ACCESSION: MSBNK-Eawag-EQ366405
RECORD_TITLE: Danofloxacin; LC-ESI-QFT; MS2; CE: 75; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs M, Schymanski E, Singer H, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3664
CH$NAME: Danofloxacin
CH$NAME: 1-cyclopropyl-6-fluoro-7-(5-methyl-2-aza-5-azoniabicyclo[2.2.1]heptan-2-yl)-4-oxoquinoline-3-carboxylate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C19H20FN3O3
CH$EXACT_MASS: 357.14887
CH$SMILES: CN1C[C@@H]2C[C@H]1CN2C3=C(C=C4C(=C3)N(C=C(C4=O)C(=O)O)C5CC5)F
CH$IUPAC: InChI=1S/C19H20FN3O3/c1-21-7-12-4-11(21)8-22(12)17-6-16-13(5-15(17)20)18(24)14(19(25)26)9-23(16)10-2-3-10/h5-6,9-12H,2-4,7-8H2,1H3,(H,25,26)/t11-,12-/m0/s1
CH$LINK: CAS
112398-08-0
CH$LINK: PUBCHEM
CID:71335
CH$LINK: INCHIKEY
QMLVECGLEOSESV-RYUDHWBXSA-N
CH$LINK: CHEMSPIDER
64439
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 75 (nominal)
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min
AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min
AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 164.9843
MS$FOCUSED_ION: PRECURSOR_M/Z 358.1561
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-001i-9260000000-043723b51191d1927511
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
53.0022 C3HO+ 1 53.0022 -0.21
53.0387 C4H5+ 1 53.0386 1.76
54.0338 C3H4N+ 1 54.0338 0.27
55.0416 C3H5N+ 1 55.0417 -0.19
55.0542 C4H7+ 1 55.0542 0.06
56.0495 C3H6N+ 1 56.0495 0.61
57.0573 C3H7N+ 1 57.0573 -0.01
58.0651 C3H8N+ 1 58.0651 0.07
60.0245 C2H3FN+ 1 60.0244 0.94
65.0386 C5H5+ 2 65.0386 0.36
66.0464 C5H6+ 2 66.0464 0.28
67.0417 C4H5N+ 1 67.0417 0.29
67.0542 C5H7+ 2 67.0542 0.2
68.0495 C4H6N+ 1 68.0495 0.21
69.0699 C5H9+ 2 69.0699 -0.1
70.0651 C4H8N+ 1 70.0651 0.2
75.0479 C3H6FN+ 1 75.0479 0.02
79.0543 C6H7+ 2 79.0542 0.42
80.0495 C5H6N+ 1 80.0495 0.18
81.0573 C5H7N+ 1 81.0573 0.61
82.0651 C5H8N+ 1 82.0651 0.17
83.0729 C5H9N+ 1 83.073 -0.25
84.0808 C5H10N+ 1 84.0808 0.17
94.0652 C6H8N+ 1 94.0651 0.58
95.0492 C6H7O+ 2 95.0491 0.72
96.0808 C6H10N+ 1 96.0808 0.25
97.076 C5H9N2+ 1 97.076 -0.05
97.0887 C6H11N+ 1 97.0886 1.02
105.0449 C6H5N2+ 1 105.0447 1.29
115.0543 C9H7+ 2 115.0542 0.29
128.0498 C9H6N+ 1 128.0495 2.53
128.0622 C10H8+ 2 128.0621 0.85
129.07 C10H9+ 2 129.0699 0.65
133.0449 C9H6F+ 1 133.0448 0.41
135.0481 C8H6FN+ 1 135.0479 1.42
136.0559 C8H7FN+ 1 136.0557 1.37
