ACCESSION: MSBNK-LCSB-LU049853
RECORD_TITLE: Prodiamine; LC-ESI-QFT; MS2; CE: 45; R=17500; [M-H]-
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 498
COMMENT: DATASET 20200303_ENTACT_RP_MIX506
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 5615
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 5612
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Prodiamine
CH$NAME: 2,4-dinitro-3-N,3-N-dipropyl-6-(trifluoromethyl)benzene-1,3-diamine
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C13H17F3N4O4
CH$EXACT_MASS: 350.1202
CH$SMILES: CCCN(CCC)C1=C(C(N)=C(C=C1[N+]([O-])=O)C(F)(F)F)[N+]([O-])=O
CH$IUPAC: InChI=1S/C13H17F3N4O4/c1-3-5-18(6-4-2)11-9(19(21)22)7-8(13(14,15)16)10(17)12(11)20(23)24/h7H,3-6,17H2,1-2H3
CH$LINK: CAS
29091-21-2
CH$LINK: CHEBI
82032
CH$LINK: KEGG
C18884
CH$LINK: PUBCHEM
CID:34469
CH$LINK: INCHIKEY
RSVPPPHXAASNOL-UHFFFAOYSA-N
CH$LINK: CHEMSPIDER
31719
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 45
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 19.704 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 349.1128
MS$FOCUSED_ION: PRECURSOR_M/Z 349.1129
MS$FOCUSED_ION: PRECURSOR_TYPE [M-H]-
MS$FOCUSED_ION: PRECURSOR_INTENSITY 68236776.44141
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-00lr-1980000000-b3da9b41a0df40dd976a
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
57.9934 CNO2- 1 57.9935 -0.12
64.0067 C3N2- 1 64.0067 0.81
65.0145 C3HN2- 1 65.0145 0.09
65.9985 C3NO- 1 65.9985 -0.18
68.0142 C3H2NO- 1 68.0142 0.24
68.9957 CF3- 1 68.9958 -0.77
70.9939 C3FO- 1 70.9939 0.6
73.0295 C3H5O2- 1 73.0295 -0.01
74.0036 C5N- 1 74.0036 -0.58
76.0067 C4N2- 2 76.0067 0.27
77.0145 C4HN2- 1 77.0145 -0.17
79.9904 C4O2- 2 79.9904 0.85
84.9968 C3FNO- 2 84.9969 -1.29
86.9887 C3FO2- 2 86.9888 -1.28
88.0004 C3F2N- 2 88.0004 -0.05
88.0066 C5N2- 2 88.0067 -0.88
89.0144 C5HN2- 2 89.0145 -1.21
89.9986 C5NO- 2 89.9985 0.64
90.0098 C4N3- 3 90.0098 0.02
92.0253 C4H2N3- 2 92.0254 -0.9
92.9959 C3F3- 1 92.9958 1.56
93.0095 C4HN2O- 2 93.0094 0.42
94.0047 C3N3O- 4 94.0047 0.09
94.01 C5HFN- 3 94.0099 1.3
95.005 C4FN2- 2 95.0051 -0.87
100.0005 C4F2N- 2 100.0004 0.53
101.0146 C6HN2- 2 101.0145 0.95
102.0098 C5N3- 3 102.0098 0.66
103.9954 C3F2NO- 2 103.9953 0.75
104.0015 C5N2O- 2 104.0016 -0.97
104.0504 C2H5FN4- 4 104.0504 0.69
106.0172 C5H2N2O- 2 106.0173 -0.92
