ACCESSION: MSBNK-LCSB-LU026806
RECORD_TITLE: Surinabant; LC-ESI-QFT; MS2; CE: 90; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 268
COMMENT: DATASET 20200303_ENTACT_RP_MIX505
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 10550
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 10548
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Surinabant
CH$NAME: 5-(4-bromophenyl)-1-(2,4-dichlorophenyl)-4-ethyl-N-piperidin-1-ylpyrazole-3-carboxamide
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C23H23BrCl2N4O
CH$EXACT_MASS: 520.0432
CH$SMILES: CCC1=C(N(N=C1C(=O)NN1CCCCC1)C1=CC=C(Cl)C=C1Cl)C1=CC=C(Br)C=C1
CH$IUPAC: InChI=1S/C23H23BrCl2N4O/c1-2-18-21(23(31)28-29-12-4-3-5-13-29)27-30(20-11-10-17(25)14-19(20)26)22(18)15-6-8-16(24)9-7-15/h6-11,14H,2-5,12-13H2,1H3,(H,28,31)
CH$LINK: CHEBI
125484
CH$LINK: PUBCHEM
CID:9849616
CH$LINK: INCHIKEY
HMXDWDSNPRNUKI-UHFFFAOYSA-N
CH$LINK: CHEMSPIDER
8025329
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 90
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 20.203 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 521.0505
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 16053062.5
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-05x0-2950000000-1f191cc10f0b994d9705
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
51.023 C4H3+ 1 51.0229 0.78
52.0307 C4H4+ 1 52.0308 -0.04
53.0022 C3HO+ 2 53.0022 0.12
53.0386 C4H5+ 1 53.0386 0.75
54.0339 C3H4N+ 1 54.0338 0.72
55.0179 C3H3O+ 2 55.0178 0.61
55.0543 C4H7+ 1 55.0542 0.46
56.0495 C3H6N+ 1 56.0495 0.17
57.0448 C2H5N2+ 1 57.0447 1.57
57.0699 C4H9+ 1 57.0699 1.28
62.9632 CClO+ 1 62.9632 -0.59
65.0385 C5H5+ 1 65.0386 -0.89
66.0338 C4H4N+ 1 66.0338 0.37
66.0464 C5H6+ 1 66.0464 0.44
67.0416 C4H5N+ 1 67.0417 -1.17
67.0542 C5H7+ 1 67.0542 -1.1
68.0494 C4H6N+ 1 68.0495 -1.66
69.0572 C4H7N+ 1 69.0573 -1.9
70.0651 C4H8N+ 1 70.0651 -0.39
74.0151 C6H2+ 1 74.0151 -0.66
75.0229 C6H3+ 1 75.0229 -0.35
76.0307 C6H4+ 1 76.0308 -0.36
78.0464 C6H6+ 1 78.0464 0.27
79.0178 C5H3O+ 2 79.0178 -0.07
80.0257 C5H4O+ 2 80.0257 0.29
81.0335 C5H5O+ 2 81.0335 0.04
82.0651 C5H8N+ 1 82.0651 -0.23
84.0808 C5H10N+ 1 84.0808 0.24
84.984 C4H2Cl+ 1 84.984 0.11
86.9632 C3ClO+ 2 86.9632 0.26
89.0386 C7H5+ 1 89.0386 -0.13
90.0338 C6H4N+ 1 90.0338 -0.25
90.0464 C7H6+ 1 90.0464 0.31
91.0543 C7H7+ 1 91.0542 0.75
94.0413 C6H6O+ 3 94.0413 0.23
95.0491 C6H7O+ 3 95.0491 -0.14
98.0363 C2H9ClNO+ 3 98.0367 -4.61
98.9996 C5H4Cl+ 1 98.9996 0.03
99.0917 C5H11N2+ 1 99.0917 0.35
100.0995 C5H12N2+ 1 100.0995 0.38
102.0464 C8H6+ 1 102.0464 0.14
103.0542 C8H7+ 1 103.0542 -0.19
104.0495 C7H6N+ 1 104.0495 0.39
104.0621 C8H8+ 1 104.0621 0.29
108.0567 C7H8O+ 3 108.057 -2.59