141.0573 C10H7N+ 1 141.0573 0.14
142.0654 C10H8N+ 1 142.0651 2
145.0651 C10H9O+ 2 145.0648 2.13
146.0528 C10H7F+ 1 146.0526 1.3
146.06 C9H8NO+ 1 146.06 -0.28
147.048 C9H6FN+ 1 147.0479 0.62
147.0605 C10H8F+ 1 147.0605 -0.03
148.0557 C9H7FN+ 1 148.0557 0.11
149.0512 C8H6FN2+ 1 149.051 1.52
151.0431 C8H6FNO+ 1 151.0428 2.03
154.0652 C11H8N+ 1 154.0651 0.48
155.0603 C10H7N2+ 1 155.0604 -0.55
155.0731 C11H9N+ 1 155.073 1.29
156.0683 C10H8N2+ 1 156.0682 0.58
156.0813 C11H10N+ 2 156.0808 3.49
158.0602 C10H8NO+ 1 158.06 1.14
159.0482 C10H6FN+ 1 159.0479 1.77
160.0434 C9H5FN2+ 1 160.0431 1.83
160.0557 C10H7FN+ 1 160.0557 0.29
161.0511 C9H6FN2+ 1 161.051 0.67
161.0635 C10H8FN+ 1 161.0635 -0.06
162.0352 C9H5FNO+ 1 162.035 1.43
162.0588 C9H7FN2+ 1 162.0588 0.07
162.0716 C10H9FN+ 1 162.0714 1.58
163.0668 C9H8FN2+ 1 163.0666 0.96
164.0506 C9H7FNO+ 1 164.0506 0.19
166.0658 C12H8N+ 2 166.0651 3.82
167.0607 C11H7N2+ 1 167.0604 1.77
167.0731 C12H9N+ 1 167.073 1.01
168.0683 C11H8N2+ 1 168.0682 0.72
168.0808 C12H10N+ 1 168.0808 0.26
169.0523 C11H7NO+ 1 169.0522 0.8
169.0761 C11H9N2+ 1 169.076 0.45
172.0558 C11H7FN+ 1 172.0557 0.62
173.0512 C10H6FN2+ 1 173.051 1.2
173.0637 C11H8FN+ 1 173.0635 1.05
174.0351 C10H5FNO+ 1 174.035 0.53
174.0594 C10H7FN2+ 1 174.0588 3.86
174.0714 C11H9FN+ 1 174.0714 0.32
175.0669 C10H8FN2+ 1 175.0666 1.75
176.0508 C10H7FNO+ 1 176.0506 1.2
176.0745 C10H9FN2+ 1 176.0744 0.41
178.0428 C10H7FO2+ 1 178.0425 1.97
178.0539 C9H7FN2O+ 1 178.0537 1.17
178.0661 C10H9FNO+ 1 178.0663 -0.95
179.0381 C9H6FNO2+ 1 179.0377 2.02
179.061 C9H8FN2O+ 2 179.0615 -2.95
180.0809 C13H10N+ 1 180.0808 0.52
181.076 C12H9N2+ 1 181.076 -0.41
182.0605 C12H8NO+ 2 182.06 2.42
182.084 C12H10N2+ 1 182.0838 0.72
183.0916 C12H11N2+ 1 183.0917 -0.24
184.0394 C11H6NO2+ 1 184.0393 0.68
184.0563 C12H7FN+ 1 184.0557 3.08
184.0629 C11H8N2O+ 1 184.0631 -1
185.0639 C12H8FN+ 1 185.0635 1.79
185.071 C11H9N2O+ 1 185.0709 0.17
186.059 C11H7FN2+ 1 186.0588 1.03
186.0714 C12H9FN+ 1 186.0714 0.41
187.0302 C10H4FN2O+ 1 187.0302 0.12
187.0433 C11H6FNO+ 1 187.0428 2.55
187.0668 C11H8FN2+ 1 187.0666 0.89
188.0145 C10H3FNO2+ 1 188.0142 1.63
188.0508 C11H7FNO+ 1 188.0506 0.75
188.0747 C11H9FN2+ 1 188.0744 1.55
188.0874 C12H11FN+ 1 188.087 2.16
189.046 C10H6FN2O+ 1 189.0459 0.49
189.0823 C11H10FN2+ 1 189.0823 0.46
189.0951 C12H12FN+ 1 189.0948 1.54
190.0539 C10H7FN2O+ 1 190.0537 0.83
