ACCESSION: MSBNK-Eawag-EQ366609
RECORD_TITLE: Difloxacin; LC-ESI-QFT; MS2; CE: 180; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs M, Schymanski E, Singer H, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3666
CH$NAME: Difloxacin
CH$NAME: 6-fluoro-1-(4-fluorophenyl)-7-(4-methylpiperazin-1-yl)-4-oxoquinoline-3-carboxylic acid
CH$NAME: 6-fluoro-1-(4-fluorophenyl)-7-(4-methylpiperazin-4-ium-1-yl)-4-oxoquinoline-3-carboxylate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C21H19F2N3O3
CH$EXACT_MASS: 399.1394479
CH$SMILES: CN1CCN(CC1)C2=C(C=C3C(=C2)N(C=C(C3=O)C(=O)O)C4=CC=C(C=C4)F)F
CH$IUPAC: InChI=1S/C21H19F2N3O3/c1-24-6-8-25(9-7-24)19-11-18-15(10-17(19)23)20(27)16(21(28)29)12-26(18)14-4-2-13(22)3-5-14/h2-5,10-12H,6-9H2,1H3,(H,28,29)
CH$LINK: CAS
98106-17-3
CH$LINK: CHEBI
4537
CH$LINK: CHEMSPIDER
50725
CH$LINK: COMPTOX
DTXSID5048348
CH$LINK: INCHIKEY
NOCJXYPHIIZEHN-UHFFFAOYSA-N
CH$LINK: KEGG
C11234
CH$LINK: PUBCHEM
CID:56206
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 180 (nominal)
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min
AC$CHROMATOGRAPHY: RETENTION_TIME 4.5 min
AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 400.1461
MS$FOCUSED_ION: PRECURSOR_M/Z 400.1467
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-0a7i-7910000000-6721a1b8ea16086eaca1
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
50.0152 C4H2+ 1 50.0151 1.37
51.023 C4H3+ 1 51.0229 1.64
52.0183 C3H2N+ 1 52.0182 2.39
53.0022 C3HO+ 1 53.0022 1.11
53.0386 C4H5+ 1 53.0386 1.01
53.9975 C2NO+ 1 53.9974 1.3
54.0339 C3H4N+ 1 54.0338 0.82
55.0416 C3H5N+ 1 55.0417 -0.74
56.0495 C3H6N+ 1 56.0495 1.15
57.0136 C3H2F+ 1 57.0135 1.15
58.0652 C3H8N+ 1 58.0651 0.76
59.0292 C3H4F+ 1 59.0292 0.94
61.0073 C5H+ 2 61.0073 1.04
62.0151 C5H2+ 2 62.0151 0.78
63.023 C5H3+ 2 63.0229 1.01
64.0183 C4H2N+ 1 64.0182 1.48
65.0261 C4H3N+ 1 65.026 1.99
65.0386 C5H5+ 2 65.0386 0.67
67.0417 C4H5N+ 1 67.0417 1.18
68.0057 C4HF+ 1 68.0057 0.89
68.0496 C4H6N+ 1 68.0495 1.39
69.0136 C4H2F+ 1 69.0135 1.24
70.0214 C4H3F+ 1 70.0213 1.29
70.0652 C4H8N+ 1 70.0651 0.63
74.0151 C6H2+ 2 74.0151 0.52
75.023 C6H3+ 2 75.0229 0.45
76.0182 C5H2N+ 1 76.0182 0.06
76.0308 C6H4+ 2 76.0308 0.11
77.0022 C5HO+ 2 77.0022 0.12
77.0386 C6H5+ 2 77.0386 0.43
78.0339 C5H4N+ 1 78.0338 0.7
78.0465 C6H6+ 2 78.0464 1.13
80.0495 C5H6N+ 1 80.0495 0.05
81.0136 C5H2F+ 2 81.0135 0.68
