MassBank Record: MSBNK-RIKEN_NPDepo-NGA03682
ACCESSION: MSBNK-RIKEN_NPDepo-NGA03682
RECORD_TITLE: Ajmaline; LC-ESI-QQQ; MS2; Frag=135.0V CID@15.0; [M+HCOO]-
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant
COMMENT: Formula(Parent): C20H26N2O2
COMMENT: Bottle Name:Ajmaline
COMMENT: PRIME Parent Name:Ajmaline
COMMENT: PRIME in-house No.:V0319
COMMENT: SubCategory_DNP: Monoterpenoid indole alkaloids, Ajmaline alkaloids, Indole alkaloids
CH$NAME: Ajmalin
CH$NAME: Cardiorythmine
CH$NAME: Raugalline
CH$NAME: Rauwolfine
CH$NAME: Tachmalin
CH$NAME: Ajmalan-17,21-diol
CH$NAME: (13S,16S,18S,1R,14R,17R)-13-ethyl-8-methyl-8,15-diazahexacyclo(14.2.1.0(1,9).0(2,7).0(10,15).0(12,17))nonadeca-2(7),3,5-triene-14,18-diol
CH$NAME: Ajmaline
CH$COMPOUND_CLASS: Alkaloids
CH$FORMULA: C20H26N2O2
CH$EXACT_MASS: 326.4424
CH$SMILES: CC[C@H]1C2CC3C4N(C)c5ccccc5[C@]45C[C@@H](C2C5O)N3[C@@H]1O
CH$IUPAC: InChI=1S/C20H26N2O2/c1-3-10-11-8-14-17-20(12-6-4-5-7-13(12)21(17)2)9-15(16(11)18(20)23)22(14)19(10)24/h4-7,10-11,14-19,23-24H,3,8-9H2,1-2H3/t10-,11?,14?,15-,16?,17?,18?,19+,20+/m0/s1
CH$LINK: CAS
4360-12-7
CH$LINK: CHEMSPIDER
10469368
CH$LINK: INCHIKEY
CJDRUOGAGYHKKD-GHVJXGQCSA-N
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+HCOO]-
PK$SPLASH: splash10-00di-4898880000-3c58d7742ca2fa6a66a2
PK$NUM_PEAK: 3740
PK$PEAK: m/z int. rel.int.
50.8 1.65 1
50.9 5.87 5
51.0 11.83 11
51.1 14.8 14
51.2 12.77 12
51.5 7.86 7
51.6 12.69 12
51.7 15.72 15
51.8 13.72 13
51.9 7.64 7
52.1 1.45 1
52.2 6.24 6
52.3 12.21 12
52.4 14.57 14
52.5 11.79 11
52.8 6.79 6
52.9 11.87 11
53.0 15.37 15
53.1 14.61 14
53.2 10.56 10
54.1 6.03 6
54.2 10.42 10
54.3 14.08 14
54.4 13.84 13
54.5 9.96 9
54.7 6.9 6
54.8 11.35 11
54.9 15.23 15
55.0 14.17 14
55.1 8.46 8
55.3 2.52 2
55.4 7.98 7
55.5 15.07 15
55.6 18.14 18
55.7 14.67 14
55.8 7.73 7
56.0 4.71 4
56.1 10.48 10
56.2 15.59 15
56.3 16.16 16
56.4 12.33 12
56.6 6.49 6
56.7 9.74 9
56.8 14.39 14
56.9 15.67 15
57.0 11.93 11
57.9 6.47 6
58.0 10.09 10
58.1 12.93 12
58.2 12.53 12
58.3 9.0 8
58.5 3.69 3
58.6 7.09 7
58.7 12.77 12
58.8 16.09 16
58.9 14.48 14
59.2 9.33 9
59.3 13.76 13
59.4 16.25 16
59.5 13.98 13
59.6 8.65 8
59.8 5.29 5
59.9 9.63 9
60.0 14.25 14
60.1 15.7 15
60.2 13.16 13
60.5 7.28 7