191.0617 C10H8FN2O+ 1 191.0615 1.11
192.0691 C13H8N2+ 2 192.0682 4.43
192.0809 C14H10N+ 1 192.0808 0.7
193.0762 C13H9N2+ 1 193.076 0.91
193.089 C14H11N+ 2 193.0886 1.91
194.0838 C13H10N2+ 1 194.0838 -0.1
195.0328 C9H6FNO3+ 1 195.0326 0.86
195.0553 C12H7N2O+ 1 195.0553 0
195.0918 C13H11N2+ 1 195.0917 0.49
196.0634 C12H8N2O+ 2 196.0631 1.66
197.0477 C12H7NO2+ 2 197.0471 2.64
197.0708 C12H9N2O+ 1 197.0709 -0.66
197.1075 C13H13N2+ 2 197.1073 1.09
198.0716 C13H9FN+ 1 198.0714 1.19
199.0668 C12H8FN2+ 1 199.0666 0.94
200.0507 C12H7FNO+ 1 200.0506 0.66
200.0745 C12H9FN2+ 1 200.0744 0.26
201.0585 C12H8FNO+ 1 201.0584 0.53
201.0823 C12H10FN2+ 1 201.0823 0.08
202.0303 C11H5FNO2+ 1 202.0299 2.06
202.054 C11H7FN2O+ 1 202.0537 1.42
202.0664 C12H9FNO+ 1 202.0663 0.5
202.09 C12H11FN2+ 1 202.0901 -0.14
203.0616 C11H8FN2O+ 1 203.0615 0.55
203.098 C12H12FN2+ 1 203.0979 0.48
205.0538 C11H8FNO2+ 1 205.0534 2.11
205.0772 C11H10FN2O+ 1 205.0772 0.3
206.0844 C14H10N2+ 2 206.0838 2.62
207.0922 C14H11N2+ 2 207.0917 2.34
209.0712 C13H9N2O+ 2 209.0709 1.25
209.1075 C14H13N2+ 2 209.1073 0.84
211.0662 C13H8FN2+ 1 211.0666 -1.96
211.0876 C13H11N2O+ 2 211.0866 4.6
212.0748 C13H9FN2+ 1 212.0744 1.66
212.0873 C14H11FN+ 1 212.087 1.49
213.0457 C12H6FN2O+ 2 213.0459 -0.79
213.0826 C13H10FN2+ 1 213.0823 1.53
213.0947 C14H12FN+ 1 213.0948 -0.42
214.0666 C13H9FNO+ 1 214.0663 1.6
214.0904 C13H11FN2+ 1 214.0901 1.36
215.0253 C11H4FN2O2+ 1 215.0251 0.69
215.0618 C12H8FN2O+ 1 215.0615 1.27
215.0976 C13H12FN2+ 1 215.0979 -1.27
216.0697 C12H9FN2O+ 1 216.0693 1.79
216.0823 C13H11FNO+ 1 216.0819 1.86
217.0409 C11H6FN2O2+ 1 217.0408 0.73
217.0774 C12H10FN2O+ 1 217.0772 1.02
218.0488 C11H7FN2O2+ 1 218.0486 1.11
219.0924 C12H12FN2O+ 2 219.0928 -1.77
220.0408 C11H7FNO3+ 1 220.0404 1.37
221.0484 C11H8FNO3+ 1 221.0483 0.53
221.0713 C14H9N2O+ 2 221.0709 1.63
221.1077 C15H13N2+ 2 221.1073 1.61
222.0435 C10H7FN2O3+ 1 222.0435 -0.14
222.0798 C14H10N2O+ 2 222.0788 4.75
223.0504 C13H7N2O2+ 2 223.0502 0.66
223.0865 C14H11N2O+ 1 223.0866 -0.27
224.0748 C14H9FN2+ 1 224.0744 1.84
225.0824 C14H10FN2+ 1 225.0823 0.83
226.0535 C13H7FN2O+ 2 226.0537 -0.98
226.0904 C14H11FN2+ 1 226.0901 1.56
227.0617 C13H8FN2O+ 1 227.0615 0.85
227.098 C14H12FN2+ 1 227.0979 0.29
228.0539 C12H8N2O3+ 1 228.0529 4.06
228.0695 C13H9FN2O+ 1 228.0693 0.69
228.0822 C14H11FNO+ 1 228.0819 1.01