106.9989 C3F3N- 1 106.9988 0.62
107.0051 C5FN2- 2 107.0051 0.16
108.0067 C3HF3N- 2 108.0067 0.64
108.0217 C6H4O2- 4 108.0217 -0.05
108.9907 C3F3O- 1 108.9907 0.03
108.9969 C5FNO- 2 108.9969 -0.22
109.0208 C5H2FN2- 2 109.0207 0.22
111 C4FN2O- 2 111 -0.39
112.0004 C5F2N- 2 112.0004 0.08
113.9996 C4HFNO2- 3 113.9997 -0.88
114.0098 C6N3- 4 114.0098 0.15
115.0176 C6HN3- 4 115.0176 0.05
115.0301 C7H3N2- 3 115.0302 -0.31
116.0252 C6H2N3- 4 116.0254 -1.56
117.0096 C6HN2O- 2 117.0094 1.28
117.0206 C5HN4- 4 117.0207 -0.31
117.0459 C7H5N2- 3 117.0458 1.08
118.0413 C6H4N3- 3 118.0411 2.03
119.0052 C6FN2- 3 119.0051 0.6
119.0251 C6H3N2O- 2 119.0251 0.05
120.0065 C4HF3N- 3 120.0067 -1.18
120.0202 C5H2N3O- 4 120.0203 -1.36
121.0084 C10H- 4 121.0084 0.36
121.0205 C6H2FN2- 3 121.0207 -1.67
122.0046 CF2N4O- 4 122.0046 0
122.9998 C5FN2O- 2 123 -1.63
124.0078 C8N2- 3 124.0067 8.98
126.0036 C5F2N2- 2 126.0035 0.53
126.0098 C7N3- 4 126.0098 0.2
127.0114 C5HF2N2- 2 127.0113 0.2
127.0176 C7HN3- 4 127.0176 -0.07
127.9953 C5F2NO- 2 127.9953 -0.03
128.0255 C7H2N3- 4 128.0254 0.97
128.038 C8H4N2- 3 128.038 -0.36
129.0036 C5HF2NO- 5 129.0032 3.61
129.0095 C7HN2O- 2 129.0094 0.21
129.0329 C7H3N3- 4 129.0332 -2.56
129.046 C8H5N2- 3 129.0458 1.44
130.0284 C6H2N4- 5 130.0285 -0.85
130.9987 C5F3N- 2 130.9988 -1.19
131.0123 C6HN3O- 4 131.0125 -1.35
132.0069 C5HF3N- 3 132.0067 1.5
132.0203 C6H2N3O- 4 132.0203 -0.62
133.002 C4F3N2- 2 133.0019 0.39
133.008 C6FN3- 5 133.0082 -1.41
133.0209 C7H2FN2- 3 133.0207 1.32
133.041 C7H5N2O- 2 133.0407 2.02
134.0048 C7HFNO- 4 134.0048 0.12
134.0161 C11H2- 5 134.0162 -0.59
134.9999 C6FN2O- 2 135 -0.62
136.0016 C4HF3NO- 3 136.0016 0.5
136.0077 C6HFN2O- 3 136.0078 -0.71
136.0205 C7H3FNO- 5 136.0204 0.28
137.0158 C6H2FN2O- 3 137.0157 1.22
138.9948 C5FN2O2- 2 138.9949 -0.67
139.0113 C6HF2N2- 3 139.0113 -0.09
139.9954 C6F2NO- 2 139.9953 0.52
140.0253 C8H2N3- 4 140.0254 -0.59
141.0206 C7HN4- 5 141.0207 -0.43
141.0458 C9H5N2- 3 141.0458 -0.04
142.041 C8H4N3- 4 142.0411 -0.43
143.0363 C7H3N4- 5 143.0363 -0.17
143.0485 C8H5N3- 4 143.0489 -2.43
143.0613 C9H7N2- 3 143.0615 -0.85
144.0066 C6HF3N- 3 144.0067 -0.07
144.0204 C7H2N3O- 4 144.0203 0.21
144.0568 C8H6N3- 4 144.0567 0.25
145.0019 C5F3N2- 2 145.0019 0.08
145.052 C7H5N4- 5 145.052 0.19
146.0097 C5HF3N2- 2 146.0097 -0.11
146.016 C7HFN3- 5 146.016 0.12
