
134.0237 C7H4NO2+ 1 134.0237 0
134.06 C8H8NO+ 1 134.06 -0.18
135.0314 C7H5NO2+ 1 135.0315 -0.32
135.0443 C8H7O2+ 1 135.0441 1.47
135.0553 C7H7N2O+ 1 135.0553 -0.13
135.0679 C8H9NO+ 1 135.0679 0.07
136.0393 C7H6NO2+ 1 136.0393 0.27
136.0758 C8H10NO+ 1 136.0757 0.76
137.0347 C6H5N2O2+ 1 137.0346 0.86
137.0472 C7H7NO2+ 1 137.0471 0.17
137.0709 C7H9N2O+ 1 137.0709 -0.2
137.0836 C8H11NO+ 1 137.0835 0.67
138.0187 C6H4NO3+ 1 138.0186 0.92
138.0549 C7H8NO2+ 1 138.055 -0.14
138.0914 C8H12NO+ 1 138.0913 0.35
139.0506 C6H7N2O2+ 1 139.0502 2.75
140.0343 C6H6NO3+ 1 140.0342 0.4
144.0558 C10H8O+ 1 144.057 -8.27
146.0601 C9H8NO+ 1 146.06 0.46
147.0556 C8H7N2O+ 1 147.0553 1.85
147.068 C9H9NO+ 1 147.0679 0.69
148.0393 C8H6NO2+ 1 148.0393 -0.17
148.0756 C9H10NO+ 1 148.0757 -0.33
149.035 C7H5N2O2+ 1 149.0346 3.04
149.0472 C8H7NO2+ 1 149.0471 0.36
149.0709 C8H9N2O+ 1 149.0709 -0.39
149.0837 C9H11NO+ 1 149.0835 1.33
150.0186 C7H4NO3+ 1 150.0186 0.34
150.055 C8H8NO2+ 1 150.055 -0.03
151.0265 C7H5NO3+ 1 151.0264 0.56
151.0503 C7H7N2O2+ 1 151.0502 0.52
151.0627 C8H9NO2+ 1 151.0628 -0.51
151.0867 C8H11N2O+ 1 151.0866 0.86
152.0342 C7H6NO3+ 1 152.0342 -0.13
152.058 C7H8N2O2+ 1 152.058 0.13
152.0706 C8H10NO2+ 1 152.0706 -0.09
153.1023 C8H13N2O+ 1 153.1022 0.3
154.0137 C6H4NO4+ 1 154.0135 1.16
158.0597 C10H8NO+ 2 158.06 -2.34
160.0399 C9H6NO2+ 1 160.0393 3.41
160.0758 C10H10NO+ 1 160.0757 0.78
161.0345 C8H5N2O2+ 1 161.0346 -0.46
161.0475 C9H7NO2+ 1 161.0471 2.08
161.0712 C9H9N2O+ 1 161.0709 1.66
162.055 C9H8NO2+ 1 162.055 0.2
163.0266 C8H5NO3+ 2 163.0264 1.49
163.0504 C8H7N2O2+ 1 163.0502 0.99
163.0628 C9H9NO2+ 1 163.0628 0.03
163.0865 C9H11N2O+ 1 163.0866 -0.56
164.0341 C8H6NO3+ 1 164.0342 -0.45
164.0706 C9H10NO2+ 1 164.0706 -0.23
165.0293 C7H5N2O3+ 1 165.0295 -0.79
165.0427 C8H7NO3+ 2 165.042 3.73
165.0661 C8H9N2O2+ 1 165.0659 1.29
165.079 C9H11NO2+ 1 165.0784 3.67
166.0499 C8H8NO3+ 1 166.0499 0.05
166.0862 C9H12NO2+ 1 166.0863 -0.28
167.0579 C8H9NO3+ 2 167.0577 1.16
168.0289 C7H6NO4+ 1 168.0291 -1.68
169.0247 C6H5N2O4+ 1 169.0244 1.61
174.0551 C10H8NO2+ 1 174.055 0.56
175.0507 C9H7N2O2+ 1 175.0502 2.85
175.0634 C10H9NO2+ 1 175.0628 3.53
176.0706 C10H10NO2+ 1 176.0706 -0.11
176.1073 C11H14NO+ 1 176.107 1.83
177.0787 C10H11NO2+ 1 177.0784 1.46
178.0498 C9H8NO3+ 1 178.0499 -0.37
178.0738 C9H10N2O2+ 1 178.0737 0.62
178.0863 C10H12NO2+ 1 178.0863 0.52
179.0577 C9H9NO3+ 2 179.0577 0.16
180.0657 C9H10NO3+ 2 180.0655 0.94
181.0244 C7H5N2O4+ 1 181.0244 0
181.0969 C9H13N2O2+ 2 181.0972 -1.36
182.0322 C7H6N2O4+ 1 182.0322 -0.24
