ACCESSION: MSBNK-LCSB-LU031803
RECORD_TITLE: Cyproterone acetate; LC-ESI-QFT; MS2; CE: 45; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 318
COMMENT: DATASET 20200303_ENTACT_RP_MIX505
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 9594
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 9592
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Cyproterone acetate
CH$NAME: [(1S,2S,3S,5R,11R,12S,15R,16S)-15-acetyl-9-chloro-2,16-dimethyl-6-oxo-15-pentacyclo[9.7.0.02,8.03,5.012,16]octadeca-7,9-dienyl] acetate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C24H29ClO4
CH$EXACT_MASS: 416.1754
CH$SMILES: CC(=O)O[C@@]1(CC[C@H]2[C@@H]3C=C(Cl)C4=CC(=O)[C@@H]5C[C@@H]5[C@]4(C)[C@H]3CC[C@]12C)C(C)=O
CH$IUPAC: InChI=1S/C24H29ClO4/c1-12(26)24(29-13(2)27)8-6-16-14-10-20(25)19-11-21(28)15-9-18(15)23(19,4)17(14)5-7-22(16,24)3/h10-11,14-18H,5-9H2,1-4H3/t14-,15+,16-,17-,18-,22-,23-,24-/m0/s1
CH$LINK: CAS
427-51-0
CH$LINK: CHEBI
50743
CH$LINK: KEGG
D01368
CH$LINK: PUBCHEM
CID:9880
CH$LINK: INCHIKEY
UWFYSQMTEOIJJG-FDTZYFLXSA-N
CH$LINK: CHEMSPIDER
9496
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 45
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 18.263 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 417.1827
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 2908947.875
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-005a-1960000000-53ab7217a1efa46119d7
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
55.0178 C3H3O+ 1 55.0178 -0.57
55.0542 C4H7+ 1 55.0542 -0.44
59.049 C3H7O+ 1 59.0491 -2.13
65.0385 C5H5+ 1 65.0386 -1.48
67.0542 C5H7+ 1 67.0542 -0.87
69.0334 C4H5O+ 1 69.0335 -1.6
69.0697 C5H9+ 1 69.0699 -2.38
71.049 C4H7O+ 1 71.0491 -1.3
79.0542 C6H7+ 1 79.0542 -0.95
81.0699 C6H9+ 1 81.0699 0.03
83.049 C5H7O+ 1 83.0491 -1.67
85.0284 C4H5O2+ 1 85.0284 -0.29
85.0648 C5H9O+ 1 85.0648 -0.39
91.0542 C7H7+ 1 91.0542 0.16
93.0699 C7H9+ 1 93.0699 0.2
95.0492 C6H7O+ 1 95.0491 0.18
95.0855 C7H11+ 1 95.0855 -0.47
97.0649 C6H9O+ 1 97.0648 0.94
99.0803 C6H11O+ 1 99.0804 -1.63
105.0699 C8H9+ 1 105.0699 0.11
107.0491 C7H7O+ 1 107.0491 -0.02
107.0856 C8H11+ 1 107.0855 0.4
109.0648 C7H9O+ 1 109.0648 -0.36
109.1012 C8H13+ 1 109.1012 0.47
111.0805 C7H11O+ 1 111.0804 0.2
115.0541 C9H7+ 1 115.0542 -1.29
117.0699 C9H9+ 1 117.0699 -0.22
119.0856 C9H11+ 1 119.0855 0.24
121.0648 C8H9O+ 1 121.0648 0.06
121.1012 C9H13+ 1 121.1012 0.37
123.0806 C8H11O+ 1 123.0804 0.93
123.1169 C9H15+ 1 123.1168 0.37
127.0308 C7H8Cl+ 1 127.0309 -0.76
128.0622 C10H8+ 1 128.0621 1.01
129.0698 C10H9+ 1 129.0699 -0.28