60.6 11.65 11
60.7 15.4 15
60.8 15.43 15
60.9 12.42 12
61.1 9.84 9
61.2 13.0 12
61.3 16.53 16
61.4 16.76 16
61.5 12.43 12
62.4 4.28 4
62.5 9.14 9
62.6 14.1 14
62.7 15.08 15
62.8 11.38 11
63.0 5.4 5
63.1 8.92 8
63.2 13.44 13
63.3 14.13 14
63.4 9.94 9
63.6 4.0 3
63.7 8.24 8
63.8 14.0 13
63.9 16.4 16
64.0 13.46 13
64.1 7.44 7
64.3 2.8 2
64.4 6.47 6
64.5 10.75 10
64.6 12.36 12
64.7 10.23 10
65.0 5.56 5
65.1 9.99 9
65.2 13.03 13
65.3 11.77 11
65.4 7.36 7
65.6 4.92 4
65.7 9.56 9
65.8 13.06 13
65.9 11.38 11
66.2 3.19 3
66.3 10.22 10
66.4 16.88 16
66.5 18.17 18
66.6 13.94 13
66.9 8.23 8
67.0 12.88 12
67.1 15.59 15
67.2 13.54 13
67.3 8.18 8
67.5 4.61 4
67.6 8.9 8
67.7 13.02 13
67.8 13.57 13
67.9 10.63 10
68.8 4.08 4
68.9 8.77 8
69.0 13.13 13
69.1 14.22 14
69.2 11.26 11
69.5 6.88 6
69.6 11.07 11
69.7 13.21 13
69.8 11.36 11
70.1 8.04 8
70.2 13.35 13
70.3 16.79 16
70.4 14.57 14
70.5 8.08 8
70.7 3.62 3
70.8 9.08 9
70.9 14.22 14
71.0 14.66 14
71.1 10.29 10
71.3 3.53 3
71.4 6.97 6
71.5 12.77 12
71.6 16.28 16
71.7 14.76 14
71.8 9.84 9
72.0 7.19 7
72.1 11.33 11
72.2 14.28 14
72.3 13.15 13
72.4 8.98 8
72.6 4.99 4
72.7 7.77 7
72.8 11.22 11
72.9 12.58 12
73.0 10.86 10
73.2 6.65 6
73.3 9.03 9
73.4 13.48 13
73.5 16.49 16
73.6 15.55 15
73.7 11.33 11
74.0 6.78 6
74.1 9.84 9
74.2 11.68 11
74.3 10.48 10
74.6 5.65 5
74.7 10.48 10
74.8 14.51 14
74.9 13.72 13
75.2 7.07 7
75.3 12.18 12
75.4 15.81 15
75.5 14.61 14
75.6 10.01 9
75.8 6.59 6
75.9 9.91 9
76.0 13.15 13
76.1 13.67 13
76.2 11.32 11
76.4 7.75 7
76.5 10.4 10
76.6 14.3 14
76.7 15.62 15
76.8 12.39 12
77.1 7.09 7
77.2 12.66 12
77.3 16.28 16
77.4 14.83 14
77.5 9.71 9
77.7 4.92 4
77.8 8.23 8
77.9 11.74 11
78.0 12.25 12
78.1 9.5 9
78.4 5.86 5
78.5 9.96 9
78.6 13.85 13
78.7 14.39 14
78.8 10.64 10
79.7 6.88 6
79.8 11.41 11
79.9 14.35 14
80.0 13.57 13
80.1 10.09 10
80.3 7.54 7
80.4 10.15 10
80.5 12.02 12
80.6 11.02 11
80.7 7.79 7
80.9 4.61 4
81.0 7.58 7
81.1 11.89 11
81.2 14.25 14
81.3 12.62 12
81.6 7.66 7
81.7 11.63 11
81.8 13.97 13
81.9 12.09 12
82.0 7.26 7
82.2 4.51 4
82.3 9.85 9
82.4 15.61 15
82.5 17.29 17
82.6 13.79 13
83.5 7.58 7
83.6 11.87 11
83.7 15.02 15
83.8 14.61 14
83.9 11.24 11
84.8 5.37 5
84.9 8.93 8
85.0 12.8 12
85.1 13.07 13
85.2 9.31 9
85.4 5.11 5
