ACCESSION: MSBNK-Athens_Univ-AU283705
RECORD_TITLE: Clobetasol propionate; LC-ESI-QTOF; MS2; CE: 50 eV; R=35000; [M+H]+
DATE: 2019.05.31
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2837
CH$NAME: Clobetasol propionate
CH$NAME: [(8S,9R,10S,11S,13S,14S,16S,17R)-17-(2-chloroacetyl)-9-fluoro-11-hydroxy-10,13,16-trimethyl-3-oxo-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-17-yl] propanoate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C25H32ClFO5
CH$EXACT_MASS: 466.1922300
CH$SMILES: CCC(=O)O[C@@]1([C@@H](C)C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(F)[C@@H](O)C[C@]12C)C(=O)CCl
CH$IUPAC: InChI=1S/C25H32ClFO5/c1-5-21(31)32-25(20(30)13-26)14(2)10-18-17-7-6-15-11-16(28)8-9-22(15,3)24(17,27)19(29)12-23(18,25)4/h8-9,11,14,17-19,29H,5-7,10,12-13H2,1-4H3/t14-,17-,18-,19-,22-,23-,24-,25-/m0/s1
CH$LINK: CAS
25122-41-2
CH$LINK: CHEBI
31414
CH$LINK: KEGG
D01272
CH$LINK: PUBCHEM
CID:32798
CH$LINK: INCHIKEY
CBGUOGMQLZIXBE-XGQKBEPLSA-N
CH$LINK: CHEMSPIDER
30399
CH$LINK: COMPTOX
DTXSID6045907
AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 50 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 10.683 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 313.2161
MS$FOCUSED_ION: PRECURSOR_M/Z 467.1995
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1
PK$SPLASH: splash10-03ka-0890000000-2270e1a0c4a90302b784
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
115.0531 ClFH13O3+ 4 115.0532 -0.66
116.0601 C3H13ClO2+ 3 116.0599 2.48
117.069 ClFH15O3+ 4 117.0688 1.86
119.0845 C9H11+ 4 119.0855 -8.64
120.0882 C8[13]CH11+ 1 120.0894 -10.59
121.0638 C8H9O+ 3 121.0648 -7.88
121.1004 C9H13+ 4 121.1012 -6.65
122.0681 C7[13]CH9O+ 1 122.0687 -5.23
122.104 C8[13]CH13+ 1 122.1051 -8.61
123.0772 C2H16ClO3+ 1 123.0782 -8.2
126.0448 CH12ClFO3+ 4 126.0454 -4.16
127.0288 C7H8Cl+ 1 127.0309 -16.91
127.0533 CH13ClFO3+ 4 127.0532 1.23
128.0611 CH14ClFO3+ 4 128.061 0.91
129.0097 C6H6ClO+ 2 129.0102 -3.96
129.0689 CH15ClFO3+ 4 129.0688 0.79
130.0759 C4H15ClO2+ 4 130.0755 3.1
131.0479 ClFH13O4+ 4 131.0481 -1.11
131.0846 C7H12FO+ 4 131.0867 -15.62
132.0556 ClFH14O4+ 4 132.0559 -2.7
132.0915 C6[13]CH12FO+ 1 132.0906 7.21
133.0402 C6H10ClO+ 2 133.0415 -9.51
