ACCESSION: MSBNK-LCSB-LU124004
RECORD_TITLE: Fluoxastrobin; LC-ESI-QFT; MS2; CE: 60; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 1240
COMMENT: DATASET 20200303_ENTACT_RP_MIX504
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 9215
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 9213
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Fluoxastrobin
CH$NAME: (E)-1-[2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yl]oxyphenyl]-1-(5,6-dihydro-1,4,2-dioxazin-3-yl)-N-methoxymethanimine
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C21H16ClFN4O5
CH$EXACT_MASS: 458.0793
CH$SMILES: CO\N=C(\C1=NOCCO1)C1=C(OC2=C(F)C(OC3=C(Cl)C=CC=C3)=NC=N2)C=CC=C1
CH$IUPAC: InChI=1S/C21H16ClFN4O5/c1-28-26-18(21-27-30-11-10-29-21)13-6-2-4-8-15(13)31-19-17(23)20(25-12-24-19)32-16-9-5-3-7-14(16)22/h2-9,12H,10-11H2,1H3/b26-18+
CH$LINK: CAS
361377-29-9
CH$LINK: CHEBI
83253
CH$LINK: PUBCHEM
CID:11048796
CH$LINK: INCHIKEY
UFEODZBUAFNAEU-NLRVBDNBSA-N
CH$LINK: CHEMSPIDER
9223963
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 60
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 17.699 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0212
MS$FOCUSED_ION: PRECURSOR_M/Z 459.0866
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 15182167.25
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-000i-1900000000-d7b9580d03c13518d71a
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
50.015 C4H2+ 1 50.0151 -1.08
51.023 C4H3+ 1 51.0229 1.05
52.0182 C3H2N+ 1 52.0182 -0.37
52.0307 C4H4+ 1 52.0308 -0.35
53.0022 C3HO+ 2 53.0022 -0.01
53.0386 C4H5+ 1 53.0386 -0.32
53.9975 C2NO+ 1 53.9974 1.69
55.0178 C3H3O+ 2 55.0178 -0.3
56.0131 C2H2NO+ 1 56.0131 -0.27
63.0229 C5H3+ 2 63.0229 -1.16
64.0181 C4H2N+ 1 64.0182 -1.8
64.0307 C5H4+ 2 64.0308 -0.53
65.0385 C5H5+ 2 65.0386 -0.92
66.0463 C5H6+ 2 66.0464 -1.17
68.0496 C4H6N+ 1 68.0495 1.55
68.9971 C3HO2+ 2 68.9971 0.39
69.0083 C2HN2O+ 1 69.0083 -1.2
69.9923 C2NO2+ 1 69.9924 -1.15
70.0086 C3HFN+ 1 70.0088 -1.64
71.029 C4H4F+ 1 71.0292 -1.97
72.0243 C3H3FN+ 1 72.0244 -2.01
73.0196 C2H2FN2+ 1 73.0197 -1.26
73.0283 C3H5O2+ 2 73.0284 -1.29
74.0035 C2HFNO+ 2 74.0037 -1.7
74.0151 C6H2+ 2 74.0151 -0.32
75.0228 CH2FN3+ 2 75.0227 1.23
76.0307 C6H4+ 2 76.0308 -0.02
77.026 C5H3N+ 3 77.026 0.21
77.0384 CH4FN3+ 2 77.0384 -0.01
78.0337 C5H4N+ 2 78.0338 -1
79.0178 C5H3O+ 4 79.0178 -0.08
79.0416 C5H5N+ 2 79.0417 -1.12
79.0541 CH6FN3+ 2 79.054 0.89
80.0494 C5H6N+ 2 80.0495 -0.74
81.0334 C5H5O+ 4 81.0335 -0.7
82.0286 C4H4NO+ 2 82.0287 -1.17