130.0777 C10H10+ 1 130.0777 0.1
131.049 C9H7O+ 1 131.0491 -1.33
131.0856 C10H11+ 1 131.0855 0.36
132.0565 C9H8O+ 2 132.057 -3.26
133.0648 C9H9O+ 1 133.0648 0.23
133.1012 C10H13+ 1 133.1012 0.05
135.0803 C9H11O+ 1 135.0804 -0.86
135.1168 C10H15+ 1 135.1168 -0.36
139.0308 C8H8Cl+ 1 139.0309 -0.89
141.0464 C8H10Cl+ 1 141.0466 -0.84
141.07 C11H9+ 1 141.0699 0.84
142.0779 C11H10+ 1 142.0777 1.5
143.0856 C11H11+ 1 143.0855 0.55
144.0932 C11H12+ 2 144.0934 -0.71
145.0648 C10H9O+ 1 145.0648 0.11
145.1012 C11H13+ 1 145.1012 0.26
146.0724 C10H10O+ 2 146.0726 -1.33
147.0803 C10H11O+ 2 147.0804 -0.69
147.1168 C11H15+ 2 147.1168 -0.02
149.0961 C10H13O+ 2 149.0961 0.08
151.0309 C9H8Cl+ 1 151.0309 -0.22
151.1117 C10H15O+ 2 151.1117 -0.29
153.0694 C12H9+ 2 153.0699 -3.21
154.078 C12H10+ 1 154.0777 1.78
155.0256 C8H8ClO+ 1 155.0258 -1.26
155.0618 C9H12Cl+ 1 155.0622 -2.3
155.0855 C12H11+ 2 155.0855 0.02
156.0934 C12H12+ 2 156.0934 0.23
157.0413 C8H10ClO+ 1 157.0415 -1.11
157.0648 C11H9O+ 2 157.0648 -0.18
157.1012 C12H13+ 2 157.1012 0.25
158.0726 C11H10O+ 2 158.0726 0.03
159.0804 C11H11O+ 2 159.0804 -0.53
159.1168 C12H15+ 2 159.1168 -0.29
160.0883 C11H12O+ 2 160.0883 0.26
161.0961 C11H13O+ 2 161.0961 0.28
161.133 C12H17+ 1 161.1325 2.97
163.0309 C10H8Cl+ 1 163.0309 -0.28
163.0755 C10H11O2+ 2 163.0754 1.02
163.1115 C11H15O+ 2 163.1117 -1.19
165.0468 C10H10Cl+ 1 165.0466 1.43
165.07 C13H9+ 2 165.0699 0.74
167.0258 C9H8ClO+ 1 167.0258 -0.33
167.0618 C10H12Cl+ 1 167.0622 -2.48
167.0854 C13H11+ 2 167.0855 -0.7
168.0932 C13H12+ 2 168.0934 -0.76
169.0414 C9H10ClO+ 1 169.0415 -0.2
169.0645 C12H9O+ 2 169.0648 -1.86
169.1011 C13H13+ 2 169.1012 -0.47
170.0724 C12H10O+ 2 170.0726 -1.39
170.1092 C13H14+ 2 170.109 0.98
171.0805 C12H11O+ 2 171.0804 0.42
171.1168 C13H15+ 2 171.1168 -0.34
172.0881 C12H12O+ 2 172.0883 -0.98
173.0963 C12H13O+ 2 173.0961 1.07
173.1326 C13H17+ 2 173.1325 0.76
175.0306 C11H8Cl+ 1 175.0309 -1.81
175.0753 C11H11O2+ 2 175.0754 -0.34
175.1118 C12H15O+ 2 175.1117 0.22
177.0465 C11H10Cl+ 1 177.0466 -0.54
177.1271 C12H17O+ 2 177.1274 -1.38
179.0258 C10H8ClO+ 1 179.0258 -0.11
179.0624 C11H12Cl+ 1 179.0622 0.86
179.0856 C14H11+ 2 179.0855 0.31
180.0932 C14H12+ 2 180.0934 -0.77
181.0415 C10H10ClO+ 1 181.0415 0.34
181.0646 C13H9O+ 2 181.0648 -1.29
181.0779 C11H14Cl+ 1 181.0779 0.21
181.1013 C14H13+ 2 181.1012 0.43
182.0731 C13H10O+ 2 182.0726 2.84
182.1092 C14H14+ 2 182.109 1.28
183.0574 C10H12ClO+ 1 183.0571 1.71
183.0807 C13H11O+ 2 183.0804 1.34
183.1169 C14H15+ 2 183.1168 0.46
184.0882 C13H12O+ 2 184.0883 -0.14
