MassBank Record: MSBNK-RIKEN_ReSpect-PT207380
ACCESSION: MSBNK-RIKEN_ReSpect-PT207380
RECORD_TITLE: N6-(gamma,gamma-Dimethylallyl)adenosine, Riboprine, Isopentenyladenosine, 2iP Riboside, (2R,3S,4R,5R)-2-(hydroxymethyl)-5-[6-(3-methylbut-2-enylamino)purin-9-yl]oxolane-3,4-diol, N-6-(delta-2-Isopentenyl)adenosinehemihydrate, 2iPA, Dimethylallyladenosine, Isopentenyl adenine riboside, 6-(gamma,gamma-Dimethylallylamino)purine riboside , N-Isopentenyladenosine; LC-ESI-QTOF; MS2
DATE: 2008.07.28
AUTHORS: Matsuda F, Suzuki M, Sawada Y, Plant Science Center, RIKEN.
LICENSE: CC BY-NC
COPYRIGHT: Copyright(C) 2009 Plant Science Center, RIKEN
COMMENT: Build 1 2009/06/24
COMMENT: Acquisition and generation of the data is financially supported in part by CREST/JST.
CH$NAME: N6-(gamma,gamma-Dimethylallyl)adenosine
CH$NAME: Riboprine
CH$NAME: Isopentenyladenosine
CH$NAME: 2iP Riboside
CH$NAME: (2R,3S,4R,5R)-2-(hydroxymethyl)-5-[6-(3-methylbut-2-enylamino)purin-9-yl]oxolane-3,4-diol
CH$NAME: N-6-(delta-2-Isopentenyl)adenosinehemihydrate
CH$NAME: 2iPA
CH$NAME: Dimethylallyladenosine
CH$NAME: Isopentenyl adenine riboside
CH$NAME: 6-(gamma,gamma-Dimethylallylamino)purine riboside
CH$NAME: N-Isopentenyladenosine
CH$COMPOUND_CLASS: CLASS1 Other CLASS2 Nucleoside CLASS3 Adenosine
CH$FORMULA: C15H21N5O4
CH$EXACT_MASS: 335.364
CH$SMILES: CC(=CCNC1=NC=NC2=C1N=CN2C3C(C(C(O3)CO)O)O)C
CH$IUPAC: InChI=1S/C15H21N5O4/c1-8(2)3-4-16-13-10-14(18-6-17-13)20(7-19-10)15-12(23)11(22)9(5-21)24-15/h3,6-7,9,11-12,15,21-23H,4-5H2,1-2H3,(H,16,17,18)
CH$LINK: CAS
7724-76-7
CH$LINK: INCHIKEY
USVMJSALORZVDV-UHFFFAOYSA-N
AC$INSTRUMENT: Q-Tof Premier, Waters
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: COLLISION_ENERGY Ramp 5-45 V
AC$MASS_SPECTROMETRY: CAPILLARY_VOLTAGE 3.0 kV
AC$CHROMATOGRAPHY: SOLVENT CH3CN/H2O
MS$FOCUSED_ION: ION_TYPE [M-H]-
MS$FOCUSED_ION: PRECURSOR_M/Z 334.15155
PK$SPLASH: splash10-0f89-0961000000-e57cf833c2dc4f96fcc4
PK$NUM_PEAK: 5
PK$PEAK: m/z int. rel.int.
133.039 93.69 257
134.0469 363.5 999
202.1096 288.1 792
266.0883 63.79 175
334.1516 68.69 189
//