133.0628 C3H14ClO3+ 4 133.0626 1.57
133.1001 C10H13+ 4 133.1012 -7.83
134.0706 C3H15ClO3+ 4 134.0704 1.08
134.1025 C9[13]CH13+ 1 134.1051 -19.46
135.0794 C9H11O+ 4 135.0804 -7.68
136.0847 C8[13]CH11O+ 1 136.0843 2.47
137.0941 C3H18ClO3+ 4 137.0939 1.68
139.0304 C8H8Cl+ 2 139.0309 -3.95
139.0545 C11H7+ 4 139.0542 2.31
141.045 C8H10Cl+ 2 141.0466 -10.97
141.0682 C5H14ClO2+ 4 141.0677 3.57
142.076 C5H15ClO2+ 4 142.0755 3.55
143.0252 C7H8ClO+ 2 143.0258 -4.24
143.0611 C8H12Cl+ 2 143.0622 -7.62
143.084 C11H11+ 4 143.0855 -10.83
144.0556 CH14ClFO4+ 4 144.0559 -2.35
144.0896 C10[13]CH11+ 1 144.0894 1.05
145.0219 C7H8[37]ClO+ 1 145.0234 -10.31
145.0636 CH15ClFO4+ 4 145.0637 -1.31
145.0999 C11H13+ 4 145.1012 -8.53
146.0706 C4H15ClO3+ 4 146.0704 1.45
146.1029 C10[13]CH13+ 1 146.1051 -15.04
147.0794 C10H11O+ 4 147.0804 -7.28
148.0825 C9[13]CH11O+ 1 148.0843 -12.76
149.0947 C10H13O+ 4 149.0961 -9.44
150.099 C9[13]CH13O+ 1 150.1 -6.81
151.0736 C3H16ClO4+ 4 151.0732 3.05
152.0612 C3H14ClFO3+ 4 152.061 1.4
153.0461 C9H10Cl+ 2 153.0466 -2.9
153.0695 C12H9+ 4 153.0699 -2.64
154.076 C6H15ClO2+ 4 154.0755 3
155.0593 C9H12Cl+ 1 155.0622 -18.75
155.0839 C6H16ClO2+ 4 155.0833 3.35
156.0561 C2H14ClFO4+ 4 156.0559 1.18
156.0905 C6H17ClO2+ 3 156.0912 -4.02
157.0404 C8H10ClO+ 2 157.0415 -6.6
157.0631 C5H14ClO3+ 4 157.0626 3.22
157.0766 C9H14Cl+ 2 157.0779 -8.26
157.0997 C12H13+ 4 157.1012 -9.28
158.0712 C2H16ClFO4+ 4 158.0716 -2.02
158.1037 C11[13]CH13+ 1 158.1051 -8.49
159.0789 C11H11O+ 4 159.0804 -9.61
160.0669 C5H14ClFO2+ 3 160.0661 4.98
160.0834 C10[13]CH11O+ 1 160.0843 -6.2
161.0591 CH15ClFO5+ 4 161.0587 2.75
161.0946 C11H13O+ 4 161.0961 -9.16
162.0977 C10[13]CH13O+ 1 162.1 -14
163.0745 CH17ClFO5+ 4 163.0743 1.32
163.089 C5H17ClFO2+ 3 163.0896 -3.36
163.1114 C11H15O+ 4 163.1117 -2.28
165.0687 C4H15ClFO3+ 4 165.0688 -0.97
166.0753 C7H15ClO2+ 4 166.0755 -0.96
167.0611 C10H12Cl+ 2 167.0622 -6.53
167.0836 C7H16ClO2+ 4 167.0833 1.41
168.092 C4H18ClFO3+ 4 168.0923 -1.7
169.0391 C9H10ClO+ 2 169.0415 -14.15
169.0629 C6H14ClO3+ 4 169.0626 1.65
169.1003 C4H19ClFO3+ 4 169.1001 1.25
170.0705 C6H15ClO3+ 4 170.0704 0.66
170.108 C4H20ClFO3+ 4 170.108 0.16
171.0564 C9H12ClO+ 3 171.0571 -4.45
171.079 C12H11O+ 4 171.0804 -8.26