184.1248 C14H16+ 2 184.1247 0.73
185.0962 C13H13O+ 2 185.0961 0.71
185.133 C14H17+ 2 185.1325 2.56
186.1037 C13H14O+ 2 186.1039 -1.41
187.0753 C12H11O2+ 2 187.0754 -0.44
187.1116 C13H15O+ 2 187.1117 -0.73
189.0466 C12H10Cl+ 1 189.0466 0.03
189.0909 C12H13O2+ 2 189.091 -0.63
189.1275 C13H17O+ 2 189.1274 0.78
191.0256 C11H8ClO+ 1 191.0258 -1.24
191.062 C12H12Cl+ 1 191.0622 -1.2
191.0852 C15H11+ 2 191.0855 -1.96
192.0931 C15H12+ 2 192.0934 -1.29
193.0417 C11H10ClO+ 1 193.0415 1.27
193.0779 C12H14Cl+ 1 193.0779 0.04
193.1013 C15H13+ 2 193.1012 0.4
194.1091 C15H14+ 2 194.109 0.35
195.0575 C11H12ClO+ 1 195.0571 1.7
195.0799 C14H11O+ 2 195.0804 -3.03
195.1168 C15H15+ 2 195.1168 -0.33
196.1248 C15H16+ 2 196.1247 0.55
197.0963 C14H13O+ 2 197.0961 1
197.1325 C15H17+ 2 197.1325 0.11
199.112 C14H15O+ 2 199.1117 1.12
201.0466 C13H10Cl+ 1 201.0466 0.46
201.1274 C14H17O+ 2 201.1274 0.1
202.0779 C16H10+ 2 202.0777 1.05
203.0625 C13H12Cl+ 1 203.0622 1.48
203.0859 C16H11+ 2 203.0855 1.97
204.0934 C16H12+ 2 204.0934 0.42
205.0417 C12H10ClO+ 1 205.0415 1.26
205.0773 C13H14Cl+ 1 205.0779 -2.5
205.101 C16H13+ 2 205.1012 -0.67
206.1088 C16H14+ 2 206.109 -1.01
207.0572 C12H12ClO+ 1 207.0571 0.2
207.0808 C15H11O+ 2 207.0804 1.86
207.1167 C16H15+ 2 207.1168 -0.47
208.0886 C15H12O+ 2 208.0883 1.51
208.1245 C16H16+ 2 208.1247 -0.88
209.0961 C15H13O+ 2 209.0961 0.21
209.1324 C16H17+ 2 209.1325 -0.41
210.1041 C15H14O+ 2 210.1039 0.97
210.1404 C16H18+ 2 210.1403 0.34
211.1116 C15H15O+ 2 211.1117 -0.82
211.148 C16H19+ 2 211.1481 -0.72
213.1277 C15H17O+ 2 213.1274 1.24
215.0617 C14H12Cl+ 1 215.0622 -2.5
217.0779 C14H14Cl+ 1 217.0779 0.17
217.1009 C17H13+ 2 217.1012 -1.47
218.1088 C17H14+ 2 218.109 -0.74
219.0571 C13H12ClO+ 1 219.0571 0.12
219.0923 C14H16Cl+ 1 219.0935 -5.28
219.1169 C17H15+ 2 219.1168 0.4
220.1247 C17H16+ 2 220.1247 0.01
221.0724 C13H14ClO+ 1 221.0728 -1.69
221.0971 C16H13O+ 2 221.0961 4.35
221.1325 C17H17+ 2 221.1325 0.31
222.1039 C16H14O+ 2 222.1039 0.02
222.1395 C17H18+ 2 222.1403 -3.65
223.1116 C16H15O+ 2 223.1117 -0.5
223.1479 C17H19+ 2 223.1481 -1.08
224.1199 C16H16O+ 2 224.1196 1.57
225.1272 C16H17O+ 2 225.1274 -0.85
227.062 C15H12Cl+ 1 227.0622 -1.09
227.1066 C15H15O2+ 2 227.1067 -0.36
229.0774 C15H14Cl+ 1 229.0779 -2.03
229.1014 C18H13+ 2 229.1012 0.87
230.109 C18H14+ 2 230.109 0.16
231.0575 C14H12ClO+ 1 231.0571 1.57
231.094 C15H16Cl+ 1 231.0935 1.93
231.1164 C18H15+ 2 231.1168 -1.93
232.1243 C18H16+ 2 232.1247 -1.43
233.073 C14H14ClO+ 1 233.0728 0.95
233.1327 C18H17+ 2 233.1325 0.89
234.1035 C17H14O+ 2 234.1039 -1.99