183.0401 C7H7N2O4+ 1 183.04 0.53
190.0873 C11H12NO2+ 1 190.0863 5.67
192.0653 C10H10NO3+ 2 192.0655 -0.89
192.1023 C11H14NO2+ 1 192.1019 1.85
193.0614 C9H9N2O3+ 1 193.0608 3.02
193.0737 C10H11NO3+ 2 193.0733 1.98
193.0979 C10H13N2O2+ 1 193.0972 3.85
194.0811 C10H12NO3+ 2 194.0812 -0.2
195.0404 C8H7N2O4+ 1 195.04 1.75
195.0528 C9H9NO4+ 2 195.0526 0.72
195.0889 C10H13NO3+ 2 195.089 -0.42
197.0559 C8H9N2O4+ 1 197.0557 1.09
208.0974 C11H14NO3+ 2 208.0968 2.71
209.0557 C9H9N2O4+ 1 209.0557 0
211.0839 C10H13NO4+ 2 211.0839 0.12
239.0665 C10H11N2O5+ 1 239.0662 1.09
PK$NUM_PEAK: 231
PK$PEAK: m/z int. rel.int.
52.0182 19539 76
52.0309 4760.7 18
53.0022 19306.4 75
53.0386 53446.2 209
54.0338 43987.2 172
55.0178 186164.7 731
55.0417 9487 37
56.0495 31952.9 125
57.0573 4472.4 17
58.0652 5681.5 22
64.0181 2649.6 10
65.026 7717.1 30
65.0385 86556.8 339
66.0338 15242.5 59
66.0464 25488 100
67.0178 10018.2 39
67.0416 84371.5 331
67.0542 61417.7 241
68.013 58453.3 229
68.0256 18495.9 72
68.0494 84959 333
68.9971 24790.2 97
69.0335 17907.6 70
69.0574 4795.8 18
70.0287 27177.6 106
70.0651 26385.3 103
71.0127 3848.1 15
72.0444 10220.6 40
72.0808 2404.4 9
74.0964 3543.7 13
77.0384 13050.7 51
78.0338 50613.1 198
78.0464 12984.2 51
79.0179 30493.5 119
79.0416 33800.6 132
79.0542 105621 414
80.0495 236199.5 927
81.0335 77121.5 302
81.0448 5554.9 21
81.0573 29387 115
81.0699 9580.9 37
82.0287 28762.4 112
82.0414 9229.6 36
82.0651 34050.4 133
83.0128 7072.7 27
83.0366 10690.1 41
83.0493 5669.8 22
84.0444 10823.8 42
85.0523 4376.7 17
86.06 26934.1 105
88.0757 5281.5 20
90.0337 3200.7 12
91.0416 19745.5 77
91.0543 104004.8 408
92.0495 163747.6 643
93.0336 10113.3 39
93.0448 11107.3 43
93.0573 81981.6 322
93.0698 12566.9 49
94.0288 122094.7 479
94.0414 20802.2 81
94.0651 194813.8 765
95.0129 7758.5 30
95.0366 27392.6 107
95.0492 100079.6 393
95.0603 15977.7 62
95.073 17257.5 67
96.0444 105072.1 412
96.0808 6332.6 24
97.0285 7980.3 31
97.0523 6765.9 26
98.0236 3666.7 14
98.0602 6699.1 26
103.0542 21922.3 86
104.0495 132936.5 522
105.0335 15091.9 59
105.0447 41167.7 161
105.0573 26773.5 105
105.0701 5874.2 23
106.0287 26223.9 103
106.0651 150642.5 591
107.0127 17584.5 69
107.0365 52974.1 208
107.0491 34415 135
107.0603 20565.6 80
107.0729 13369.1 52
108.0205 27268.7 107
108.0444 134338.7 527
108.0807 37261.9 146
109.0284 35447.3 139
109.0522 45116 177
109.065 11524.8 45
109.0758 15458.9 60
110.0238 7819.6 30
110.0363 6608.6 25
110.0475 6403.5 25
110.06 57607 226
111.0316 12118.2 47
111.044 35739.8 140
111.0553 16118.8 63
111.0677 4110.3 16