83.0289 C5H4F+ 1 83.0292 -3.03
84.9838 C4H2Cl+ 1 84.984 -1.57
86.0036 C3HFNO+ 3 86.0037 -0.49
86.0235 C3H4NO2+ 4 86.0237 -1.71
86.9877 C3FO2+ 3 86.9877 -0.05
86.9996 C4H4Cl+ 3 86.9996 -0.43
89.0386 C7H5+ 3 89.0386 -0.21
90.0338 C6H4N+ 3 90.0338 -0.33
91.0542 C7H7+ 3 91.0542 -0.08
92.0256 C6H4O+ 5 92.0257 -0.71
92.0367 C5H4N2+ 2 92.0369 -2.48
92.0494 C6H6N+ 3 92.0495 -0.44
93.0334 C6H5O+ 5 93.0335 -0.6
94.0412 C6H6O+ 5 94.0413 -0.98
95.0491 C6H7O+ 5 95.0491 -0.61
96.0372 C6H5F+ 1 96.037 1.78
96.0444 C5H6NO+ 5 96.0444 0.09
97.0033 C3HN2O2+ 3 97.0033 0.47
97.0522 C5H7NO+ 5 97.0522 -0.19
98.0365 C5H6O2+ 5 98.0362 2.39
98.9995 ClFH3N3+ 4 98.9994 0.6
100.0188 C4H3FNO+ 4 100.0193 -5.13
102.0338 C7H4N+ 4 102.0338 -0.71
103.0416 C7H5N+ 4 103.0417 -0.37
103.0541 C3H6FN3+ 3 103.054 0.65
104.0141 C3H3FNO2+ 5 104.0142 -1.33
104.0494 C2H5FN4+ 4 104.0493 0.86
105.0335 C7H5O+ 5 105.0335 -0.31
105.0447 C6H5N2+ 3 105.0447 -0.48
106.0287 C6H4NO+ 6 106.0287 -0.53
106.0525 C6H6N2+ 3 106.0525 -0.15
106.0648 C2H7FN4+ 4 106.0649 -0.81
107.0291 C7H4F+ 1 107.0292 -0.89
108.0241 C6H3FN+ 1 108.0244 -2.58
109.0285 C6H5O2+ 7 109.0284 0.78
109.032 C6H4FN+ 1 109.0322 -1.81
110.0163 C6H3FO+ 4 110.0162 0.45
110.9994 CH3ClFN3+ 4 110.9994 0.41
111.044 C6H7O2+ 6 111.0441 -0.73
112.0075 C6H5Cl+ 4 112.0074 0.23
113.0397 C6H6FO+ 4 113.0397 -0.52
114.9944 C5H4ClO+ 5 114.9945 -0.85
115.0295 C7H3N2+ 4 115.0291 3.38
116.0368 C7H4N2+ 4 116.0369 -0.56
116.0496 C8H6N+ 5 116.0495 1.25
116.9894 C5H3ClF+ 1 116.9902 -6.66
117.0447 C7H5N2+ 4 117.0447 -0.26
118.0286 C7H4NO+ 7 118.0287 -0.83
118.0525 CH9FNO4+ 4 118.051 12.99
119.0366 C7H5NO+ 7 119.0366 0.18
119.0602 C7H7N2+ 4 119.0604 -1.28
120.0443 C7H6NO+ 7 120.0444 -0.43
121.0324 C7H4FN+ 1 121.0322 1.16
121.0395 C6H5N2O+ 5 121.0396 -0.75
122.04 C7H5FN+ 1 122.0401 -0.75
122.9994 C2H3ClFN3+ 4 122.9994 -0.25
123.0241 C7H4FO+ 4 123.0241 0.01
123.0352 C6H4FN2+ 1 123.0353 -1.01
124.0391 CH5FN4O2+ 5 124.0391 -0.4
125.0597 C7H9O2+ 7 125.0597 0.21
126.0105 C6H5ClN+ 8 126.0105 0.28
127.0184 C6H6ClN+ 7 127.0183 0.84
127.0293 C8H3N2+ 5 127.0291 1.41
128.0023 C6H5ClO+ 6 128.0023 -0.53
128.0369 C8H4N2+ 5 128.0369 -0.13
129.0099 CH5ClFN3O+ 6 129.01 -0.25
129.0446 C8H5N2+ 4 129.0447 -0.93
130.0288 C8H4NO+ 7 130.0287 0.44
130.0399 C7H4N3+ 8 130.04 -0.64
131.0369 C5H8ClN2+ 7 131.0371 -1.05
131.049 C4H6FN3O+ 8 131.0489 0.33
131.0602 C8H7N2+ 4 131.0604 -1.57
132.0243 C8H3FN+ 1 132.0244 -0.81
132.0443 C3H5FN4O+ 7 132.0442 0.6
132.0554 C7H6N3+ 7 132.0556 -1.51