234.1401 C18H18+ 2 234.1403 -1.05
235.0883 C14H16ClO+ 1 235.0884 -0.57
235.1118 C17H15O+ 2 235.1117 0.05
235.1482 C18H19+ 2 235.1481 0.21
236.1195 C17H16O+ 2 236.1196 -0.18
236.1559 C18H20+ 2 236.156 -0.28
237.1275 C17H17O+ 2 237.1274 0.29
237.1639 C18H21+ 2 237.1638 0.58
238.1354 C17H18O+ 2 238.1352 0.57
241.0781 C16H14Cl+ 1 241.0779 0.87
243.0569 C15H12ClO+ 1 243.0571 -0.94
243.0928 C16H16Cl+ 1 243.0935 -2.98
243.1166 C19H15+ 2 243.1168 -0.94
244.1012 C16H17Cl+ 1 244.1013 -0.51
244.1244 C19H16+ 2 244.1247 -1.23
245.0728 C15H14ClO+ 1 245.0728 0.17
245.1094 C16H18Cl+ 1 245.1092 1.07
245.1323 C19H17+ 2 245.1325 -0.64
246.1048 C18H14O+ 2 246.1039 3.45
246.1405 C19H18+ 2 246.1403 0.87
247.1118 C18H15O+ 2 247.1117 0.12
247.1483 C19H19+ 2 247.1481 0.77
248.1196 C18H16O+ 2 248.1196 0.08
248.1559 C19H20+ 2 248.156 -0.38
249.1278 C18H17O+ 2 249.1274 1.64
249.1637 C19H21+ 2 249.1638 -0.24
250.1356 C18H18O+ 2 250.1352 1.53
250.1719 C19H22+ 2 250.1716 1.07
251.1431 C18H19O+ 2 251.143 0.33
251.1799 C19H23+ 2 251.1794 1.81
252.1509 C18H20O+ 2 252.1509 0.17
253.1579 C18H21O+ 2 253.1587 -3.13
255.0935 C17H16Cl+ 1 255.0935 0.09
257.0727 C16H14ClO+ 1 257.0728 -0.31
257.1085 C17H18Cl+ 1 257.1092 -2.48
259.088 C16H16ClO+ 1 259.0884 -1.44
259.1481 C20H19+ 2 259.1481 0.03
260.1561 C20H20+ 2 260.156 0.46
261.1271 C19H17O+ 2 261.1274 -1.3
261.1637 C20H21+ 2 261.1638 -0.4
262.1352 C19H18O+ 2 262.1352 -0.17
262.1708 C20H22+ 2 262.1716 -2.88
263.1431 C19H19O+ 2 263.143 0.14
264.1511 C19H20O+ 2 264.1509 0.79
265.1587 C19H21O+ 2 265.1587 -0.06
267.0941 C18H16Cl+ 1 267.0935 2.37
269.0715 C17H14ClO+ 1 269.0728 -4.84
269.1089 C18H18Cl+ 1 269.1092 -0.9
270.1403 C21H18+ 2 270.1403 -0.06
271.0889 C17H16ClO+ 1 271.0884 1.65
271.1249 C18H20Cl+ 1 271.1248 0.27
273.1026 C17H18ClO+ 1 273.1041 -5.37
273.1275 C20H17O+ 2 273.1274 0.53
275.1429 C20H19O+ 2 275.143 -0.66
275.1794 C21H23+ 2 275.1794 -0.02
277.1588 C20H21O+ 2 277.1587 0.26
278.1664 C20H22O+ 2 278.1665 -0.44
279.1744 C20H23O+ 2 279.1743 0.18
281.1089 C19H18Cl+ 1 281.1092 -0.78
285.1043 C18H18ClO+ 1 285.1041 0.72
285.1631 C22H21+ 2 285.1638 -2.54
288.1511 C21H20O+ 2 288.1509 0.9
295.1253 C20H20Cl+ 1 295.1248 1.75
297.1402 C20H22Cl+ 1 297.1405 -0.8
299.12 C19H20ClO+ 1 299.1197 0.79
303.1743 C22H23O+ 2 303.1743 -0.09
306.1615 C21H22O2+ 2 306.1614 0.14
313.1355 C20H22ClO+ 1 313.1354 0.56
314.1432 C20H23ClO+ 1 314.1432 0.04
315.1505 C20H24ClO+ 1 315.151 -1.54
321.1851 C22H25O2+ 2 321.1849 0.47
357.161 C22H26ClO2+ 1 357.1616 -1.71
PK$NUM_PEAK: 257
PK$PEAK: m/z int. rel.int.