108.984 C6H2Cl+ 1 108.984 0.3
112.979 C5H2ClO+ 3 112.9789 1.45
114.0463 C9H6+ 2 114.0464 -1
115.0542 C9H7+ 2 115.0542 0.11
116.0621 C9H8+ 2 116.0621 0.01
117.0572 C8H7N+ 1 117.0573 -0.65
117.07 C9H9+ 1 117.0699 0.96
118.0653 C8H8N+ 1 118.0651 1.39
120.9606 C4H3Cl2+ 1 120.9606 0.02
122.9996 C7H4Cl+ 1 122.9996 0.22
123.9949 C6H3ClN+ 2 123.9949 0.27
125.0026 C6H4ClN+ 2 125.0027 -0.31
126.0104 C6H5ClN+ 3 126.0105 -0.59
126.0464 C10H6+ 2 126.0464 0.19
126.9945 C6H4ClO+ 3 126.9945 -0.27
127.0417 C9H5N+ 2 127.0417 0.29
127.0542 C10H7+ 2 127.0542 -0.33
128.0023 C6H5ClO+ 4 128.0023 -0.06
128.0495 C9H6N+ 2 128.0495 0.43
128.062 C10H8+ 2 128.0621 -0.3
129.0102 C6H6ClO+ 4 129.0102 0.55
129.0572 C9H7N+ 2 129.0573 -0.96
129.0698 C10H9+ 2 129.0699 -0.28
130.0652 C9H8N+ 2 130.0651 0.94
130.9491 C4H4Br+ 1 130.9491 0.43
132.0569 C9H8O+ 3 132.057 -0.83
132.9607 C5H3Cl2+ 1 132.9606 0.14
135.0316 C4H8ClN2O+ 3 135.032 -2.8
136.0073 C8H5Cl+ 2 136.0074 -0.86
138.0104 C7H5ClN+ 3 138.0105 -1
139.0058 C6H4ClN2+ 3 139.0058 0.25
139.0541 C11H7+ 2 139.0542 -1.26
140.0495 C10H6N+ 2 140.0495 0.09
141.0573 C10H7N+ 2 141.0573 0.22
141.0698 C11H9+ 2 141.0699 -0.45
142.0055 C6H5ClNO+ 4 142.0054 0.66
142.0652 C10H8N+ 2 142.0651 0.45
143.073 C10H9N+ 2 143.073 0.14
144.0568 C10H8O+ 3 144.057 -0.86
144.9606 C6H3Cl2+ 1 144.9606 0.03
145.0051 C3H9Cl2NO+ 3 145.0056 -3.46
145.0648 C10H9O+ 3 145.0648 0.01
145.9683 C6H4Cl2+ 1 145.9685 -1.11
146.0602 C9H8NO+ 3 146.06 0.77
149.0153 C9H6Cl+ 3 149.0153 0.15
150.0105 C8H5ClN+ 3 150.0105 0.09
151.0185 C8H6ClN+ 3 151.0183 1.01
152.0137 C7H5ClN2+ 4 152.0136 0.74
152.0261 C8H7ClN+ 3 152.0262 -0.68
152.0494 C11H6N+ 2 152.0495 -0.82
153.0573 C11H7N+ 2 153.0573 -0.1
154.0651 C11H8N+ 2 154.0651 -0.08
154.9491 C6H4Br+ 1 154.9491 -0.12
155.0007 C6H4ClN2O+ 3 155.0007 0.25
155.0604 C10H7N2+ 3 155.0604 -0.04
157.0522 C10H7NO+ 3 157.0522 -0.26
158.9436 C5H4BrO+ 3 158.944 -2.29
158.9763 C7H5Cl2+ 2 158.9763 0.16
159.0208 C4H11Cl2NO+ 4 159.0212 -2.92
159.9715 C6H4Cl2N+ 2 159.9715 0.01
160.9793 C6H5Cl2N+ 3 160.9794 -0.16
161.9632 C6H4Cl2O+ 2 161.9634 -1.05
162.0104 C9H5ClN+ 4 162.0105 -0.47
162.9712 C6H5Cl2O+ 3 162.9712 -0.28
164.0008 C7H3ClN3+ 4 164.001 -1.23
164.0262 C9H7ClN+ 4 164.0262 0.32
166.0527 C11H6N2+ 4 166.0525 0.79
167.0603 C11H7N2+ 4 167.0604 -0.57
168.0566 C9H11ClN+ 4 168.0575 -5.16
168.0683 C11H8N2+ 4 168.0682 0.63
168.9648 C7H6Br+ 1 168.9647 0.13
169.0647 C12H9O+ 4 169.0648 -0.78
169.0761 C11H9N2+ 4 169.076 0.37
170.06 C11H8NO+ 4 170.06 -0.11
171.0555 C10H7N2O+ 4 171.0553 1.08
171.9715 C7H4Cl2N+ 2 171.9715 -0.06
172.9597 C6H6BrO+ 3 172.9597 0.06
172.9668 C6H3Cl2N2+ 2 172.9668 0.06
173.9642 C7H4Cl2O+ 3 173.9634 4.92
174.0105 C10H5ClN+ 5 174.0105 0.11