133.0322 C8H4FN+ 1 133.0322 -0.44
133.0395 C7H5N2O+ 5 133.0396 -1.32
133.0521 C3H6FN4O+ 7 133.052 0.39
134.0234 C2H3FN4O2+ 7 134.0235 -0.67
134.04 C8H5FN+ 1 134.0401 -0.76
134.0472 C7H6N2O+ 6 134.0475 -1.86
134.0599 C3H7FN4O+ 7 134.0598 0.52
135.024 C8H4FO+ 4 135.0241 -0.58
135.0311 C2H4FN4O2+ 6 135.0313 -1.54
135.0359 C7H4FN2+ 2 135.0353 4.15
135.0477 C8H6FN+ 2 135.0479 -1.52
135.0551 C7H7N2O+ 6 135.0553 -1.03
136.0391 C2H5FN4O2+ 7 136.0391 0.06
137.0027 C7H4ClN+ 7 137.0027 -0.02
137.0272 C7H4FNO+ 4 137.0271 0.61
137.047 C7H7NO2+ 6 137.0471 -0.6
138.0105 C7H5ClN+ 8 138.0105 -0.33
138.9949 C7H4ClO+ 5 138.9945 2.92
139.0056 C6H4ClN2+ 7 139.0058 -1.06
140.0026 C7H5ClO+ 6 140.0023 1.83
140.0366 C9H4N2+ 6 140.0369 -1.95
140.9901 C7H3ClF+ 1 140.9902 -0.78
141.0098 C2H5ClFN3O+ 6 141.01 -1.08
141.0449 C9H5N2+ 6 141.0447 1.44
142.0399 C8H4N3+ 9 142.04 -0.79
142.0523 C9H6N2+ 7 142.0525 -1.56
143.006 C7H5ClF+ 2 143.0058 0.87
143.0478 C8H5N3+ 9 143.0478 -0.33
144.0317 C8H4N2O+ 7 144.0318 -0.59
144.0445 C9H6NO+ 8 144.0444 1.09
144.0555 C8H6N3+ 9 144.0556 -1.16
145.0395 C8H5N2O+ 7 145.0396 -0.77
146.0234 C3H3FN4O2+ 7 146.0235 -0.07
146.0469 C8H6N2O+ 7 146.0475 -3.67
147.0355 C8H4FN2+ 2 147.0353 1.13
147.055 C8H7N2O+ 7 147.0553 -1.66
147.9948 C8H3ClN+ 6 147.9949 -0.54
148.0305 C7H3FN3+ 7 148.0306 -0.59
148.0436 C8H5FN2+ 2 148.0431 3.1
149.0272 C8H4FNO+ 4 149.0271 0.68
149.0513 C8H6FN2+ 2 149.051 2.38
150.0349 C8H5FNO+ 5 150.035 -0.63
151.0057 C7H4ClN2+ 7 151.0058 -0.55
151.0425 C8H6FNO+ 5 151.0428 -1.81
152.0506 C8H7FNO+ 5 152.0506 -0.28
153.0456 C7H6FN2O+ 6 153.0459 -1.83
154.0398 C9H4N3+ 10 154.04 -0.9
154.9894 C7H4ClO2+ 5 154.9894 -0.18
155.024 C9H3N2O+ 8 155.024 -0.05
156.0557 C9H6N3+ 10 156.0556 0.42
157.0396 C9H5N2O+ 8 157.0396 -0.3
158.0167 C7H6ClFN+ 4 158.0167 -0.46
158.0235 C3H8ClFN2O2+ 8 158.0253 -11.14
158.0472 C9H6N2O+ 8 158.0475 -1.92
159.0353 C9H4FN2+ 3 159.0353 0.21
159.0426 C8H5N3O+ 10 159.0427 -0.72
159.0553 C9H7N2O+ 8 159.0553 -0.16
160.0267 C8H4N2O2+ 6 160.0267 -0.09
160.0432 C9H5FN2+ 3 160.0431 0.23
160.0504 C8H6N3O+ 10 160.0505 -0.98
161.027 C9H4FNO+ 5 161.0271 -0.67
161.0345 C8H5N2O2+ 6 161.0346 -0.26
161.0705 C9H9N2O+ 9 161.0709 -2.58
162.0348 C9H5FNO+ 5 162.035 -0.74
162.0424 C8H6N2O2+ 6 162.0424 0.14
162.0544 C4H7FN4O2+ 10 162.0548 -1.94
163.0057 C8H4ClN2+ 7 163.0058 -0.57
163.0303 C8H4FN2O+ 6 163.0302 0.8
163.0424 C9H6FNO+ 6 163.0428 -2.68
163.0498 C8H7N2O2+ 7 163.0502 -2.37
164.0009 C7H3ClN3+ 7 164.001 -0.44
164.034 C3H5FN4O3+ 7 164.034 0.13