229.0411 C12H6FN2O2+ 1 229.0408 1.48
229.0773 C13H10FN2O+ 1 229.0772 0.58
230.0485 C12H7FN2O2+ 2 230.0486 -0.42
230.0853 C13H11FN2O+ 1 230.085 1.42
231.0563 C12H8FN2O2+ 2 231.0564 -0.57
231.0931 C13H12FN2O+ 1 231.0928 1.01
233.036 C11H6FN2O3+ 1 233.0357 1.34
233.048 C12H8FNO3+ 2 233.0483 -0.96
234.0565 C12H9FNO3+ 1 234.0561 1.55
235.0514 C11H8FN2O3+ 1 235.0513 0.23
235.0641 C12H10FNO3+ 1 235.0639 0.58
235.087 C15H11N2O+ 2 235.0866 1.79
236.0592 C11H9FN2O3+ 1 236.0592 0.29
237.1022 C15H13N2O+ 2 237.1022 -0.04
238.098 C14H12N3O+ 3 238.0975 2.19
239.0615 C14H8FN2O+ 2 239.0615 0.09
239.0979 C15H12FN2+ 1 239.0979 0.15
240.07 C14H9FN2O+ 1 240.0693 2.86
240.0815 C15H11FNO+ 2 240.0819 -1.87
240.1059 C15H13FN2+ 1 240.1057 0.84
241.0772 C14H10FN2O+ 1 241.0772 0.3
241.1141 C15H14FN2+ 1 241.1136 2.1
242.0855 C14H11FN2O+ 1 242.085 2.22
243.0564 C13H8FN2O2+ 2 243.0564 -0.09
243.0928 C14H12FN2O+ 2 243.0928 0.09
245.0726 C13H10FN2O2+ 1 245.0721 2.28
245.1089 C14H14FN2O+ 1 245.1085 1.76
246.0566 C13H9FNO3+ 1 246.0561 1.96
247.052 C12H8FN2O3+ 1 247.0513 2.48
248.1185 C16H14N3+ 3 248.1182 1.23
252.1131 C15H14N3O+ 2 252.1131 -0.11
253.0774 C15H10FN2O+ 1 253.0772 0.8
254.0483 C14H7FN2O2+ 2 254.0486 -1.01
255.0566 C14H8FN2O2+ 1 255.0564 0.54
256.0644 C14H9FN2O2+ 2 256.0643 0.52
257.0724 C14H10FN2O2+ 1 257.0721 1.2
257.1087 C15H14FN2O+ 1 257.1085 0.79
261.0674 C13H10FN2O3+ 1 261.067 1.66
263.0832 C13H12FN2O3+ 1 263.0826 2.14
264.0769 C15H10N3O2+ 3 264.0768 0.67
267.0925 C16H12FN2O+ 2 267.0928 -1.08
268.1001 C16H13FN2O+ 2 268.1006 -2.02
269.0722 C15H10FN2O2+ 2 269.0721 0.59
269.1081 C16H14FN2O+ 2 269.1085 -1.25
271.1243 C16H16FN2O+ 2 271.1241 0.71
273.0672 C14H10FN2O3+ 2 273.067 0.56
274.0751 C14H11FN2O3+ 1 274.0748 1.09
275.0828 C14H12FN2O3+ 2 275.0826 0.7
277.0989 C14H14FN2O3+ 1 277.0983 2.18
278.0924 C16H12N3O2+ 3 278.0924 0.1
279.1007 C16H13N3O2+ 3 279.1002 1.62
281.1091 C17H14FN2O+ 1 281.1085 2.36
282.0883 C15H12N3O3+ 1 282.0873 3.55
283.1244 C17H16FN2O+ 1 283.1241 0.89
284.0827 C15H11FN3O2+ 2 284.083 -0.85
287.0832 C15H12FN2O3+ 1 287.0826 1.86
289.0983 C15H14FN2O3+ 2 289.0983 -0.02
298.0986 C16H13FN3O2+ 3 298.0986 0.03
301.0985 C16H14FN2O3+ 2 301.0983 0.57
315.1143 C17H16FN2O3+ 1 315.1139 1.02
340.1465 C19H19FN3O2+ 1 340.1456 2.58
358.1564 C19H21FN3O3+ 1 358.1561 0.74
PK$NUM_PEAK: 234
PK$PEAK: m/z int. rel.int.