175.0184 C10H6ClN+ 5 175.0183 0.3
176.0261 C10H7ClN+ 5 176.0262 -0.46
177.0339 C10H8ClN+ 5 177.034 -0.27
177.0573 C13H7N+ 3 177.0573 -0.22
177.9823 C6H6Cl2NO+ 4 177.9821 1.12
180.9646 C8H6Br+ 1 180.9647 -0.79
181.9599 C7H5BrN+ 1 181.96 -0.41
182.9553 C6H4BrN2+ 2 182.9552 0.21
183.9527 C4H8BrClN+ 3 183.9523 1.91
183.9717 C8H4Cl2N+ 2 183.9715 1.14
184.9667 C7H3Cl2N2+ 2 184.9668 -0.32
184.9793 C8H5Cl2N+ 3 184.9794 -0.25
185.0472 C8H10ClN2O+ 4 185.0476 -2.44
185.0708 C11H9N2O+ 4 185.0709 -0.5
186.9827 C7H5Cl2N2+ 3 186.9824 1.28
189.0215 C10H6ClN2+ 5 189.0214 0.62
189.07 C15H9+ 5 189.0699 0.64
190.0657 C14H8N+ 4 190.0651 3
190.0776 C15H10+ 4 190.0777 -0.79
191.0729 C14H9N+ 3 191.073 -0.35
192.9651 C9H6Br+ 3 192.9647 1.95
193.9599 C8H5BrN+ 1 193.96 -0.53
195.9716 C9H4Cl2N+ 3 195.9715 0.55
197.9873 C9H6Cl2N+ 4 197.9872 0.36
199.031 C13H8Cl+ 6 199.0309 0.72
201.0573 C15H7N+ 4 201.0573 0.21
202.0293 C11H7ClN2+ 5 202.0292 0.21
203.0371 C11H8ClN2+ 5 203.0371 0.23
203.0729 C15H9N+ 4 203.073 -0.27
204.0208 C11H7ClNO+ 4 204.0211 -1.51
204.0808 C15H10N+ 4 204.0808 0.29
205.9606 C9H5BrN+ 2 205.96 2.97
207.9761 C9H7BrN+ 2 207.9756 2.19
211.0186 C13H6ClN+ 6 211.0183 1.05
212.0262 C13H7ClN+ 6 212.0262 -0.01
214.0651 C16H8N+ 4 214.0651 0.08
215.073 C16H9N+ 4 215.073 0.39
216.0685 C15H8N2+ 5 216.0682 1.42
216.0805 C16H10N+ 4 216.0808 -1.07
217.0886 C16H11N+ 3 217.0886 -0.13
219.0323 C8H11Cl2N3+ 4 219.0325 -0.75
224.0261 C14H7ClN+ 6 224.0262 -0.41
225.0341 C14H8ClN+ 6 225.034 0.5
225.0464 C15H10Cl+ 6 225.0466 -0.67
226.0299 C13H7ClN2+ 6 226.0292 2.96
226.0417 C14H9ClN+ 6 226.0418 -0.29
227.0604 C16H7N2+ 5 227.0604 0.05
227.073 C17H9N+ 4 227.073 0.24
228.0683 C16H8N2+ 5 228.0682 0.28
228.0803 C17H10N+ 5 228.0808 -1.94
229.076 C16H9N2+ 5 229.076 0.03
230.0364 C13H9ClNO+ 5 230.0367 -1.42
231.975 C11H7BrN+ 4 231.9756 -2.83
232.9706 C10H6BrN2+ 3 232.9709 -1.34
236.998 C11H7Cl2N2+ 4 236.9981 -0.19
237.0338 C15H8ClN+ 7 237.034 -0.81
238.0418 C15H9ClN+ 7 238.0418 -0.2
239.0377 C14H8ClN2+ 7 239.0371 2.83
241.0759 C17H9N2+ 5 241.076 -0.34
242.0838 C17H10N2+ 5 242.0838 -0.25
243.0917 C17H11N2+ 4 243.0917 -0.04
244.0994 C17H12N2+ 4 244.0995 -0.39
246.9951 C13H7Cl2N+ 5 246.995 0.58
248.003 C13H8Cl2N+ 6 248.0028 0.54
250.0288 C18H4NO+ 6 250.0287 0.25
250.0416 C16H9ClN+ 7 250.0418 -0.67
251.0369 C15H8ClN2+ 6 251.0371 -0.7
251.0497 C16H10ClN+ 7 251.0496 0.26
252.0576 C16H11ClN+ 6 252.0575 0.4
261.0337 C20H5O+ 7 261.0335 0.79
262.0431 C8H15BrN4O+ 6 262.0424 2.65
263.037 C16H8ClN2+ 6 263.0371 -0.09
264.0447 C16H9ClN2+ 6 264.0449 -0.59
264.0568 C20H8O+ 6 264.057 -0.6
272.0028 C15H8Cl2N+ 6 272.0028 -0.2
276.0449 C17H9ClN2+ 6 276.0449 -0.03
277.0527 C17H10ClN2+ 6 277.0527 -0.06