85.5 9.22 9
85.6 14.1 14
85.7 15.7 15
85.8 12.53 12
86.1 5.49 5
86.2 11.26 11
86.3 15.53 15
86.4 14.03 14
86.5 8.1 8
86.7 4.57 4
86.8 9.71 9
86.9 14.08 14
87.0 13.98 13
87.1 9.9 9
87.3 6.21 6
87.4 10.57 10
87.5 14.95 14
87.6 15.27 15
87.7 11.24 11
88.6 5.1 5
88.7 10.2 10
88.8 15.33 15
88.9 16.18 16
89.0 12.43 12
89.9 7.23 7
90.0 11.83 11
90.1 15.42 15
90.2 14.98 14
90.3 11.11 11
90.5 7.39 7
90.6 11.11 11
90.7 15.3 15
90.8 15.99 15
90.9 11.96 11
91.0 5.86 5
91.2 3.44 3
91.3 8.84 8
91.4 14.04 14
91.5 14.69 14
91.6 10.32 10
91.8 4.44 4
91.9 8.14 8
92.0 12.24 12
92.1 12.64 12
92.2 9.28 9
92.4 4.95 4
92.5 8.18 8
92.6 12.87 12
92.7 14.86 14
92.8 11.87 11
92.9 6.13 6
93.1 3.37 3
93.2 7.73 7
93.3 11.67 11
93.4 12.24 12
93.5 9.52 9
93.7 6.56 6
93.8 10.41 10
93.9 15.18 15
94.0 16.88 16
94.1 13.76 13
94.2 7.99 7
94.4 5.43 5
94.5 10.78 10
94.6 15.04 15
94.7 14.04 14
94.8 9.09 9
95.0 7.07 7
95.1 11.98 11
95.2 15.94 15
95.3 15.65 15
95.4 11.41 11
96.3 3.59 3
96.4 8.08 8
96.5 13.12 13
96.6 14.48 14
96.7 11.05 11
97.0 5.07 5
97.1 9.85 9
97.2 13.47 13
97.3 12.68 12
97.6 7.07 7
97.7 12.52 12
97.8 16.52 16
97.9 15.29 15
98.0 10.19 10
98.2 6.03 6
98.3 9.87 9
98.4 13.75 13
98.5 14.01 13
98.6 10.16 10
98.9 6.22 6
99.0 11.55 11
99.1 14.92 14
99.2 13.34 13
99.3 8.35 8
99.5 5.62 5
99.6 10.41 10
99.7 14.98 14
99.8 15.29 15
99.9 10.56 10
100.1 2.81 2
100.2 7.26 7
100.3 14.08 14
100.4 17.29 17
100.5 14.41 14
100.8 7.94 7
100.9 12.49 12
101.0 14.93 14
101.1 13.0 12
101.2 8.24 8
101.4 4.52 4
101.5 8.32 8
101.6 12.87 12
101.7 14.39 14
101.8 11.19 11
102.1 5.68 5
102.2 11.54 11
102.3 15.1 15
102.4 13.13 13
102.7 6.16 6
102.8 12.45 12
102.9 17.86 17
103.0 17.99 17
103.1 12.64 12
104.0 7.35 7
104.1 12.45 12
104.2 15.9 15
104.3 15.05 15
104.4 10.34 10
104.6 3.56 3
104.7 7.12 7
104.8 12.72 12
104.9 15.24 15
105.0 12.14 12
105.3 4.28 4
105.4 10.51 10
105.5 15.72 15
105.6 15.43 15
105.7 10.13 10
105.9 4.39 4
106.0 8.52 8
106.1 12.74 12
106.2 13.02 13
106.3 9.34 9
106.5 4.63 4
106.6 8.1 8
106.7 12.86 12
106.8 14.89 14
106.9 12.47 12
107.0 7.76 7
107.2 4.54 4
107.3 7.57 7
107.4 10.97 10
107.5 12.18 12
107.8 8.54 8
107.9 10.76 10
108.0 13.29 13
108.1 13.69 13
108.2 11.2 11
108.4 6.05 6
108.5 8.71 8
108.6 13.57 13