53.0022 4791.7 5
53.0387 3144 3
54.0338 1755.5 2
55.0416 1094.4 1
55.0542 7582.2 9
56.0495 4253 5
57.0573 4927.9 6
58.0651 1964 2
60.0245 1809.9 2
65.0386 8697.1 10
66.0464 1792.5 2
67.0417 45351 55
67.0542 11054.9 13
68.0495 33191 40
69.0699 2644.1 3
70.0651 84642.6 103
75.0479 4317.9 5
79.0543 12631.1 15
80.0495 32185.5 39
81.0573 41976 51
82.0651 818498.9 999
83.0729 107326.6 130
84.0808 25880.9 31
94.0652 59211.1 72
95.0492 2866.8 3
96.0808 58711.1 71
97.076 7223.4 8
97.0887 1855.2 2
105.0449 2082.5 2
115.0543 857.4 1
128.0498 1691.2 2
128.0622 1058.5 1
129.07 2023.5 2
133.0449 2332.6 2
135.0481 3610 4
136.0559 2494.2 3
141.0573 2226.9 2
142.0654 1636 1
145.0651 1984.7 2
146.0528 3244.7 3
146.06 823.4 1
147.048 2032.8 2
147.0605 4588.9 5
148.0557 5886.2 7
149.0512 2787 3
151.0431 871.1 1
154.0652 12229 14
155.0603 6542.2 7
155.0731 3354.5 4
156.0683 1830.5 2
156.0813 1496 1
158.0602 900.5 1
159.0482 2187 2
160.0434 3015.6 3
160.0557 5741.8 7
161.0511 2568.6 3
161.0635 4280.8 5
162.0352 2493 3
162.0588 5075.6 6
162.0716 2882.6 3
163.0668 1980.8 2
164.0506 4795.6 5
166.0658 1789.3 2
167.0607 4014.1 4
167.0731 1683.5 2
168.0683 7424.6 9
168.0808 937.9 1
169.0523 869.3 1
169.0761 5034.8 6
172.0558 21150.4 25
173.0512 2894.4 3
173.0637 11247 13
174.0351 1736.5 2
174.0594 4194.5 5
174.0714 13757.1 16
175.0669 6558.9 8
176.0508 1716.7 2
176.0745 2963.7 3
178.0428 1610 1
178.0539 11402.5 13
178.0661 8224.7 10
179.0381 1955 2
179.061 4522.4 5
180.0809 935.3 1
181.076 3604.3 4
182.0605 2383.4 2
182.084 2243.7 2
183.0916 3224.5 3
184.0394 2296.8 2
184.0563 943.5 1
184.0629 3499.8 4
185.0639 5034.7 6
185.071 1295.9 1
186.059 7651.9 9
186.0714 5792 7
187.0302 3985.1 4
187.0433 4004.8 4
187.0668 38820.7 47
188.0145 2146.1 2
188.0508 3383.6 4
188.0747 4730.8 5
188.0874 2786.9 3
189.046 8141.2 9
189.0823 6288.4 7
189.0951 2550 3
190.0539 5864 7
191.0617 5112.2 6
192.0691 2233.5 2
192.0809 2877.1 3
193.0762 5951.8 7
193.089 989 1
194.0838 2351.9 2
195.0328 903.1 1
195.0553 3081.2 3
195.0918 1821.1 2
196.0634 6618.6 8
197.0477 2005.6 2
197.0708 3474.5 4