82.0087 C4HFN+ 1 82.0088 -0.9
82.0214 C5H3F+ 2 82.0213 0.73
82.0651 C5H8N+ 1 82.0651 0.17
83.0292 C5H4F+ 2 83.0292 0.54
84.0371 C5H5F+ 2 84.037 1.55
85.0074 C7H+ 2 85.0073 1.22
86.0152 C7H2+ 2 86.0151 1.03
87.0104 C6HN+ 1 87.0104 0.34
87.023 C7H3+ 2 87.0229 1.07
88.0182 C6H2N+ 1 88.0182 0.62
88.0308 C7H4+ 2 88.0308 0.89
89.0386 C7H5+ 2 89.0386 0.71
90.0341 C6H4N+ 1 90.0338 2.94
90.0465 C7H6+ 2 90.0464 1.09
91.0544 C7H7+ 2 91.0542 2.34
92.0257 C6H4O+ 2 92.0257 0.37
93.0137 C6H2F+ 2 93.0135 1.78
94.0215 C6H3F+ 2 94.0213 1.49
95.0293 C6H4F+ 2 95.0292 1.42
95.0493 C6H7O+ 2 95.0491 1.14
96.0371 C6H5F+ 2 96.037 1.04
96.0444 C5H6NO+ 1 96.0444 0.41
97.0448 C6H6F+ 2 97.0448 0.26
98.0152 C8H2+ 2 98.0151 0.7
99.0104 C7HN+ 1 99.0104 0.6
99.023 C8H3+ 2 99.0229 0.84
100.0182 C7H2N+ 1 100.0182 0.45
100.0309 C8H4+ 2 100.0308 1.68
101.0387 C8H5+ 2 101.0386 0.83
102.034 C7H4N+ 1 102.0338 1.42
102.0465 C8H6+ 2 102.0464 0.96
103.0416 C7H5N+ 1 103.0417 -0.3
104.0495 C7H6N+ 1 104.0495 0.43
105.0136 C7H2F+ 2 105.0135 1.29
105.0448 C6H5N2+ 1 105.0447 1.19
106.0089 C6HFN+ 1 106.0088 1.38
106.0214 C7H3F+ 2 106.0213 0.66
107.0292 C7H4F+ 2 107.0292 0.8
108.0245 C6H3FN+ 1 108.0244 0.8
108.037 C7H5F+ 2 108.037 0.09
109.0449 C7H6F+ 2 109.0448 1.15
111.0229 C9H3+ 2 111.0229 0.12
112.0183 C8H2N+ 1 112.0182 1.56
112.0319 C6H5FO+ 2 112.0319 -0.4
113.0262 C8H3N+ 1 113.026 1.5
113.0391 CH5F2N3O+ 2 113.0395 -3.98
114.0339 C8H4N+ 1 114.0338 1
115.0418 C8H5N+ 1 115.0417 1.56
115.0543 C9H7+ 2 115.0542 0.9
116.0495 C8H6N+ 1 116.0495 0.47
117.0574 C8H7N+ 1 117.0573 1.02
118.0214 C8H3F+ 2 118.0213 0.34
119.0294 C8H4F+ 2 119.0292 1.72
119.0493 C8H7O+ 2 119.0491 1.17
120.0371 C8H5F+ 2 120.037 0.92
120.0444 C7H6NO+ 1 120.0444 -0.17
121.0324 C7H4FN+ 1 121.0322 1.5
122.0402 C7H5FN+ 1 122.0401 1.12
123.023 C10H3+ 2 123.0229 0.43
123.0354 C6H4FN2+ 1 123.0353 0.47
124.0184 C9H2N+ 1 124.0182 2.05
125.0199 C7H3F2+ 1 125.0197 1.02
125.0386 C10H5+ 2 125.0386 0.51
126.0344 C9H4N+ 2 126.0338 4.56
126.0466 C10H6+ 2 126.0464 1.73
127.0417 C9H5N+ 1 127.0417 0.7
127.0544 C10H7+ 2 127.0542 1.36
128.0496 C9H6N+ 1 128.0495 1.05
128.0623 C10H8+ 2 128.0621 1.78
129.0448 C8H5N2+ 1 129.0447 0.82
130.0402 C7H4N3+ 1 130.04 1.66
130.0654 C9H8N+ 1 130.0651 2.19
131.0293 C9H4F+ 2 131.0292 1.18
132.0246 C8H3FN+ 1 132.0244 1.71
132.0374 C9H5F+ 2 132.037 2.88
133.0326 C8H4FN+ 1 133.0322 2.57