171.1153 C4H21ClFO3+ 4 171.1158 -2.69
172.0584 C8[13]CH12ClO+ 1 172.061 -15
172.0842 C11[13]CH11O+ 1 172.0843 -0.92
173.0527 C9H12[37]ClO+ 1 173.0547 -11.38
173.0948 C12H13O+ 4 173.0961 -7.28
174.0984 C11[13]CH13O+ 1 174.1 -9.44
175.0747 C5H16ClO4+ 4 175.0732 9.02
175.0917 C12H12F+ 3 175.0918 -0.03
175.1103 C3H21ClFO4+ 4 175.1107 -2.2
176.0834 C11H12O2+ 4 176.0832 0.99
177.0461 C11H10Cl+ 2 177.0466 -2.78
177.0688 C5H16[37]ClO4+ 1 177.0708 -11.34
177.0889 C5H18ClO4+ 4 177.0888 0.27
178.0761 C8H15ClO2+ 4 178.0755 3.04
179.0844 C5H17ClFO3+ 4 179.0845 -0.6
180.0909 C8H17ClO2+ 4 180.0912 -1.63
181.041 C10H10ClO+ 3 181.0415 -2.36
181.0633 C7H14ClO3+ 4 181.0626 3.85
181.1001 C5H19ClFO3+ 4 181.1001 -0.39
182.0716 C4H16ClFO4+ 4 182.0716 0.15
183.0571 C7H14[37]ClO3+ 1 183.0602 -16.8
183.0788 C7H16ClO3+ 4 183.0782 2.97
183.1154 C5H21ClFO3+ 4 183.1158 -2.24
184.0865 C7H17ClO3+ 4 184.0861 2.53
185.0723 C10H14ClO+ 3 185.0728 -2.71
185.0948 C13H13O+ 4 185.0961 -7.21
186.0747 C9[13]CH14ClO+ 1 186.0767 -10.5
186.1002 C12[13]CH13O+ 1 186.1 1.28
187.0734 C12H11O2+ 4 187.0754 -10.26
187.1105 C4H21ClFO4+ 4 187.1107 -1.17
188.0779 C11[13]CH11O2+ 1 188.0793 -7.23
188.1151 C7H21ClO3+ 3 188.1174 -12.22
189.0693 C6H15ClFO3+ 4 189.0688 2.67
189.0887 C6H18ClO4+ 5 189.0888 -0.54
190.0765 C6H16ClFO3+ 4 190.0767 -0.87
191.0855 C9H16ClO2+ 4 191.0833 11.38
192.0921 C6H18ClFO3+ 4 192.0923 -1.09
193.0782 C9H16[37]ClO2+ 1 193.0809 -14.05
193.0995 C9H18ClO2+ 4 193.099 2.49
194.0709 C8H15ClO3+ 4 194.0704 2.36
194.1065 C9H19ClO2+ 4 194.1068 -1.41
195.0567 C11H12ClO+ 3 195.0571 -2.34
195.0782 C5H17ClFO4+ 4 195.0794 -5.91
195.1153 C15H15+ 4 195.1168 -7.74
196.0872 C5H18ClFO4+ 4 196.0872 -0.28
196.1212 C14[13]CH15+ 1 196.1207 2.38
197.0549 C11H11ClF+ 4 197.0528 10.7
197.0767 C5H17[37]ClFO4+ 1 197.077 -1.52
197.0943 C8H18ClO3+ 4 197.0939 2.2
197.1328 C15H17+ 4 197.1325 1.58
198.102 C8H19ClO3+ 4 198.1017 1.36
199.0728 C7H16ClO4+ 5 199.0732 -1.93
199.1103 C8H20ClO3+ 4 199.1095 3.81
200.1133 C7[13]CH20ClO3+ 1 200.1135 -0.89
201.0884 C7H18ClO4+ 5 201.0888 -1.99
202.0751 C10H15ClO2+ 4 202.0755 -1.78
203.0845 C10H16ClO2+ 4 203.0833 5.64
204.0915 C10H17ClO2+ 4 204.0912 1.76
205.0639 C6H15ClFO4+ 4 205.0637 0.68