108.7 16.06 16
108.8 13.5 13
108.9 7.99 7
109.1 5.31 5
109.2 10.01 9
109.3 14.3 14
109.4 14.41 14
109.5 10.12 10
109.7 4.47 4
109.8 8.23 8
109.9 12.84 12
110.0 14.14 14
110.1 11.16 11
110.4 6.02 6
110.5 10.83 10
110.6 14.7 14
110.7 14.45 14
110.8 10.56 10
111.0 5.71 5
111.1 8.58 8
111.2 12.46 12
111.3 13.87 13
111.4 11.38 11
111.7 7.19 7
111.8 11.6 11
111.9 14.47 14
112.0 13.37 13
112.1 9.46 9
112.3 6.41 6
112.4 9.4 9
112.5 12.69 12
112.6 13.72 13
112.7 11.61 11
113.0 8.1 8
113.1 12.18 12
113.2 14.47 14
113.3 12.86 12
114.2 3.27 3
114.3 8.61 8
114.4 14.04 14
114.5 15.14 15
114.6 11.8 11
115.5 6.88 6
115.6 11.46 11
115.7 15.27 15
115.8 15.23 15
115.9 11.27 11
116.2 6.53 6
116.3 10.72 10
116.4 12.86 12
116.5 10.85 10
116.8 6.79 6
116.9 11.39 11
117.0 15.04 15
117.1 15.1 15
117.2 11.51 11
118.1 6.41 6
118.2 12.02 12
118.3 15.55 15
118.4 14.57 14
118.5 10.63 10
118.7 7.0 6
118.8 9.72 9
118.9 13.02 13
119.0 13.79 13
119.1 10.7 10
119.4 6.06 6
119.5 11.84 11
119.6 15.93 15
119.7 15.15 15
119.8 10.86 10
120.0 7.44 7
120.1 10.44 10
120.2 12.68 12
120.3 11.45 11
120.4 7.38 7
120.6 2.74 2
120.7 5.43 5
120.8 9.63 9
120.9 11.96 11
121.0 10.5 10
121.2 5.53 5
121.3 8.89 8
121.4 14.98 14
121.5 18.37 18
121.6 15.43 15
121.7 8.14 8
121.9 3.41 3
122.0 9.31 9
122.1 15.02 15
122.2 15.59 15
122.3 10.66 10
122.6 5.87 5
122.7 11.89 11
122.8 15.51 15
122.9 14.03 14
123.2 7.42 7
123.3 12.74 12
123.4 16.88 16
123.5 15.78 15
123.6 10.22 10
123.8 4.8 4
123.9 9.17 9
124.0 14.19 14
124.1 15.52 15
124.2 12.09 12
124.5 5.34 5
124.6 10.07 10
124.7 13.81 13
124.8 13.63 13
124.9 10.1 10
125.7 5.49 5
125.8 8.27 8
125.9 12.84 12
126.0 14.8 14
126.1 12.45 12
126.4 7.0 6
126.5 10.98 10
126.6 14.1 14
126.7 13.28 13
126.8 8.76 8
127.0 3.78 3
127.1 8.26 8
127.2 13.85 13
127.3 15.51 15
127.4 11.67 11
128.3 8.18 8
128.4 12.66 12
128.5 15.89 15
128.6 14.86 14
128.7 9.9 9
128.9 3.78 3
129.0 7.48 7
129.1 12.68 12
129.2 15.08 15
129.3 12.88 12
129.6 6.81 6
129.7 11.54 11
129.8 14.9 14
129.9 13.59 13
130.0 8.46 8
130.2 3.87 3
130.3 7.83 7
130.4 11.9 11
130.5 12.24 12
130.6 8.76 8
130.8 4.93 4
130.9 8.4 8
131.0 12.21 12
131.1 12.97 12
131.2 10.41 10
131.5 7.7 7
131.6 11.14 11
131.7 13.63 13
131.8 13.09 13
131.9 9.63 9
132.8 4.73 4