278.0605 C17H11ClN2+ 5 278.0605 -0.1
278.9849 C11H5Cl2N4O+ 3 278.9835 4.97
279.0683 C17H12ClN2+ 5 279.0684 -0.36
285.0107 C16H9Cl2N+ 7 285.0107 0.08
286.0196 C7H16BrClN4O+ 7 286.0191 1.88
289.0527 C18H10ClN2+ 6 289.0527 -0.09
290.9441 C16H4BrO+ 5 290.944 0.33
291.0317 C17H8ClN2O+ 6 291.032 -0.76
291.9526 C13H8BrClN+ 4 291.9523 1.03
292.0391 C17H9ClN2O+ 6 292.0398 -2.26
294.9992 C16H10BrN+ 4 294.9991 0.16
296.0344 C13H12Cl2N3O+ 4 296.0352 -2.54
296.9972 C19H4ClNO+ 4 296.9976 -1.18
299.0138 C16H9Cl2N2+ 6 299.0137 0.19
306.9861 C16H8BrN2+ 5 306.9865 -1.55
312.0215 C17H10Cl2N2+ 6 312.0216 -0.08
313.0294 C17H11Cl2N2+ 6 313.0294 0.08
315.9522 C15H8BrClN+ 5 315.9523 -0.36
321.0024 C17H10BrN2+ 4 321.0022 0.7
323.0153 C8H20BrCl2N3O+ 7 323.0161 -2.69
325.9133 C13H7BrCl2N+ 3 325.9133 -0.11
329.9553 C15H8BrClN2+ 5 329.9554 -0.25
342.9639 C16H9BrClN2+ 4 342.9632 2.1
356.9793 C17H11BrClN2+ 5 356.9789 1.23
PK$NUM_PEAK: 226
PK$PEAK: m/z int. rel.int.
51.023 4805.7 5
52.0307 8749.1 9
53.0022 13815.2 15
53.0386 28025.2 30
54.0339 10823.4 11
55.0179 20636.6 22
55.0543 166511.5 183
56.0495 164348.2 181
57.0448 10790 11
57.0699 3276 3
62.9632 13605.1 15
65.0385 27657.7 30
66.0338 4682.9 5
66.0464 10695.3 11
67.0416 5383.1 5
67.0542 14285.3 15
68.0494 7491.1 8
69.0572 3571.6 3
70.0651 11174.4 12
74.0151 130218.7 143
75.0229 149844 165
76.0307 179428.8 197
78.0464 17098.2 18
79.0178 13275.9 14
80.0257 12052.9 13
81.0335 29768.1 32
82.0651 34946 38
84.0808 407727.2 449
84.984 109191.8 120
86.9632 349940.1 385
89.0386 32567.5 35
90.0338 8519.6 9
90.0464 34426.1 37
91.0543 11978.3 13
94.0413 125656.4 138
95.0491 35914.8 39
98.0363 12682.4 13
98.9996 64416.6 71
99.0917 42844.6 47
100.0995 3943.5 4
102.0464 54607.4 60
103.0542 58320.4 64
104.0495 10462.6 11
104.0621 40959.8 45
108.0567 4154.5 4
108.984 906051.4 999
112.979 18360 20
114.0463 6672.1 7
115.0542 620934.4 684
116.0621 316071.9 348
117.0572 34921.2 38
117.07 6920.1 7
118.0653 15448.4 17
120.9606 47408.8 52
122.9996 17270 19
123.9949 28305.3 31
125.0026 25657.7 28
126.0104 23125.9 25
126.0464 101336.9 111
126.9945 70741.7 77
127.0417 75403.7 83
127.0542 57769.1 63
128.0023 108697 119
128.0495 26211.4 28
128.062 90913.8 100
129.0102 16748.4 18
129.0572 8668 9
129.0698 4718.1 5
130.0652 17568.3 19
130.9491 45555 50
132.0569 12734.3 14
132.9607 370459.9 408
135.0316 9632.9 10
136.0073 4133.4 4
138.0104 4075 4
139.0058 30876.3 34
139.0541 10822 11
140.0495 178001.2 196
141.0573 54177.7 59
141.0698 38832.1 42
142.0055 5749.6 6
142.0652 106597.6 117
143.073 182716.9 201
144.0568 4835.2 5
144.9606 278683 307
145.0051 27334.2 30
145.0648 107962.2 119
145.9683 14609.7 16
146.0602 14586.8 16