165.0218 C8H4FNO2+ 8 165.0221 -1.45
165.0459 C8H6FN2O+ 6 165.0459 -0.01
166.0054 C8H5ClNO+ 9 166.0054 0.17
166.0299 C8H5FNO2+ 6 166.0299 0.05
167.0377 C8H6FNO2+ 6 167.0377 0.16
167.0477 C10H5N3+ 10 167.0478 -0.88
168.001 C8H4ClFN+ 3 168.0011 -0.54
168.0318 C10H4N2O+ 8 168.0318 0
168.0453 C8H7FNO2+ 8 168.0455 -1.64
169.0394 C10H5N2O+ 9 169.0396 -1.25
170.0348 C9H4N3O+ 11 170.0349 -0.58
171.019 C9H3N2O2+ 7 171.0189 0.36
171.0553 C10H7N2O+ 8 171.0553 0.31
172.0431 C10H5FN2+ 3 172.0431 0.04
172.0504 C9H6N3O+ 12 172.0505 -0.72
173.0388 C8H10ClO2+ 7 173.0364 13.71
173.0508 C10H6FN2+ 4 173.051 -0.74
174.0465 C14H6+ 7 174.0464 0.69
174.0664 C2H16ClFO5+ 12 174.0665 -0.44
175.0301 C9H4FN2O+ 7 175.0302 -0.74
176.0379 C9H5FN2O+ 7 176.038 -1.06
177.0217 C9H6ClN2+ 8 177.0214 1.4
177.0457 C9H6FN2O+ 7 177.0459 -0.7
178.0298 C9H5FNO2+ 8 178.0299 -0.73
179.0005 C8H4ClN2O+ 7 179.0007 -0.75
179.0609 C12H7N2+ 7 179.0604 2.83
182.0349 C10H4N3O+ 13 182.0349 -0.04
182.061 C9H9FNO2+ 8 182.0612 -0.74
183.0121 C8H5ClFN2+ 4 183.012 0.65
183.9959 C8H4ClFNO+ 6 183.996 -0.63
185.039 C9H10ClO2+ 6 185.0364 13.99
186.0299 C9H4N3O2+ 11 186.0298 0.49
186.0459 C10H5FN3+ 8 186.0462 -1.62
187.0302 C10H4FN2O+ 7 187.0302 0.07
187.0409 C5H11ClFNO3+ 11 187.0406 1.58
187.0534 C6H13ClFO3+ 9 187.0532 1.24
188.0379 C10H5FN2O+ 7 188.038 -0.89
189.0458 C10H6FN2O+ 7 189.0459 -0.13
190.0308 C7H8ClFN2O+ 6 190.0304 2.01
190.0409 C9H5FN3O+ 11 190.0411 -0.98
191.0249 C9H4FN2O2+ 8 191.0251 -1
192.0679 C13H8N2+ 9 192.0682 -1.74
193.041 C9H6FN2O2+ 8 193.0408 1.03
194.0601 C13H8NO+ 11 194.06 0.4
195.0122 C9H5ClFN2+ 6 195.012 1.16
195.0326 C9H6FNO3+ 8 195.0326 -0.32
195.0567 C9H8FN2O2+ 8 195.0564 1.22
195.9957 C12HFO2+ 6 195.9955 1.12
196.0506 C11H6N3O+ 13 196.0505 0.15
197.0634 C13H8FN+ 4 197.0635 -0.72
198.0296 C10H4N3O2+ 11 198.0298 -1.22
199.0409 C6H11ClFNO3+ 11 199.0406 1.73
200.0465 C7H7FN3O3+ 12 200.0466 -0.31
201.0332 C10H4FN3O+ 11 201.0333 -0.46
202.0528 C14H6N2+ 9 202.0525 1.05
203.0248 C10H4FN2O2+ 9 203.0251 -1.58
203.0494 C6H13ClFO4+ 10 203.0481 6.41
203.0602 C14H7N2+ 9 203.0604 -0.95
204.0329 C10H5FN2O2+ 8 204.033 -0.05
204.0561 C6H14ClFO4+ 12 204.0559 1.02
205.0406 C10H6FN2O2+ 8 205.0408 -0.77
205.0605 C10H9N2O3+ 7 205.0608 -1.2
207.0562 C10H8FN2O2+ 8 207.0564 -1.07
213.0334 C11H4FN3O+ 11 213.0333 0.44
213.0567 C7H13ClFNO3+ 11 213.0563 1.9
214.041 C11H5FN3O+ 11 214.0411 -0.53
215.049 C16H7O+ 11 215.0491 -0.43
215.0599 C15H7N2+ 9 215.0604 -2.15
216.0565 C11H7FN3O+ 12 216.0568 -1.1
217.0405 C11H6FN2O2+ 9 217.0408 -1.19
