ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP004550
RECORD_TITLE: TRIMETHYLSILYLSERINE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HAYASHI A, DEPT. OF CHEMISTRY, FAC. OF SCI. AND TECHNOLOGY, KINKI UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: TRIMETHYLSILYLSERINE
CH$NAME: DI-O-TRIMETHYLSILYL-MONP-N-TRIMETHYLSILYLSERINE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₂H₃₁NO₃Si₃
CH$EXACT_MASS: 321.16117
CH$SMILES: C[Si](C)(C)OCC([H])(N[Si](C)(C)C)C(=O)O[Si](C)(C)C
CH$IUPAC: InChI=1S/C12H31NO3Si3/c1-17(2,3)13-11(10-15-18(4,5)6)12(14)16-19(7,8)9/h11,13H,10H2,1-9H3
CH$LINK: INCHIKEY MBEDINMZZORSJN-UHFFFAOYSA-N

AC$INSTRUMENT: SHIMADZU LKB-9000B
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0uxr-1490000000-9666ebcfcd4b5b750021
PK$NUM_PEAK: 65
PK$PEAK: m/z int. rel.int.
  55 0.6 6
  57 1.9 19
  58 1.5 15
  59 0.5 5
  60 1.1 11
  61 1.9 19
  66 0.3 3
  70 0.1 1
  72 2.4 24
  75 29.8 298
  76 2.2 22
  77 1.5 15
  80 0.1 1
  84 1 10
  86 0.9 9
  87 0.9 9
  88 0.09 1
  89 0.8 8
  93 0.4 4
  100 15.2 152
  101 0.22 2
  102 1.5 15
  103 4.4 44
  114 2.6 26
  115 0.15 2
  116 15.7 157
  117 4.9 49
  118 1.2 12
  119 0.09 1
  129 0.7 7
  130 1.9 19
  131 2.7 27
  132 1.33 13
  133 5.8 58
  134 1.1 11
  144 2.5 25
  146 0.19 2
  147 22.5 225
  148 3.7 37
  149 2.3 23
  159 0.14 1
  163 1.2 12
  174 0.9 9
  188 6.6 66
  189 0.28 3
  190 1 10
  191 1.1 11
  203 3.5 35
  204 99.99 999
  205 21.8 218
  206 7.8 78
  207 1 10
  216 0.23 2
  217 1.1 11
  218 59.2 592
  219 12.8 128
  220 0.5 5
  221 1.8 18
  234 1.1 11
  278 5.9 59
  279 0.14 1
  280 0.7 7
  306 6 60
  307 1.9 19
  308 1.5 15
//