205.0763 C10H16[37]ClO2+ 1 205.0809 -22.43
205.0997 C7H19ClFO3+ 4 205.1001 -1.94
206.0715 C6H16ClFO4+ 4 206.0716 -0.35
206.1075 C7H20ClFO3+ 4 206.108 -1.95
207.078 C9H16ClO3+ 4 207.0782 -1.14
207.1165 C16H15+ 4 207.1168 -1.73
208.0862 C9H17ClO3+ 4 208.0861 0.65
208.1211 C15[13]CH15+ 1 208.1207 1.71
209.0953 C6H19ClFO4+ 4 209.095 1.24
209.1296 C10H22ClO2+ 4 209.1303 -3.25
210.1021 C9H19ClO3+ 4 210.1017 1.77
211.0745 C5H17ClFO5+ 4 211.0743 1.15
211.1098 C9H20ClO3+ 4 211.1095 1.1
212.0781 C12H14ClF+ 4 212.0763 8.8
212.1169 C9H21ClO3+ 4 212.1174 -2.05
213.0902 C5H19ClFO5+ 4 213.09 1.34
213.1259 C9H22ClO3+ 4 213.1252 3.34
214.1297 C8[13]CH22ClO3+ 1 214.1291 2.63
215.085 C17H11+ 4 215.0855 -2.27
216.0923 C8H18ClFO3+ 4 216.0923 0.1
217.1005 C8H19ClFO3+ 4 217.1001 1.75
218.07 C10H15ClO3+ 4 218.0704 -1.99
218.1071 C11H19ClO2+ 4 218.1068 1.16
219.0575 C13H12ClO+ 3 219.0571 1.75
219.0797 C7H17ClFO4+ 4 219.0794 1.23
219.1158 C8H21ClFO3+ 4 219.1158 -0.11
220.0862 C10H17ClO3+ 4 220.0861 0.78
220.1244 C17H16+ 4 220.1247 -1.13
221.0948 C7H19ClFO4+ 4 221.095 -1.07
221.1313 C8H23ClFO3+ 4 221.1314 -0.58
222.1011 C10H19ClO3+ 4 222.1017 -2.91
223.1103 C7H21ClFO4+ 4 223.1107 -1.9
224.0819 C6H18ClFO5+ 4 224.0821 -1.02
224.1165 C10H21ClO3+ 4 224.1174 -3.9
225.0917 C12H14FO3+ 4 225.0921 -1.85
225.1258 C16H17O+ 4 225.1274 -7.29
226.0979 C6H20ClFO5+ 4 226.0978 0.37
226.1301 C15[13]CH17O+ 1 226.1313 -5.41
227.0825 C12H16ClO2+ 4 227.0833 -3.72
227.1047 C9H20ClO4+ 5 227.1045 1.01
227.1406 C10H24ClO3+ 4 227.1408 -1.02
228.0906 C12H17ClO2+ 4 228.0912 -2.37
229.0994 C12H18ClO2+ 4 229.099 2
230.1077 C9H20ClFO3+ 4 230.108 -0.97
231.079 C11H16ClO3+ 4 231.0782 3.44
231.1142 C18H15+ 4 231.1168 -11.46
232.0877 C8H18ClFO4+ 4 232.0872 2.06
232.1196 C17[13]CH15+ 1 232.1207 -4.81
233.0716 C11H16[37]ClO3+ 1 233.0758 -18.32
233.0955 C8H19ClFO4+ 4 233.095 1.77
233.1329 C18H17+ 5 233.1325 1.76
234.1025 C8H20ClFO4+ 4 234.1029 -1.46
234.1382 C12H23ClO2+ 4 234.1381 0.43
235.1103 C8H21ClFO4+ 4 235.1107 -1.71
235.1473 C18H19+ 4 235.1481 -3.36
236.1175 C11H21ClO3+ 4 236.1174 0.72
236.153 C17[13]CH19+ 1 236.152 4.25
237.0873 C10H18ClO4+ 5 237.0888 -6.2
237.126 C8H23ClFO4+ 4 237.1263 -1.27
237.162 C12H26ClO2+ 4 237.1616 1.66