132.9 9.94 9
133.0 13.6 13
133.1 12.68 12
133.2 8.27 8
133.4 5.14 5
133.5 9.65 9
133.6 13.91 13
133.7 13.84 13
133.8 9.59 9
134.0 5.67 5
134.1 9.71 9
134.2 13.95 13
134.3 14.8 14
134.4 11.42 11
134.5 5.92 5
134.7 1.67 1
134.8 6.12 6
134.9 12.02 12
135.0 14.77 14
135.1 12.36 12
135.4 6.88 6
135.5 11.08 11
135.6 13.43 13
135.7 11.63 11
135.8 7.36 7
136.0 5.93 5
136.1 9.27 9
136.2 11.41 11
136.3 10.45 10
136.6 6.25 6
136.7 10.75 10
136.8 15.46 15
136.9 16.38 16
137.0 12.12 12
137.1 5.64 5
137.3 3.51 3
137.4 8.68 8
137.5 12.61 12
137.6 12.33 12
137.9 9.36 9
138.0 13.44 13
138.1 16.0 15
138.2 14.14 14
138.3 8.64 8
138.5 3.05 3
138.6 7.14 7
138.7 12.49 12
138.8 14.98 14
138.9 12.97 12
139.0 8.4 8
139.2 6.34 6
139.3 10.91 10
139.4 14.74 14
139.5 14.28 14
139.6 9.97 9
139.8 6.05 6
139.9 9.78 9
140.0 13.35 13
140.1 13.1 13
140.2 8.95 8
140.4 4.41 4
140.5 8.84 8
140.6 14.49 14
140.7 16.59 16
140.8 13.12 13
140.9 6.59 6
141.1 2.23 2
141.2 7.12 7
141.3 12.66 12
141.4 14.71 14
141.5 12.15 12
142.4 5.11 5
142.5 10.92 10
142.6 14.86 14
142.7 13.05 13
142.8 7.53 7
143.0 4.71 4
143.1 9.41 9
143.2 13.81 13
143.3 14.58 14
143.4 11.41 11
143.7 6.82 6
143.8 11.11 11
143.9 13.82 13
144.0 12.74 12
144.1 9.18 9
144.3 6.81 6
144.4 9.84 9
144.5 12.83 12
144.6 13.34 13
144.7 11.3 11
144.9 8.57 8
145.0 10.72 10
145.1 13.62 13
145.2 14.25 14
145.3 11.01 10
145.6 5.37 5
145.7 11.54 11
145.8 15.83 15
145.9 14.52 14
146.0 9.31 9
146.2 5.51 5
146.3 9.4 9
146.4 13.37 13
146.5 14.19 14
146.6 11.2 11
146.9 7.38 7
147.0 11.35 11
147.1 13.7 13
147.2 12.49 12
147.3 8.65 8
147.5 4.52 4
147.6 7.38 7
147.7 11.36 11
147.8 12.93 12
147.9 10.63 10
148.7 3.75 3
148.8 7.47 7
148.9 13.02 13
149.0 15.86 15
149.1 13.85 13
149.2 9.06 9
149.4 7.01 7
149.5 10.89 10
149.6 13.87 13
149.7 13.75 13
149.8 11.08 11
150.1 7.96 7
150.2 11.02 11
150.3 12.93 12
150.4 11.52 11
150.7 9.03 9
150.8 13.72 13
150.9 17.09 17
151.0 16.56 16
151.1 12.24 12
152.0 7.22 7
152.1 12.23 12
152.2 15.67 15
152.3 14.86 14
152.4 10.72 10
152.6 6.95 6
152.7 11.11 11
152.8 15.8 15
152.9 16.75 16
153.0 13.02 13
153.9 6.57 6
154.0 11.26 11
154.1 15.93 15
154.2 16.85 16
154.3 13.0 12
154.6 7.69 7
154.7 12.72 12
154.8 15.51 15
154.9 13.95 13
155.2 8.45 8
155.3 12.8 12