133.0449 C9H6F+ 2 133.0448 0.94
134.0401 C8H5FN+ 1 134.0401 -0.03
135.0481 C8H6FN+ 1 135.0479 1.86
137.0389 C11H5+ 3 137.0386 2.43
138.0341 C10H4N+ 1 138.0338 1.77
139.0543 C11H7+ 2 139.0542 0.67
140.0496 C10H6N+ 1 140.0495 0.67
141.0576 C10H7N+ 1 141.0573 1.84
142.0527 C9H6N2+ 1 142.0525 1.2
143.0293 C10H4F+ 2 143.0292 0.88
144.0371 C10H5F+ 2 144.037 1.04
144.0447 C9H6NO+ 1 144.0444 2.01
145.0326 C9H4FN+ 1 145.0322 2.42
145.0448 C10H6F+ 2 145.0448 -0.31
146.0402 C9H5FN+ 1 146.0401 0.66
146.0529 C10H7F+ 2 146.0526 1.92
147.0354 C8H4FN2+ 1 147.0353 0.73
148.0183 C11H2N+ 1 148.0182 0.91
148.031 C12H4+ 3 148.0308 1.61
148.0558 C9H7FN+ 1 148.0557 0.92
149.02 C9H3F2+ 1 149.0197 2.13
149.0389 C4H5F2N3O+ 3 149.0395 -4.43
150.0467 C12H6+ 3 150.0464 1.72
151.0356 C9H5F2+ 1 151.0354 1.57
151.0415 C11H5N+ 1 151.0417 -1.13
152.05 C8H7FNO+ 2 152.0506 -4.26
153.0447 C10H5N2+ 1 153.0447 -0.16
153.0577 C11H7N+ 2 153.0573 2.87
154.0402 C9H4N3+ 1 154.04 1.21
155.0293 C11H4F+ 2 155.0292 1.26
155.0606 C10H7N2+ 1 155.0604 1.65
156.0246 C10H3FN+ 1 156.0244 1.19
156.037 C11H5F+ 2 156.037 0.07
157.045 C11H6F+ 2 157.0448 1.5
158.0402 C10H5FN+ 1 158.0401 1.24
160.0558 C10H7FN+ 1 160.0557 0.54
161.0388 C13H5+ 3 161.0386 1.57
162.0275 C10H4F2+ 1 162.0276 -0.3
162.0342 C9H5FNO+ 2 162.035 -4.87
162.0462 C8H5FN3+ 2 162.0462 -0.01
163.0544 C13H7+ 3 163.0542 1.25
167.0294 C12H4F+ 2 167.0292 1.59
167.0493 C12H7O+ 3 167.0491 0.89
168.0372 C12H5F+ 2 168.037 1.37
169.0326 C11H4FN+ 2 169.0322 1.96
169.045 C12H6F+ 2 169.0448 1.27
169.065 C12H9O+ 3 169.0648 1.23
170.0403 C11H5FN+ 1 170.0401 1.27
170.0526 C12H7F+ 2 170.0526 -0.06
170.0599 C11H8NO+ 1 170.06 -1.06
171.048 C11H6FN+ 1 171.0479 0.47
173.0199 C11H3F2+ 1 173.0197 1.08
173.0389 C14H5+ 4 173.0386 1.81
173.0515 C10H6FN2+ 2 173.051 3.05
174.0277 C11H4F2+ 1 174.0276 1.1
174.0344 C10H5FNO+ 2 174.035 -3.04
174.0466 C14H6+ 3 174.0464 0.97
175.0355 C11H5F2+ 1 175.0354 0.73
175.0422 C13H5N+ 2 175.0417 2.91
176.0309 C10H4F2N+ 1 176.0306 1.81
176.0501 C10H7FNO+ 2 176.0506 -3.12
177.0453 C9H6FN2O+ 2 177.0459 -2.98
177.0577 C13H7N+ 2 177.0573 2.03
179.0294 C13H4F+ 2 179.0292 1.15
180.0372 C13H5F+ 2 180.037 1.22
181.045 C13H6F+ 2 181.0448 0.86
182.0402 C12H5FN+ 1 182.0401 0.64
182.0529 C13H7F+ 3 182.0526 1.54
183.0608 C13H8F+ 3 183.0605 2.05
184.0319 C12H5FO+ 2 184.0319 0.14
184.0559 C12H7FN+ 2 184.0557 1.34