238.1319 C11H23ClO3+ 4 238.133 -4.66
239.104 C10H20ClO4+ 5 239.1045 -2.11
239.1423 C11H24ClO3+ 4 239.1408 5.95
240.1449 C10[13]CH24ClO3+ 1 240.1448 0.8
241.0991 C13H18ClO2+ 4 241.099 0.57
242.1058 C13H19ClO2+ 4 242.1068 -4.04
243.1156 C10H21ClFO3+ 4 243.1158 -0.53
244.0867 C9H18ClFO4+ 4 244.0872 -2.28
244.123 C13H21ClO2+ 4 244.1225 2.24
245.0948 C9H19ClFO4+ 4 245.095 -1.06
245.1315 C10H23ClFO3+ 4 245.1314 0.18
246.1028 C9H20ClFO4+ 4 246.1029 -0.32
246.1377 C13H23ClO2+ 4 246.1381 -1.81
247.1111 C9H21ClFO4+ 4 247.1107 1.51
247.1461 C13H24ClO2+ 4 247.1459 0.68
248.1184 C9H22ClFO4+ 4 248.1185 -0.64
249.1255 C12H22ClO3+ 4 249.1252 1.32
249.1621 C13H26ClO2+ 4 249.1616 2.06
250.0945 C11H19ClO4+ 5 250.0966 -8.53
250.1332 C12H23ClO3+ 4 250.133 0.7
250.1701 C13H27ClO2+ 4 250.1694 2.76
251.1058 C8H21ClFO5+ 5 251.1056 0.61
251.1417 C9H25ClFO4+ 4 251.142 -1.04
251.1716 C12[13]CH27ClO2+ 1 251.1733 -6.92
252.1491 C12H25ClO3+ 4 252.1487 1.64
253.1024 C17H14FO+ 5 253.1023 0.5
253.1183 C11H22ClO4+ 5 253.1201 -7.14
253.1584 C12H26ClO3+ 4 253.1565 7.46
254.128 C11H23ClO4+ 5 254.1279 0.09
254.1571 C11[13]CH26ClO3+ 1 254.1604 -12.88
255.1153 C11H21ClFO3+ 4 255.1158 -1.75
256.124 C11H22ClFO3+ 4 256.1236 1.69
257.0928 C13H18ClO3+ 4 257.0939 -4.35
257.1322 C20H17+ 5 257.1325 -1.07
258.103 C10H20ClFO4+ 4 258.1029 0.61
258.1386 C14H23ClO2+ 4 258.1381 1.91
259.11 C13H20ClO3+ 4 259.1095 1.73
259.1474 C11H25ClFO3+ 4 259.1471 1.18
260.1185 C10H22ClFO4+ 4 260.1185 0.06
260.1553 C11H26ClFO3+ 5 260.1549 1.64
261.0854 C16H15ClF+ 4 261.0841 5.15
261.1259 C10H23ClFO4+ 4 261.1263 -1.63
261.1632 C20H21+ 5 261.1638 -2.32
262.0974 C9H20ClFO5+ 5 262.0978 -1.39
262.134 C10H24ClFO4+ 4 262.1342 -0.65
262.1674 C19[13]CH21+ 1 262.1677 -1.15
263.1424 C19H19O+ 4 263.143 -2.44
264.1114 C12H21ClO4+ 5 264.1123 -3.53
264.146 C18[13]CH19O+ 1 264.1469 -3.48
265.1197 C12H22ClO4+ 5 265.1201 -1.56
265.1531 C17[13]C2H19O+ 1 265.1503 10.55
266.1612 C13H27ClO3+ 4 266.1643 -11.68
267.1129 C15H20ClO2+ 4 267.1146 -6.54
267.1391 C15H20FO3+ 4 267.1391 -0.03
267.1737 C10H29ClFO4+ 4 267.1733 1.59
268.1282 C14H20O5+ 5 268.1305 -8.7
269.1338 C18H18FO+ 5 269.1336 0.78
270.1375 C15H23ClO2+ 4 270.1381 -2.43