146.994 C5F3NO- 3 146.9937 1.71
147.0003 C7FN2O- 3 147 1.63
147.024 C12H3- 6 147.024 -0.39
148.0018 C5HF3NO- 4 148.0016 1.41
148.008 C7HFN2O- 4 148.0078 0.82
149.003 C6FN3O- 4 149.0031 -0.79
149.0092 C5H2F3NO- 4 149.0094 -1.14
150.0359 C3H4F2N4O- 6 150.0359 0.53
151.0114 C7HF2N2- 3 151.0113 0.64
151.0441 C8H6FNO- 7 151.0439 1.14
152.013 C8N4- 6 152.0128 1.1
152.0254 C9H2N3- 4 152.0254 -0.03
153.0332 C9H3N3- 4 153.0332 -0.51
154.0286 C8H2N4- 6 154.0285 0.42
154.041 C9H4N3- 4 154.0411 -0.39
155.006 C6HF2N2O- 3 155.0062 -1.32
155.0125 C8HN3O- 5 155.0125 0.18
155.0488 C9H5N3- 4 155.0489 -0.37
156.0077 C7N4O- 5 156.0078 -0.18
156.0201 C8H2N3O- 4 156.0203 -1.37
156.0266 C7H4F2NO- 6 156.0266 -0.14
156.033 C9H4N2O- 3 156.0329 0.86
156.0568 C9H6N3- 5 156.0567 0.63
157.0019 C6F3N2- 2 157.0019 -0.31
158.0096 C6HF3N2- 2 158.0097 -0.68
158.016 C8HFN3- 6 158.016 0.12
158.0355 C8H4N3O- 5 158.036 -3.15
159.011 C7FN4- 7 159.0112 -1.48
159.0176 C6H2F3N2- 2 159.0176 0.11
159.0365 C9H4FN2- 4 159.0364 0.6
160.0016 C6HF3NO- 4 160.0016 -0.02
160.0317 C8H3FN3- 6 160.0316 0.06
160.9969 C5F3N2O- 2 160.9968 0.39
161.0158 C8H2FN2O- 4 161.0157 0.68
161.0525 C9H6FN2- 4 161.052 3
162.0108 C7HFN3O- 6 162.0109 -0.42
162.0173 C6H3F3NO- 6 162.0172 0.29
162.08 C9H10N2O- 3 162.0799 0.94
163.0127 C5H2F3N2O- 3 163.0125 1.45
164.0062 C7F2N3- 6 164.0066 -2.16
164.0263 C7H3FN3O- 6 164.0266 -1.68
165.0107 C7H2FN2O2- 4 165.0106 0.61
166.0226 C12H3F- 6 166.0224 1.02
166.041 C10H4N3- 5 166.0411 -0.34
167.006 C7HF2N2O- 4 167.0062 -1.48
167.0364 C9H3N4- 7 167.0363 0.7
168.0132 C10HFN2- 4 168.0129 1.44
168.0204 C9H2N3O- 6 168.0203 0.66
168.0565 C10H6N3- 5 168.0567 -1.57
169.0017 C7F3N2- 3 169.0019 -1.26
169.0219 C7H3F2N2O- 3 169.0219 0.11
169.0407 C10H5N2O- 3 169.0407 -0.25
169.0518 C9H5N4- 6 169.052 -0.81
170.0101 C7HF3N2- 3 170.0097 2.08
171.0176 C7H2F3N2- 3 171.0176 0.48
172.0016 C7HF3NO- 5 172.0016 0.45
172.0517 C9H6N3O- 6 172.0516 0.54
173.0206 C6H2F3N3- 4 173.0206 0
173.039 C9H4FN3- 5 173.0395 -2.64
174.0045 C6HF3N2O- 3 174.0046 -1.08
174.0474 C9H5FN3- 6 174.0473 0.73
175.0121 C6H2F3N2O- 3 175.0125 -1.93
175.0194 C13H3O- 7 175.0189 2.53
175.0313 C9H4FN2O- 4 175.0313 -0.01
175.0551 C9H6FN3- 6 175.0551 -0.13
176.0201 C6H3F3N2O- 3 176.0203 -1.38
176.0274 C5H4F2N3O2- 7 176.0277 -1.53
176.0391 C9H5FN2O- 4 176.0391 -0.08
177.0472 C9H6FN2O- 4 177.047 1.06