186.0267 C12H4F2+ 1 186.0276 -4.56
186.0352 C11H5FNO+ 2 186.035 1.51
187.0554 C12H8FO+ 2 187.0554 0
188.0432 C12H6F2+ 1 188.0432 0.01
188.05 C11H7FNO+ 2 188.0506 -3.29
189.0575 C14H7N+ 1 189.0573 0.84
190.0655 C14H8N+ 2 190.0651 2.18
192.037 C14H5F+ 2 192.037 0.16
192.0446 C13H6NO+ 2 192.0444 0.99
193.0327 C13H4FN+ 2 193.0322 2.49
193.0453 C14H6F+ 3 193.0448 2.46
193.0649 C14H9O+ 3 193.0648 0.3
194.0402 C13H5FN+ 1 194.0401 0.8
194.0528 C14H7F+ 3 194.0526 0.93
194.0608 C10H9FNO2+ 2 194.0612 -2.18
195.0481 C13H6FN+ 2 195.0479 1.19
196.0559 C13H7FN+ 2 196.0557 1
197.02 C13H3F2+ 1 197.0197 1.41
197.051 C12H6FN2+ 1 197.051 0.04
198.0278 C13H4F2+ 1 198.0276 1.07
199.0354 C13H5F2+ 1 199.0354 -0.07
200.0308 C12H4F2N+ 1 200.0306 1.04
200.0431 C13H6F2+ 1 200.0432 -0.64
200.0509 C12H7FNO+ 2 200.0506 1.21
202.0464 C12H6F2N+ 1 202.0463 0.78
202.0653 C12H9FNO+ 2 202.0663 -4.55
204.038 C12H6F2O+ 1 204.0381 -0.6
204.0557 C13H6N3+ 1 204.0556 0.42
205.0324 C14H4FN+ 2 205.0322 0.98
205.0451 C15H6F+ 3 205.0448 1.39
206.0404 C14H5FN+ 2 206.0401 1.53
207.0481 C14H6FN+ 2 207.0479 1.16
207.061 C15H8F+ 3 207.0605 2.49
208.0559 C14H7FN+ 2 208.0557 1.13
209.0639 C14H8FN+ 2 209.0635 1.54
210.0281 C14H4F2+ 1 210.0276 2.72
211.0443 C10H7F2NO2+ 1 211.0439 1.53
212.0276 C10H6F2O3+ 3 212.028 -1.57
212.0417 C6H6N5O4+ 1 212.0414 1.18
212.0506 C13H7FNO+ 1 212.0506 -0.18
213.0386 C13H5F2N+ 1 213.0385 0.77
214.0455 C13H6F2N+ 1 214.0463 -3.56
215.0423 C12H5F2N2+ 1 215.0415 3.39
218.0399 C15H5FN+ 1 218.0401 -0.52
218.0599 C15H8NO+ 1 218.06 -0.6
219.048 C15H6FN+ 2 219.0479 0.6
220.0561 C15H7FN+ 2 220.0557 1.75
221.0512 C11H7F2N2O+ 2 221.0521 -4.23
221.0636 C15H8FN+ 2 221.0635 0.5
222.0465 C10H6F2N3O+ 4 222.0473 -3.76
222.0712 C15H9FN+ 1 222.0714 -0.47
224.0309 C14H4F2N+ 1 224.0306 1.24
225.0393 C14H5F2N+ 1 225.0385 3.66
225.0494 C7H7N5O4+ 1 225.0493 0.73
226.0465 C14H6F2N+ 1 226.0463 0.88
227.0534 C14H7F2N+ 1 227.0541 -2.94
228.0559 C15H6N3+ 3 228.0556 1.3
230.0405 C13H6F2NO+ 2 230.0412 -3.16
232.0558 C16H7FN+ 2 232.0557 0.33
233.0514 C15H6FN2+ 2 233.051 1.79
233.0632 C16H8FN+ 1 233.0635 -1.63
234.0589 C15H7FN2+ 2 234.0588 0.39
237.0387 C15H5F2N+ 1 237.0385 1.11
238.046 C15H6F2N+ 1 238.0463 -1.39
238.0667 C15H9FNO+ 2 238.0663 1.85
239.0543 C15H7F2N+ 1 239.0541 0.72
257.0293 C14H5F2NO2+ 1 257.0283 3.94
PK$NUM_PEAK: 259
PK$PEAK: m/z int. rel.int.