55.0178 5522.4 25
55.0542 11774 55
59.049 7862.8 36
65.0385 2945.2 13
67.0542 18596.4 87
69.0334 7746.2 36
69.0697 8611.6 40
71.049 6548.1 30
79.0542 19872 93
81.0699 36578.6 171
83.049 7148.5 33
85.0284 12212.7 57
85.0648 11573.9 54
91.0542 42239.6 198
93.0699 50376.3 236
95.0492 16005.6 75
95.0855 26877.5 126
97.0649 14779.3 69
99.0803 4884.1 22
105.0699 87555.9 411
107.0491 11877.6 55
107.0856 40190.1 188
109.0648 16859.2 79
109.1012 21802.6 102
111.0805 6216.9 29
115.0541 4221.7 19
117.0699 23344.8 109
119.0856 71413.9 335
121.0648 34682.2 162
121.1012 43217.7 203
123.0806 12628.6 59
123.1169 5499.9 25
127.0308 7783.4 36
128.0622 6121.2 28
129.0698 27957.2 131
130.0777 5399.1 25
131.049 6121.3 28
131.0856 66889.9 314
132.0565 2412.4 11
133.0648 12497.8 58
133.1012 203745.4 957
135.0803 12063.7 56
135.1168 13892.6 65
139.0308 6496.4 30
141.0464 6204.6 29
141.07 11979.9 56
142.0779 14701.5 69
143.0856 55067 258
144.0932 6580.1 30
145.0648 36797.9 172
145.1012 104160 489
146.0724 7534.2 35
147.0803 34010.1 159
147.1168 190671.7 895
149.0961 5600.5 26
151.0309 2923.1 13
151.1117 5254.1 24
153.0694 2329.7 10
154.078 4469 20
155.0256 9149.2 42
155.0618 4239.8 19
155.0855 40442.4 190
156.0934 9021.1 42
157.0413 6320.6 29
157.0648 13948 65
157.1012 73503.9 345
158.0726 9304.7 43
159.0804 36505.3 171
159.1168 45461.3 213
160.0883 4077 19
161.0961 11878 55
161.133 3201.4 15
163.0309 5924.7 27
163.0755 3571.2 16
163.1115 5880.2 27
165.0468 7301.6 34
165.07 10011.4 47
167.0258 11109 52
167.0618 4004.7 18
167.0854 20617.6 96
168.0932 7824.1 36
169.0414 8926.4 41
169.0645 2614.7 12
169.1011 39221.2 184
170.0724 3577.8 16
170.1092 7482.2 35
171.0805 28075.4 131
171.1168 35782.6 168
172.0881 5682.2 26
173.0963 18189.8 85
173.1326 7511.5 35
175.0306 3277.1 15
175.0753 3740 17
175.1118 59888.3 281
177.0465 24070.5 113
177.1271 7830.5 36
179.0258 9182.7 43
179.0624 5135.5 24
179.0856 12665.6 59
180.0932 8118.3 38
181.0415 54481.4 255
181.0646 3152.8 14
181.0779 19394.2 91
181.1013 37136.6 174
182.0731 2554.9 12
182.1092 18739.3 88
183.0574 6234.4 29
183.0807 13789.9 64
183.1169 62892.2 295
184.0882 11480.3 53
184.1248 7314 34
185.0962 63027.2 296
185.133 14271.8 67
186.1037 3853.6 18
187.0753 9681.6 45
187.1116 10399.3 48
189.0466 10369.5 48
189.0909 4007.4 18
189.1275 5312.5 24
191.0256 9189.3 43
191.062 11960.6 56
191.0852 3868.8 18
192.0931 5906.1 27
193.0417 18618.5 87
193.0779 7545.4 35
193.1013 32888.7 154
194.1091 10637.9 49
195.0575 19334.8 90
195.0799 11022.3 51
195.1168 34410.4 161
196.1248 11306.8 53
197.0963 14370 67
197.1325 21763.3 102
199.112 19087.3 89
201.0466 7013.3 32
201.1274 10281.1 48
202.0779 2892.2 13
203.0625 11241 52
203.0859 3867.6 18
204.0934 7348.3 34
205.0417 39584.1 185
205.0773 5666.2 26
205.101 22900.3 107
206.1088 9414.9 44
207.0572 13294.9 62
207.0808 3056.1 14
207.1167 25925.1 121
208.0886 2827.7 13
208.1245 5379.2 25
209.0961 20933.2 98
209.1324 22450.3 105
210.1041 4244.9 19
210.1404 8014 37
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//