155.4 16.21 16
155.5 15.02 15
155.6 9.75 9
155.8 4.22 4
155.9 7.98 7
156.0 12.31 12
156.1 13.24 13
156.2 10.0 9
156.4 4.71 4
156.5 8.37 8
156.6 14.19 14
156.7 17.55 17
156.8 15.42 15
156.9 9.4 9
157.1 5.93 5
157.2 11.83 11
157.3 17.12 17
157.4 17.2 17
157.5 12.49 12
158.4 5.9 5
158.5 9.72 9
158.6 13.44 13
158.7 13.98 13
158.8 10.95 10
159.1 6.98 6
159.2 10.61 10
159.3 12.97 12
159.4 12.49 12
159.7 9.75 9
159.8 13.25 13
159.9 16.31 16
160.0 15.71 15
160.1 11.13 11
161.6 6.69 6
161.7 10.81 10
161.8 13.09 13
161.9 10.89 10
162.0 5.75 5
162.2 2.64 2
162.3 7.58 7
162.4 13.22 13
162.5 15.68 15
162.6 14.06 14
163.5 5.07 5
163.6 10.04 10
163.7 14.03 14
163.8 13.56 13
163.9 9.14 9
164.1 3.53 3
164.2 7.58 7
164.3 13.62 13
164.4 16.54 16
164.5 14.19 14
164.8 8.89 8
164.9 13.06 13
165.0 15.4 15
165.1 13.38 13
165.2 8.36 8
165.4 6.05 6
165.5 11.04 11
165.6 15.58 15
165.7 16.15 16
165.8 12.59 12
166.1 6.85 6
166.2 10.88 10
166.3 13.6 13
166.4 12.31 12
166.5 7.88 7
166.7 4.23 4
166.8 9.12 9
166.9 14.95 14
167.0 16.52 16
167.1 11.92 11
168.0 5.97 5
168.1 9.71 9
168.2 12.91 12
168.3 12.91 12
168.4 9.21 9
168.6 3.81 3
168.7 8.27 8
168.8 14.42 14
168.9 16.33 16
169.0 12.11 12
169.9 6.37 6
170.0 11.51 11
170.1 15.68 15
170.2 15.27 15
170.3 10.95 10
170.5 6.54 6
170.6 10.2 10
170.7 14.66 14
170.8 15.9 15
170.9 12.4 12
171.2 6.09 6
171.3 11.51 11
171.4 15.3 15
171.5 14.26 14
171.6 9.72 9
171.8 6.71 6
171.9 10.81 10
172.0 14.96 14
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172.2 12.55 12
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568.8 13.73 13
568.9 13.53 13
569.0 9.5 9
569.2 3.63 3
569.3 7.31 7
569.4 13.15 13
569.5 16.06 16
569.6 13.32 13
569.7 7.25 7
569.9 4.74 4
570.0 10.6 10
570.1 15.59 15
570.2 15.55 15
570.3 11.08 11
570.5 5.97 5
570.6 9.5 9
570.7 14.23 14
570.8 16.21 16
570.9 13.63 13
571.2 7.34 7
571.3 12.56 12
571.4 16.22 16
571.5 14.36 14
571.6 8.2 8
571.8 4.01 4
571.9 8.99 8
572.0 13.1 13
572.1 12.66 12
572.2 8.29 8
572.4 2.47 2
572.5 5.87 5
572.6 11.13 11
572.7 13.79 13
572.8 11.58 11
573.1 5.55 5
573.2 10.57 10
573.3 13.88 13
573.4 12.2 12
573.5 6.94 6
573.7 2.71 2
573.8 6.76 6
573.9 11.39 11
574.0 13.22 13
574.1 11.16 11
574.4 7.25 7
574.5 11.02 11
574.6 13.44 13