271.1102 C11H21ClFO4+ 4 271.1107 -1.73
271.1467 C12H25ClFO3+ 4 271.1471 -1.23
272.1176 C14H21ClO3+ 4 272.1174 0.83
273.126 C20H17O+ 4 273.1274 -4.95
273.1614 C15H26ClO2+ 4 273.1616 -0.54
274.1326 C19[13]CH17O+ 1 274.1313 4.74
275.1032 C13H20ClO4+ 5 275.1045 -4.62
275.1408 C14H24ClO3+ 4 275.1408 -0.21
276.1134 C10H22ClFO5+ 5 276.1134 0.04
276.1497 C11H26ClFO4+ 4 276.1498 -0.42
277.1216 C10H23ClFO5+ 5 277.1213 1.13
277.1573 C11H27ClFO4+ 4 277.1576 -1.23
278.1273 C13H23ClO4+ 5 278.1279 -2.35
278.1655 C11H28ClFO4+ 4 278.1655 0.15
279.1383 C19H19O2+ 4 279.138 1.24
279.1711 C11H29ClFO4+ 4 279.1733 -7.83
280.1778 C10[13]CH29ClFO4+ 1 280.1772 2.25
281.1531 C13H26ClO4+ 5 281.1514 5.94
282.1582 C12[13]CH26ClO4+ 1 282.1553 10.27
283.1469 C13H26[37]ClO4+ 1 283.149 -7.33
285.1266 C12H23ClFO4+ 4 285.1263 0.93
285.16 C16H26ClO2+ 4 285.1616 -5.53
286.1341 C12H24ClFO4+ 4 286.1342 -0.17
287.1399 C15H24ClO3+ 4 287.1408 -3.39
288.1495 C21H20O+ 4 288.1509 -4.57
289.1205 C14H22ClO4+ 5 289.1201 1.26
289.1544 C20[13]CH20O+ 1 289.1548 -1.38
290.1311 C17H19FO3+ 4 290.1313 -0.52
291.1369 C14H24ClO4+ 5 291.1358 4.02
291.1737 C12H29ClFO4+ 4 291.1733 1.26
292.1401 C13[13]CH24ClO4+ 1 292.1397 1.61
292.1773 C15H29ClO3+ 4 292.18 -9.26
295.1689 C20H23O2+ 5 295.1693 -1.27
296.1789 C17H25FO3+ 4 296.1782 2.22
299.0786 C18H16ClO2+ 4 299.0833 -15.82
301.1581 C19H22FO2+ 4 301.1598 -5.74
302.1633 C18[13]CH22FO2+ 1 302.1637 -1.39
304.1448 C12H26ClFO5+ 5 304.1447 0.1
305.156 C18H22FO3+ 4 305.1547 3.98
306.1595 C21H22O2+ 5 306.1614 -6.36
307.165 C20[13]CH22O2+ 1 307.1653 -1.14
313.0992 C19H18ClO2+ 4 313.099 0.64
319.1687 C22H23O2+ 5 319.1693 -1.6
327.1469 C21H24ClO+ 4 327.151 -12.57
337.1325 C22H22ClO+ 3 337.1354 -8.41
355.1476 C19H25ClFO3+ 4 355.1471 1.34
PK$NUM_PEAK: 307
PK$PEAK: m/z int. rel.int.
115.0531 2552 44
116.0601 984 17
117.069 1712 29
119.0845 4624 80
120.0882 456 7
121.0638 14604 253
121.1004 2792 48
122.0681 1452 25
122.104 412 7
123.0772 760 13
126.0448 404 7
127.0288 384 6
127.0533 512 8
128.0611 6552 113
129.0097 308 5
129.0689 4180 72
130.0759 1040 18
131.0479 1544 26
131.0846 6008 104
132.0556 3580 62
132.0915 692 12
133.0402 976 16
133.0628 1628 28
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//