112.0393 15401.3 60
112.0756 3981.8 15
114.0551 5500 21
117.0448 6287.5 24
117.0573 20369.2 80
117.0698 2751.4 10
118.0651 49719.5 195
119.0367 11554.7 45
119.0492 11797.4 46
119.0603 16721.4 65
119.0731 9762.7 38
120.0444 163300.5 641
120.0808 34731.9 136
121.0284 4620.8 18
121.0395 18838.8 73
121.0523 37945.8 149
121.0648 3343.4 13
121.0761 18480.4 72
122.0235 13434.2 52
122.06 204185 802
123.0314 15826.1 62
123.044 16799.6 65
123.0552 31286 122
123.0677 19334.7 75
123.0919 3563.7 13
124.0393 58205.1 228
124.0635 3296.2 12
124.0758 14751 57
125.0347 3064.6 12
125.0472 9067.5 35
126.055 10259.8 40
130.065 13936.4 54
131.0491 7392.3 29
131.0604 4540.8 17
132.0444 72413.2 284
132.0809 8757.1 34
133.0286 7235.9 28
133.0398 4042.7 15
133.0522 35386.8 138
133.0759 10613.3 41
134.0237 20942.1 82
134.06 123279.4 484
135.0314 96239 378
135.0443 8206 32
135.0553 31453.7 123
135.0679 30401.8 119
136.0393 179036.9 703
136.0758 88511.2 347
137.0347 4564.5 17
137.0472 28668.5 112
137.0709 42098.7 165
137.0836 5044 19
138.0187 5434.4 21
138.0549 47722.4 187
138.0914 8237.6 32
139.0506 4793.8 18
140.0343 7482.2 29
144.0558 7425.8 29
146.0601 23033.8 90
147.0556 7343.2 28
147.068 18194.2 71
148.0393 182815.2 718
148.0756 74025.6 290
149.035 4407.8 17
149.0472 47630.3 187
149.0709 27266 107
149.0837 5827.5 22
150.0186 164901.2 647
150.055 192361.7 755
151.0265 26177.9 102
151.0503 28306.1 111
151.0627 21308.9 83
151.0867 9507.5 37
152.0342 70942.5 278
152.058 5324.5 20
152.0706 10670.6 41
153.1023 12297.6 48
154.0137 2502 9
158.0597 2861.5 11
160.0399 3075 12
160.0758 8029.1 31
161.0345 2399.4 9
161.0475 5903.4 23
161.0712 6156.8 24
162.055 62138.3 244
163.0266 3254.3 12
163.0504 8824 34
163.0628 32630.6 128
163.0865 9288.5 36
164.0341 24935.5 97
164.0706 111886.4 439
165.0293 4985.2 19
165.0427 2987.5 11
165.0661 5586.5 21
165.079 4484.1 17
166.0499 47215.6 185
166.0862 18804 73
167.0579 12157.7 47
168.0289 2658.7 10
169.0247 5719.5 22
174.0551 2888.2 11
175.0507 3567.8 14
175.0634 2737.6 10
176.0706 50684.1 199
176.1073 2937.2 11
177.0787 2969.9 11
178.0498 28575.9 112
178.0738 3225.8 12
178.0863 15028.9 59
179.0577 15984.3 62
180.0657 7974.3 31
181.0244 254336.6 999
181.0969 17777.9 69
182.0322 23726.2 93
183.0401 12091.8 47
190.0873 3086.1 12
192.0653 12464.4 48
192.1023 7228.8 28
193.0614 4114.9 16
193.0737 5317.1 20
193.0979 2912.5 11
194.0811 21759.3 85
195.0404 8274.7 32
195.0528 7724.8 30
195.0889 2726 10
197.0559 5556.7 21
208.0974 2851.3 11
209.0557 19899.3 78
211.0839 2678.5 10
239.0665 3171.6 12
//