178.0221 C8H2F2N3- 7 178.0222 -0.89
180.0016 C7F2N3O- 5 180.0015 0.47
181.0218 C8H3F2N2O- 4 181.0219 -0.45
182.0171 C7H2F2N3O- 7 182.0171 -0.08
182.0362 C10H4N3O- 6 182.036 1.18
183.0441 C10H5N3O- 6 183.0438 1.69
184.0129 C7HF3N3- 5 184.0128 0.27
184.0319 C10H3FN3- 6 184.0316 1.52
184.0514 C10H6N3O- 7 184.0516 -1.04
184.9968 C7F3N2O- 3 184.9968 -0.09
186.0476 C10H5FN3- 6 186.0473 1.62
187.0127 C7H2F3N2O- 3 187.0125 1.09
187.0551 C10H6FN3- 7 187.0551 -0.08
187.9963 C7HF3NO2- 5 187.9965 -0.74
188.0078 C6HF3N3O- 6 188.0077 0.22
188.0267 C9H3FN3O- 7 188.0266 0.55
188.0629 C10H7FN3- 7 188.0629 -0.15
189.0152 C6H2F3N3O- 6 189.0155 -1.62
189.047 C10H6FN2O- 5 189.047 0.06
190.0208 C3H5F3N2O4- 6 190.0207 0.78
191.0074 C6H2F3N2O2- 4 191.0074 0.14
191.0296 C9H3F2N3- 5 191.0301 -2.14
194.0171 C8H2F2N3O- 7 194.0171 -0.44
196.0327 C8H4F2N3O- 7 196.0328 -0.25
197.0173 C5H4F3N2O3- 3 197.018 -3.45
199.0365 C13H5F2- 5 199.0365 -0.07
199.0488 C9H6F3N2- 4 199.0489 -0.38
200.0074 C7HF3N3O- 6 200.0077 -1.38
201.0155 C7H2F3N3O- 6 201.0155 -0.22
201.0644 C9H8F3N2- 4 201.0645 -0.58
201.9995 C7HF3N2O2- 3 201.9996 -0.1
202.0231 C7H3F3N3O- 6 202.0234 -1.11
202.0419 C10H5FN3O- 7 202.0422 -1.48
203.0504 C10H6FN3O- 6 203.05 2
204.0026 C6HF3N3O2- 5 204.0026 0.02
204.0579 C10H7FN3O- 7 204.0579 0.28
205.0245 C12H4F3- 4 205.0271 -12.6
206.0536 C10H6F2N3- 6 206.0535 0.22
208.0328 C9H4F2N3O- 6 208.0328 -0.08
208.0688 C10H8F2N3- 6 208.0692 -1.59
208.0881 C13H10N3- 6 208.088 0.47
209.0286 C13H4FNO- 8 209.0282 1.77
210.0281 C9H3F3N3- 4 210.0285 -1.52
211.0235 C8H2F3N4- 7 211.0237 -0.76
212.0278 C13H5FO2- 6 212.0279 -0.28
212.0435 C9H5F3N3- 4 212.0441 -2.63
213.0277 C9H4F3N2O- 4 213.0281 -2
213.0647 C10H8F3N2- 4 213.0645 1.04
214.0234 C8H3F3N3O- 6 214.0234 0.03
215.031 C8H4F3N3O- 6 215.0312 -0.81
215.0421 C12H5F2N2- 5 215.0426 -2.68
216.1142 C12H14N3O- 5 216.1142 -0.11
217.0105 C7H2F3N3O2- 6 217.0105 -0.04
217.0228 C8H4F3N2O2- 3 217.023 -0.97
217.0531 C10H6FN4O- 8 217.0531 -0.06
217.9944 C7HF3N2O3- 2 217.9945 -0.14
218.0179 C7H3F3N3O2- 6 218.0183 -1.99
219.026 C7H4F3N3O2- 6 219.0261 -0.71
220.0098 C7H3F3N2O3- 4 220.0101 -1.3
222.0484 C10H6F2N3O- 6 222.0484 -0.2
223.0568 C10H7F2N3O- 7 223.0563 2.48
224.0441 C10H5F3N3- 4 224.0441 0.16
224.0642 C10H8F2N3O- 6 224.0641 0.3
225.0232 C13H4FNO2- 6 225.0232 0.29