218.036 C10H5FN3O2+ 12 218.036 -0.09
218.0716 C7H16ClFO4+ 13 218.0716 0.2
219.0553 C14H7N2O+ 11 219.0553 -0.15
220.0277 C10H5FN2O3+ 10 220.0279 -0.56
221.0459 C12H5N4O+ 13 221.0458 0.62
222.0588 C14H7FN2+ 5 222.0588 -0.08
223.0665 C14H8FN2+ 5 223.0666 -0.53
223.9908 C10H4ClFNO2+ 7 223.9909 -0.54
225.0583 C14H8FNO+ 8 225.0584 -0.72
226.0532 C13H7FN2O+ 9 226.0537 -2.29
228.044 C11H5FN4O+ 13 228.0442 -0.99
229.0284 C16H5O2+ 12 229.0284 -0.14
229.0516 C11H6FN4O+ 13 229.052 -1.63
230.0359 C11H5FN3O2+ 13 230.036 -0.71
230.0709 C15H8N3+ 13 230.0713 -1.74
232.0632 C15H8N2O+ 11 232.0631 0.25
239.0013 C13H2FNO3+ 9 239.0013 -0.26
239.037 C14H8ClN2+ 12 239.0371 -0.04
239.0563 C12H7N4O2+ 10 239.0564 -0.29
239.9854 C13HFO4+ 9 239.9853 0.23
240.0439 C12H5FN4O+ 14 240.0442 -1.16
241.0516 C8H13ClFNO4+ 14 241.0512 1.64
243.0667 C8H15ClFNO4+ 14 243.0668 -0.27
248.0619 C15H7FN3+ 9 248.0619 0.05
249.0694 C15H8FN3+ 10 249.0697 -1.21
250.0533 C15H7FN2O+ 10 250.0537 -1.65
250.0772 C15H9FN3+ 10 250.0775 -1.25
251.0613 C15H8FN2O+ 9 251.0615 -0.83
252.0691 C15H9FN2O+ 9 252.0693 -0.87
255.0313 C12H4FN4O2+ 12 255.0313 0.22
257.0467 C12H6FN4O2+ 13 257.0469 -1.05
257.0595 C13H8FN3O2+ 14 257.0595 -0.11
261.0671 C13H10FN2O3+ 11 261.067 0.23
262.0536 C16H7FN2O+ 9 262.0537 -0.23
263.0601 C19H7N2+ 11 263.0604 -1.15
264.032 C18H4N2O+ 11 264.0318 0.59
266.0125 C11H6ClFN3O2+ 10 266.0127 -0.77
277.0643 C16H8FN3O+ 13 277.0646 -0.88
278.0721 C16H9FN3O+ 13 278.0724 -1.14
279.0563 C16H8FN2O2+ 12 279.0564 -0.39
280.0642 C16H9FN2O2+ 12 280.0643 -0.1
298.0611 C18H8N3O2+ 13 298.0611 0.12
301.0719 C17H9N4O2+ 10 301.072 -0.19
304.0514 C17H7FN3O2+ 13 304.0517 -0.89
306.0671 C17H9FN3O2+ 13 306.0673 -0.76
313.0717 C18H9N4O2+ 10 313.072 -1.02
315.0329 C16H9ClFN2O2+ 11 315.0331 -0.68
318.0672 C18H9FN3O2+ 13 318.0673 -0.41
320.0229 C17H5FN2O4+ 10 320.0228 0.23
331.0622 C18H8FN4O2+ 12 331.0626 -1.03
339.0445 C17H9ClFN4O+ 11 339.0443 0.6
340.0283 C17H8ClFN3O2+ 8 340.0284 -0.14
342.0441 C17H10ClFN3O2+ 8 342.044 0.24
367.0394 C18H9ClFN4O2+ 8 367.0393 0.41
PK$NUM_PEAK: 307
PK$PEAK: m/z int. rel.int.
50.015 6307 2
51.023 14812.9 6
52.0182 4377 1
52.0307 4497.8 1
53.0022 16924.2 6
53.0386 37742.8 15
53.9975 3501.2 1
55.0178 9932.4 4
56.0131 6222.8 2
63.0229 46536 19
64.0181 15109.5 6
64.0307 8273.8 3
65.0385 214086.4 88
66.0463 11584.8 4
68.0496 3259.9 1
68.9971 3522.8 1
69.0083 12580 5
69.9923 53344.5 21
70.0086 6150.3 2
71.029 3825.4 1
72.0243 3415.1 1
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//