197.1075 6369.7 7
198.0716 2670.8 3
199.0668 13001.5 15
200.0507 6288.9 7
200.0745 7080.3 8
201.0585 15903.9 19
201.0823 6069.4 7
202.0303 1968.3 2
202.054 2568.6 3
202.0664 37362.1 45
202.09 4693.2 5
203.0616 31404.4 38
203.098 3311.5 4
205.0538 3592 4
205.0772 2870.8 3
206.0844 1706.7 2
207.0922 2923.7 3
209.0712 2594.7 3
209.1075 931.3 1
211.0662 3544.1 4
211.0876 1068.5 1
212.0748 5154.4 6
212.0873 12261.7 14
213.0457 885 1
213.0826 11830.2 14
213.0947 3102.7 3
214.0666 3147.8 3
214.0904 13091.5 15
215.0253 35647.9 43
215.0618 50325.1 61
215.0976 4704.5 5
216.0697 9143.8 11
216.0823 1819.4 2
217.0409 10572.7 12
217.0774 9322.4 11
218.0488 23567 28
219.0924 5240.4 6
220.0408 1637.3 1
221.0484 1049.1 1
221.0713 3718.8 4
221.1077 2533.9 3
222.0435 1982.6 2
222.0798 831.5 1
223.0504 927.4 1
223.0865 991.4 1
224.0748 2064.9 2
225.0824 2681.8 3
226.0535 2373.2 2
226.0904 2861.4 3
227.0617 12246.6 14
227.098 4906.8 5
228.0539 1799.9 2
228.0695 2867.2 3
228.0822 1856.3 2
229.0411 1059.9 1
229.0773 16506.7 20
230.0485 2174 2
230.0853 3690.1 4
231.0563 2077.5 2
231.0931 13224 16
233.036 15608.6 19
233.048 2513.9 3
234.0565 2104.5 2
235.0514 6352.1 7
235.0641 2561.7 3
235.087 2446.6 2
236.0592 9716.6 11
237.1022 10328.1 12
238.098 5722.5 6
239.0615 1701.9 2
239.0979 11121.2 13
240.07 1049.3 1
240.0815 850.1 1
240.1059 3622.7 4
241.0772 13963.2 17
241.1141 1043.4 1
242.0855 3367.2 4
243.0564 5002.1 6
243.0928 3613.4 4
245.0726 1785.2 2
245.1089 2117.1 2
246.0566 974.9 1
247.052 2813.6 3
248.1185 989 1
252.1131 3478.4 4
253.0774 2776.2 3
254.0483 7915.1 9
255.0566 246739 301
256.0644 13540 16
257.0724 2220.8 2
257.1087 1929.7 2
261.0674 2236.8 2
263.0832 863.8 1
264.0769 2906.7 3
267.0925 4537.2 5
268.1001 1617 1
269.0722 1754.6 2
269.1081 915.7 1
271.1243 6903.1 8
273.0672 68332.3 83
274.0751 3661 4
275.0828 5938.1 7
277.0989 3541.9 4
278.0924 2182.3 2
279.1007 2827.6 3
281.1091 1908.2 2
282.0883 912.1 1
283.1244 1966.3 2
284.0827 2283 2
287.0832 3130.9 3
289.0983 3106.6 3
298.0986 3527.9 4
301.0985 2774.3 3
315.1143 1804 2
340.1465 2106.4 2
358.1564 30660 37
//