225.0515 C10H6F3N3- 5 225.0519 -2.07
226.0431 C9H6F2N3O2- 5 226.0434 -1.26
226.06 C10H7F3N3- 5 226.0598 1.05
228.0263 C8H3F3N4O- 7 228.0264 -0.5
228.0391 C9H5F3N3O- 5 228.039 0.23
228.0944 C13H11FN3- 6 228.0942 0.8
229.0343 C8H4F3N4O- 7 229.0343 0.05
230.0032 C12H3FO4- 6 230.0021 5.03
230.0175 C11H2F2N3O- 6 230.0171 1.53
230.0544 C9H7F3N3O- 5 230.0547 -1.15
231.0135 C7H2F3N4O2- 6 231.0135 0.04
231.0273 C13H4F3N- 6 231.0301 -12.24
231.0326 C13H4F3N- 7 231.0301 10.55
231.0753 C10H10F3N2O- 5 231.0751 0.83
231.9975 C7HF3N3O3- 4 231.9975 -0.19
233.0483 C10H6FN4O2- 7 233.048 0.97
235.0216 C12H5F2O3- 7 235.0212 1.71
235.0435 C10H5F2N4O- 7 235.0437 -0.71
237.0394 C10H4F3N4- 7 237.0394 0.39
238.0462 C9H9F3O4- 7 238.0458 1.6
238.0594 C11H7F3N3- 5 238.0598 -1.47
239.0549 C10H6F3N4- 6 239.055 -0.49
240.0391 C10H5F3N3O- 6 240.039 0.25
240.0616 C9H11F3O4- 6 240.0615 0.65
240.0754 C11H9F3N3- 5 240.0754 -0.04
241.034 C9H4F3N4O- 7 241.0343 -1.25
241.047 C10H6F3N3O- 6 241.0468 0.76
242.0549 C10H7F3N3O- 6 242.0547 0.89
243.0132 C8H2F3N4O2- 7 243.0135 -1.57
243.062 C10H8F3N3O- 6 243.0625 -1.86
244.021 C8H3F3N4O2- 7 244.0214 -1.36
244.0339 C9H5F3N3O2- 4 244.0339 -0.12
244.0703 C10H9F3N3O- 6 244.0703 -0.16
245.0292 C8H4F3N4O2- 6 245.0292 0.08
246.086 C10H11F3N3O- 6 246.086 0.29
249.0001 C7H2F3N3O4- 5 249.0003 -0.81
250.0081 C7H3F3N3O4- 6 250.0081 -0.06
251.0387 C10H5F2N4O2- 5 251.0386 0.22
253.0544 C10H7F2N4O2- 5 253.0543 0.6
253.0835 C12H10F3N3- 3 253.0832 0.97
255.0499 C10H6F3N4O- 8 255.0499 -0.11
256.0579 C10H7F3N4O- 7 256.0577 0.43
257.0652 C10H8F3N4O- 7 257.0656 -1.4
258.0502 C10H7F3N3O2- 4 258.0496 2.36
259.1062 C12H14F3N2O- 5 259.1064 -0.57
260.0655 C10H9F3N3O2- 4 260.0652 0.95
266.1109 C13H14F2N3O- 5 266.111 -0.35
268.1071 C13H13F3N3- 3 268.1067 1.6
270.0375 C10H5F3N4O2- 4 270.037 1.68
271.0447 C10H6F3N4O2- 5 271.0448 -0.4
272.052 C13H6F2N4O- 5 272.0515 1.96
273.0597 C13H7F2N4O- 5 273.0593 1.23
285.0602 C11H8F3N4O2- 4 285.0605 -1.01
286.1173 C13H15F3N3O- 2 286.1173 0.08
287.0762 C11H10F3N4O2- 4 287.0761 0.07
288.0482 C10H7F3N4O3- 3 288.0476 2.28
289.0554 C10H8F3N4O3- 3 289.0554 0.12
289.1173 C13H16F3N2O2- 1 289.1169 1.34
302.1121 C13H15F3N3O2- 2 302.1122 -0.27
306.1073 C12H15F3N3O3- 1 306.1071 0.5
313.0919 C13H12F3N4O2- 2 313.0918 0.47
349.1128 C13H16F3N4O4- 1 349.1129 -0.37
PK$NUM_PEAK: 298
PK$PEAK: m/z int. rel.int.