50.0152 802984.9 143
51.023 881526.2 157
52.0183 29360.4 5
53.0022 349290.7 62
53.0386 211933 37
53.9975 17756.7 3
54.0339 87305.5 15
55.0416 19280.8 3
56.0495 538075.9 96
57.0136 3065300.5 546
58.0652 409006.6 72
59.0292 132902.2 23
61.0073 447783.1 79
62.0151 1001221.8 178
63.023 2318325.5 413
64.0183 168837.3 30
65.0261 31683.2 5
65.0386 246109.5 43
67.0417 207618.4 37
68.0057 124594 22
68.0496 29407.2 5
69.0136 133961.9 23
70.0214 251494.2 44
70.0652 83092.7 14
74.0151 2809420 501
75.023 5598672 999
76.0182 289082.9 51
76.0308 311802.3 55
77.0022 85870.7 15
77.0386 289109.1 51
78.0339 145034 25
78.0465 108019.1 19
80.0495 37027.2 6
81.0136 1913906.9 341
82.0087 162230.9 28
82.0214 124592.6 22
82.0651 125823.5 22
83.0292 1471224.4 262
84.0371 79862.2 14
85.0074 200866.5 35
86.0152 532272.6 94
87.0104 132486.7 23
87.023 825435.9 147
88.0182 325141.9 58
88.0308 234758.9 41
89.0386 1420671.6 253
90.0341 30957.7 5
90.0465 96707.5 17
91.0544 43224.7 7
92.0257 18979.7 3
93.0137 165172.9 29
94.0215 466031.7 83
95.0293 212792.6 37
95.0493 532068.6 94
96.0371 155534.5 27
96.0444 157110.7 28
97.0448 20281.6 3
98.0152 829065.2 147
99.0104 120097.4 21
99.023 1013774.8 180
100.0182 455900.4 81
100.0309 151606.8 27
101.0387 172852.5 30
102.034 118516 21
102.0465 398620.6 71
103.0416 34954.3 6
104.0495 75460.2 13
105.0136 718137.3 128
105.0448 350922.5 62
106.0089 109338.1 19
106.0214 334684.8 59
107.0292 3833801.5 684
108.0245 152554.2 27
108.037 174969.9 31
109.0449 225214.4 40
110.0152 241630.7031 43
111.0229 283331.5 50
112.0183 152068.3 27
112.0319 43554.8 7
113.0262 26387.3 4
113.0391 399082.5 71
114.0339 282457.4 50
115.0418 90174.3 16
115.0543 357075.8 63
116.0495 25926.8 4
117.0574 20569.7 3
118.0214 78915.7 14
119.0294 30557.1 5
119.0493 118173.1 21
120.0371 444440.7 79
120.0444 34613.6 6
121.0324 83700.2 14
122.0152 261071.1094 46
122.0402 146767.8 26
123.0105 104156.6328 18
123.023 626505.8 111
123.0354 415810.9 74
124.0184 231667.3 41
125.0199 145690.5 25
125.0386 146054.9 26
126.0344 169932 30
126.0466 76482.7 13
127.0417 43921.7 7
127.0544 17159.7 3
128.0496 377517.9 67
128.0623 22344.5 3
129.0136 203676.7031 36
129.0448 483684.9 86
130.0402 81817.3 14
130.0654 23366.8 4
131.0293 1204776.4 214
132.0246 348837.3 62
132.0374 100144.4 17
133.0326 43098.5 7
133.0449 599902.6 107
134.0401 148359.9 26
135.0481 78477.5 14
137.0389 208367.8 37
138.0341 93662.4 16
139.0543 88405.9 15
140.0496 190109.7 33
141.0576 118266.3 21
142.0527 27545.5 4
143.0293 123750.7 22
144.0371 343919 61
144.0447 31368.5 5
145.0326 85494.6 15
145.0448 20810.9 3
146.0152 128889.5625 22