574.7 12.24 12
574.8 8.18 8
575.0 4.35 4
575.1 8.51 8
575.2 13.87 13
575.3 16.13 16
575.4 13.66 13
575.7 7.57 7
575.8 12.43 12
575.9 15.99 15
576.0 14.96 14
576.1 10.51 10
576.3 7.42 7
576.4 10.45 10
576.5 12.36 12
576.6 11.08 11
576.9 6.22 6
577.0 9.93 9
577.1 13.98 13
577.2 15.27 15
577.3 12.66 12
577.6 6.12 6
577.7 10.81 10
577.8 14.86 14
577.9 14.38 14
578.0 9.36 9
578.2 2.45 2
578.3 6.52 6
578.4 12.74 12
578.5 15.53 15
578.6 12.36 12
578.9 6.15 6
579.0 12.5 12
579.1 16.57 16
579.2 14.7 14
579.3 8.67 8
579.5 4.64 4
579.6 9.52 9
579.7 14.33 14
579.8 15.3 15
579.9 11.95 11
580.8 6.78 6
580.9 12.08 12
581.0 16.25 16
581.1 15.46 15
581.2 10.29 10
581.4 5.26 5
581.5 9.33 9
581.6 13.46 13
581.7 13.91 13
581.8 10.79 10
582.7 6.25 6
582.8 10.66 10
582.9 14.83 14
583.0 15.3 15
583.1 11.79 11
584.6 3.6 3
584.7 7.66 7
584.8 12.53 12
584.9 14.39 14
585.0 11.8 11
585.3 5.34 5
585.4 9.91 9
585.5 13.72 13
585.6 13.65 13
585.7 10.09 10
585.9 6.52 6
586.0 9.62 9
586.1 12.56 12
586.2 12.05 12
586.5 6.22 6
586.6 10.47 10
586.7 14.64 14
586.8 15.34 15
586.9 11.73 11
587.0 6.05 6
587.2 3.24 3
587.3 7.69 7
587.4 11.33 11
587.5 10.48 10
587.6 5.71 5
587.8 1.67 1
587.9 6.93 6
588.0 13.03 13
588.1 15.12 15
588.2 12.01 11
589.1 6.16 6
589.2 11.61 11
589.3 15.58 15
589.4 15.33 15
589.5 11.63 11
590.4 6.75 6
590.5 12.08 12
590.6 15.36 15
590.7 13.54 13
590.8 8.11 8
591.0 5.08 5
591.1 9.85 9
591.2 14.17 14
591.3 14.83 14
591.4 11.86 11
591.7 8.23 8
591.8 12.23 12
591.9 14.93 14
592.0 13.94 13
592.1 9.91 9
592.3 7.01 7
592.4 10.89 10
592.5 13.97 13
592.6 12.99 12
592.7 8.93 8
592.9 6.22 6
593.0 10.34 10
593.1 14.49 14
593.2 15.04 15
593.3 11.57 11
593.6 8.27 8
593.7 12.62 12
593.8 15.55 15
593.9 14.38 14
594.0 9.49 9
594.2 4.82 4
594.3 9.55 9
594.4 15.12 15
594.5 17.01 16
594.6 14.22 14
594.7 9.56 9
594.9 7.91 7
595.0 11.05 11
595.1 12.96 12
595.2 11.38 11
595.5 6.53 6
595.6 10.85 10
595.7 14.8 14
595.8 15.31 15
595.9 12.06 12
596.8 7.22 7
596.9 11.79 11
597.0 14.69 14
597.1 13.94 13
597.4 9.02 9
597.5 12.04 12
597.6 14.52 14
597.7 13.97 13
597.8 10.26 10
598.0 4.23 4
598.1 7.16 7
598.2 12.55 12
598.3 15.64 15
598.4 13.31 13
598.5 7.28 7
598.7 3.0 2
598.8 8.02 8
598.9 13.25 13
599.0 14.32 14
599.1 10.72 10
//