57.9934 28619.1 12
64.0067 91293 40
65.0145 101067.8 45
65.9985 405467.4 180
68.0142 9813.4 4
68.9957 44890.7 20
70.9939 14923.3 6
73.0295 72554.8 32
74.0036 19246.2 8
76.0067 14033.7 6
77.0145 14408.1 6
79.9904 14079.6 6
84.9968 24363.6 10
86.9887 16177.4 7
88.0004 507876.5 226
88.0066 199382.1 88
89.0144 60439.1 26
89.9986 36177.9 16
90.0098 39116.4 17
92.0253 13182.3 5
92.9959 16474.3 7
93.0095 18922.9 8
94.0047 14422.9 6
94.01 9187 4
95.005 67852.5 30
100.0005 60603.1 27
101.0146 40034.2 17
102.0098 22751.7 10
103.9954 182825.3 81
104.0015 18706.9 8
104.0504 9856.7 4
106.0172 15995 7
106.9989 21110.8 9
107.0051 50488.5 22
108.0067 34519.5 15
108.0217 29945.2 13
108.9907 98993.3 44
108.9969 79233.3 35
109.0208 17329.6 7
111 107213.5 47
112.0004 145282.4 64
113.9996 11542.2 5
114.0098 72276.1 32
115.0176 47782.5 21
115.0301 8179.5 3
116.0252 43109.5 19
117.0096 21928.1 9
117.0206 27339.5 12
117.0459 22026.1 9
118.0413 10783.8 4
119.0052 49206.1 21
119.0251 203810.8 90
120.0065 48892.8 21
120.0202 9009.9 4
121.0084 18721.6 8
121.0205 10842.8 4
122.0046 14168.9 6
122.9998 13150.3 5
124.0078 24286.7 10
126.0036 72415.8 32
126.0098 50272.4 22
127.0114 82232.4 36
127.0176 77215 34
127.9953 31871.7 14
128.0255 10713 4
128.038 17416 7
129.0036 10086.5 4
129.0095 9315.6 4
129.0329 10238 4
129.046 40640.8 18
130.0284 11507.3 5
130.9987 81007.6 36
131.0123 17711.5 7
132.0069 16125.1 7
132.0203 17339.3 7
133.002 135110.6 60
133.008 18850.4 8
133.0209 31374.6 14
133.041 12170.3 5
134.0048 12509.3 5
134.0161 247575 110
134.9999 59675 26
136.0016 223684.4 99
136.0077 26279.5 11
136.0205 52096.1 23
137.0158 37347.6 16
138.9948 11468.2 5
139.0113 65950.8 29
139.9954 9476.1 4
140.0253 12918.4 5
141.0206 18957 8
141.0458 27285 12
142.041 32251.2 14
143.0363 33668.6 15
143.0485 11557.9 5
143.0613 25614 11
144.0066 85350.7 38
144.0204 41446.3 18
144.0568 32272.9 14
145.0019 307595.4 137
145.052 51064.2 22
146.0097 173617.2 77
146.016 60591.2 27
146.994 18855.5 8
147.0003 15643.4 6
147.024 83212.9 37
148.0018 11235.5 5
148.008 32922.8 14
149.003 47877.4 21
149.0092 17442.4 7
150.0359 10142.1 4
151.0114 37888.6 16
151.0441 57142.8 25
152.013 13971.5 6
152.0254 8063.7 3
153.0332 8472.2 3
154.0286 11747.9 5
154.041 11571.7 5
155.006 22300 9
155.0125 60423.4 26
155.0488 22657.1 10
156.0077 9224.1 4
156.0201 21640.4 9
156.0266 50931.6 22
156.033 16763.3 7
156.0568 55060.8 24
157.0019 547152.9 244
158.0096 30571.8 13
158.016 30009.3 13
158.0355 10729 4
159.011 29717.4 13
159.0176 228858.6 102
159.0365 18710.2 8
160.0016 201951.1 90
160.0317 61328.4 27
160.9969 124431.8 55
161.0158 16656.7 7
161.0525 14816 6
162.0108 95839.1 42
162.0173 9543.4 4
162.08 42320.8 18
163.0127 12920.6 5
164.0062 12282.6 5
164.0263 14184.5 6
165.0107 28178.5 12
166.0226 37227.9 16
166.041 60170.7 26
167.006 23142.8 10
167.0364 25691.1 11
168.0132 13801.1 6
168.0204 32887.7 14