149.0153 93297.7 102
150.0105 10689.7 11
151.0185 28501.7 31
152.0137 9281.9 10
152.0261 19621.4 21
152.0494 6130.2 6
153.0573 244907.5 270
154.0651 132385 145
154.9491 93659.1 103
155.0007 9059.7 9
155.0604 157566.8 173
157.0522 9196.2 10
158.9436 4275.3 4
158.9763 16795.1 18
159.0208 7660.6 8
159.9715 176122 194
160.9793 81033.5 89
161.9632 11678.8 12
162.0104 13151.7 14
162.9712 161267.1 177
164.0008 22563.8 24
164.0262 8063.5 8
166.0527 21282.9 23
167.0603 17138 18
168.0566 10120.6 11
168.0683 48242.9 53
168.9648 40096 44
169.0647 4057.7 4
169.0761 22194 24
170.06 18200.2 20
171.0555 6212.6 6
171.9715 71893.5 79
172.9597 203236.5 224
172.9668 890720.4 982
173.9642 4242.2 4
174.0105 58621.4 64
175.0184 15457.4 17
176.0261 6265 6
177.0339 35433.5 39
177.0573 89122.7 98
177.9823 4670.5 5
180.9646 8981.3 9
181.9599 75408.4 83
182.9553 535141.8 590
183.9527 5609.7 6
183.9717 5275.4 5
184.9667 7156.2 7
184.9793 19862.8 21
185.0472 3488.4 3
185.0708 13912.1 15
186.9827 6041.7 6
189.0215 4901.9 5
189.07 49979.4 55
190.0657 14609.6 16
190.0776 16034.4 17
191.0729 18389.7 20
192.9651 7760.5 8
193.9599 22980.1 25
195.9716 31382.8 34
197.9873 13801.9 15
199.031 30188.7 33
201.0573 26915.9 29
202.0293 23174.1 25
203.0371 9916.8 10
203.0729 25877.9 28
204.0208 6600.1 7
204.0808 18544.8 20
205.9606 4406.8 4
207.9761 6564.3 7
211.0186 29212.5 32
212.0262 29047.6 32
214.0651 37966.7 41
215.073 38560.4 42
216.0685 56251.9 62
216.0805 297349.8 327
217.0886 607525.1 669
219.0323 6055.8 6
224.0261 56047.1 61
225.0341 7581.4 8
225.0464 38681.1 42
226.0299 4918.6 5
226.0417 8779.1 9
227.0604 21792.3 24
227.073 49191.3 54
228.0683 126789.7 139
228.0803 7741.1 8
229.076 585641.1 645
230.0364 20161.3 22
231.975 5843.5 6
232.9706 4042.6 4
236.998 6995.9 7
237.0338 73294.9 80
238.0418 43272.3 47
239.0377 4244.6 4
241.0759 49717.6 54
242.0838 347515.3 383
243.0917 310358.2 342
244.0994 76280.8 84
246.9951 43066.5 47
248.003 31970.2 35
250.0288 8196.4 9
250.0416 70202.1 77
251.0369 19473.4 21
251.0497 188228 207
252.0576 49229.4 54
261.0337 19504.4 21
262.0431 19586.1 21
263.037 338978.5 373
264.0447 216186.8 238
264.0568 12576.2 13
272.0028 44169.4 48
276.0449 47387.9 52
277.0527 351903.8 388
278.0605 219567.4 242
278.9849 63558.8 70
279.0683 27655.4 30
285.0107 21182.9 23
286.0196 18148.6 20
289.0527 13213.3 14
290.9441 9395.8 10
291.0317 44306.2 48
291.9526 11091 12
292.0391 16068.5 17
294.9992 8908.3 9
296.0344 7593.2 8
296.9972 14830.7 16
299.0138 88053.7 97
306.9861 10305.7 11
312.0215 15946.5 17
313.0294 70625.1 77
315.9522 3621.5 3
321.0024 15060.4 16
323.0153 6022.2 6
325.9133 224115.2 247
329.9553 6409.7 7
342.9639 17322.2 19
356.9793 9085.9 10
//