146.0402 202855.4 36
146.0529 31677.2 5
147.023 206482.5781 36
147.0354 92173.1 16
148.0183 109116.9 19
148.031 42377.1 7
148.0558 84047.6 14
149.02 305926.2 54
149.0389 277944 49
150.0467 351782.6 62
151.0356 323826.4 57
151.0415 40389 7
152.05 66771.9 11
153.0447 19808.1 3
153.0577 21951.7 3
154.0402 187351.3 33
155.0293 964439.1 172
155.0606 103337 18
156.0246 184292.6 32
156.037 179563.6 32
157.045 471795.8 84
158.0402 540096.8 96
160.0558 24588.8 4
161.0388 837747.9 149
162.0275 113872 20
162.0342 89805 16
162.0462 137132.3 24
163.0544 322371.3 57
164.0496 155911.2969 27
167.0294 177638.1 31
167.0493 83845.6 14
168.0372 1262036.5 225
169.0326 92653.2 16
169.045 105975.8 18
169.065 64049.4 11
170.0403 124535.6 22
170.0526 250601.5 44
170.0599 25257.8 4
171.048 29427.9 5
173.0199 220793 39
173.0389 91181.5 16
173.0515 76779.9 13
174.0277 34997.3 6
174.0344 74735.8 13
174.0466 331508 59
175.0355 467695.4 83
175.0422 198405.7 35
176.0309 244779.1 43
176.0501 40569.5 7
177.0453 22743.9 4
177.0577 45112.7 8
179.0294 1849508.6 330
180.0251 176363.9688 31
180.0372 746499.7 133
181.045 2950414.2 526
182.0402 796797.6 142
182.0529 77265.8 13
183.0608 83481.5 14
184.0319 29453.6 5
184.0559 82622.6 14
186.0267 216630.8 38
186.0352 219963.5 39
187.0554 261235 46
188.0432 70986.4 12
188.05 716822.4 127
189.0575 100485.2 17
190.0655 39512.5 7
192.037 359545.2 64
192.0446 50434 8
193.0327 209809.9 37
193.0453 32798.8 5
193.0649 72923.6 13
194.0402 107341.9 19
194.0528 349675.9 62
194.0608 58356.1 10
195.0481 374482.2 66
196.0559 93346.9 16
197.02 145346.4 25
197.051 106430.8 18
198.0278 265263.3 47
199.0354 2466798 440
200.0308 426509.2 76
200.0431 94407.1 16
200.0509 34415.4 6
201.0499 196588.5469 35
201.0579 138458.0625 24
202.0464 86443.4 15
202.0653 45691.8 8
204.0246 109253.1953 19
204.038 87019.6 15
204.0557 24784.1 4
205.0324 153617.5 27
205.0451 236103.4 42
206.0404 2098191 374
207.0481 334635.1 59
207.061 114297.6 20
208.0559 606033.8 108
209.0639 40411.7 7
210.0281 26061.5 4
211.0443 21839.9 3
212.0276 157428.3 28
212.0417 139225.3 24
212.0506 100615.2 17
213.0386 92881.9 16
214.0455 27830.2 4
215.0423 35281.2 6
218.0399 33757.7 6
218.0599 43098.2 7
219.048 298510.1 53
220.0561 225800 40
221.0512 82718.9 14
221.0636 99757.8 17
222.0465 109186.1 19
222.0712 44318.3 7
224.0309 423368.2 75
225.0393 159056.9 28
225.0494 28325.8 5
226.0465 789305.2 140
227.0534 25042.5 4
228.0559 85755.5 15
230.0405 82545.7 14
232.0558 116105.2 20
233.0514 42924 7
233.0632 33437.2 5
234.0589 25393.1 4
237.0387 26750.9 4
238.046 75174.6 13
238.0667 27418.8 4
239.0543 37301.2 6
257.0293 32956 5
//