168.0565 18884.9 8
169.0017 26930.5 12
169.0219 12091.6 5
169.0407 21392.8 9
169.0518 30422.1 13
170.0101 64423.9 28
171.0176 79530.5 35
172.0016 17223.6 7
172.0517 13996.3 6
173.0206 44318.5 19
173.039 13666.7 6
174.0045 64313.9 28
174.0474 49917.6 22
175.0121 25072.7 11
175.0194 79039.3 35
175.0313 19476.6 8
175.0551 16625 7
176.0201 20380.8 9
176.0274 53843.3 24
176.0391 18479.1 8
177.0472 55754.5 24
178.0221 91228.5 40
180.0016 24407.1 10
181.0218 26214.5 11
182.0171 18589.2 8
182.0362 64386 28
183.0441 17083.4 7
184.0129 135095.9 60
184.0319 14161.2 6
184.0514 135700.3 60
184.9968 308629.1 137
186.0476 43394.1 19
187.0127 113567.8 50
187.0551 13256.8 5
187.9963 22422.2 10
188.0078 79805.3 35
188.0267 125016.8 55
188.0629 73978.3 33
189.0152 18975 8
189.047 45966.5 20
190.0208 12555.6 5
191.0074 35506.7 15
191.0296 10406.9 4
194.0171 39338.7 17
196.0327 48960.1 21
197.0173 24564.8 10
199.0365 94680 42
199.0488 88851.3 39
200.0074 34772.4 15
201.0155 30516.3 13
201.0644 81927.7 36
201.9995 188447.3 84
202.0231 12931.7 5
202.0419 71620 31
203.0504 39235 17
204.0026 103552.5 46
204.0579 95590.9 42
205.0245 62843.8 28
206.0536 123317.7 55
208.0328 43050.6 19
208.0688 8610.2 3
208.0881 16570.9 7
209.0286 13128.6 5
210.0281 88453.5 39
211.0235 27165.8 12
212.0278 56140.2 25
212.0435 44585.7 19
213.0277 8741.2 3
213.0647 14070.6 6
214.0234 248144.6 110
215.031 214730.1 95
215.0421 12130.8 5
216.1142 771866.4 344
217.0105 45510.9 20
217.0228 54767.8 24
217.0531 9197.5 4
217.9944 129459.9 57
218.0179 159661.8 71
219.026 13323.7 5
220.0098 21712.9 9
222.0484 58756.9 26
223.0568 9647.8 4
224.0441 14757.6 6
224.0642 55206.4 24
225.0232 105227.1 46
225.0515 19125.2 8
226.0431 12478.5 5
226.06 51074.1 22
228.0263 40579.8 18
228.0391 64366.8 28
228.0944 12939 5
229.0343 22287.7 9
230.0032 43192.2 19
230.0175 63284.1 28
230.0544 16622.5 7
231.0135 167393.5 74
231.0273 10391.9 4
231.0326 11452.7 5
231.0753 25788.2 11
231.9975 2238202.8 999
233.0483 80208.9 35
235.0216 14717.8 6
235.0435 26725.9 11
237.0394 101713.3 45
238.0462 34209.6 15
238.0594 15392.1 6
239.0549 65284.2 29
240.0391 132559.4 59
240.0616 18855.1 8
240.0754 28231.6 12
241.034 24144 10
241.047 19723.5 8
242.0549 184842.2 82
243.0132 14201.6 6
243.062 10050.1 4
244.021 44238.3 19
244.0339 76682.2 34
244.0703 175444.2 78
245.0292 70088.4 31
246.086 34217.4 15
249.0001 59386.8 26
250.0081 75092.5 33
251.0387 31210.2 13
253.0544 21559.9 9
253.0835 21463.2 9
255.0499 130385.6 58
256.0579 72280.4 32
257.0652 14475.9 6
258.0502 20691.9 9
259.1062 363864.8 162
260.0655 48024.2 21
266.1109 302978.1 135
268.1071 30818.7 13
270.0375 35061.2 15
271.0447 79790 35
272.052 40385.8 18
273.0597 10328.6 4
285.0602 18187.6 8
286.1173 198318.1 88
287.0762 20365.2 9
288.0482 13326.7 5
289.0554 67602.8 30
289.1173 36596.9 16
302.1121 147475.6 65
306.1073 105163.8 46
313.0919 11668.7 5
349.1128 644930.9 287
//
