ACCESSION: MSBNK-MSSJ-MSJ01066
RECORD_TITLE: Azinphos-methyl; GC-EI-Q; MS; Positive; M+*
DATE: 2017.07.13 (Created 2016.12.28)
AUTHORS: Shimadzu Corporation., Kyoto, Japan
LICENSE: CC BY
COPYRIGHT: Shimadzu Cooperation., Kyoto, Japan
PUBLICATION: Shimadzu Collection of Pesticide GCMS Data

CH$NAME: Azinphos-methyl
CH$COMPOUND_CLASS: Non-Natural Product; Pesticides
CH$FORMULA: C₁₀H₁₂N₃O₃PS₂
CH$EXACT_MASS: 317.00577
CH$SMILES: [H]c(c([H])2)c([H])c(N=1)c(c([H])2)C(=O)N(N1)C([H])([H])SP(=S)(OC([H])([H])[H])OC([H])([H])[H]
CH$IUPAC: InChI=1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3
CH$LINK: INCHIKEY CJJOSEISRRTUQB-UHFFFAOYSA-N
CH$LINK: PUBCHEM CID:2268
CH$LINK: COMPTOX DTXSID3020122

AC$INSTRUMENT: GCMS-QP2010 Plus, Shimadzu
AC$INSTRUMENT_TYPE: GC-EI-Q
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION EI
AC$CHROMATOGRAPHY: COLUMN_NAME Ptx-5MS(RESTEK), 0.32 mm I.D. x 30 m, df=0.25 microm
AC$CHROMATOGRAPHY: COLUMN_TEMPERATURE 80 C (1 min)-20 C/min - 180 C - 5 C/min - 330C (10 min)
AC$CHROMATOGRAPHY: INJECTION_TEMPERATURE 260 C
AC$CHROMATOGRAPHY: RETENTION_TIME 18.2 min

MS$FOCUSED_ION: ION_TYPE [M]+*
MS$FOCUSED_ION: PRECURSOR_M/Z 317.01

PK$SPLASH: splash10-0h0r-9800000000-81a9e77b860eaa92c697
PK$NUM_PEAK: 107
PK$PEAK: m/z int. rel.int.
  40 8 8
  41 38 38
  42 38 38
  43 79 79
  44 112 112
  45 75 75
  46 47 47
  47 163 163
  48 27 27
  49 25 25
  50 170 170
  51 215 215
  52 30 30
  53 13 13
  54 18 18
  55 39 39
  56 35 35
  57 56 56
  58 9 9
  59 13 13
  62 73 73
  63 230 230
  64 64 64
  65 26 26
  67 6 6
  69 18 18
  70 39 39
  71 25 25
  72 11 11
  74 53 53
  75 47 47
  76 283 283
  77 999 999
  78 139 139
  79 100 100
  80 29 29
  81 7 7
  82 15 15
  83 5 5
  88 5 5
  89 7 7
  90 47 47
  91 12 12
  92 31 31
  93 314 314
  94 35 35
  95 31 31
  96 7 7
  97 9 9
  98 8 8
  99 6 6
  102 64 64
  103 89 89
  104 348 348
  105 427 427
  106 45 45
  108 11 11
  109 29 29
  111 12 12
  112 14 14
  113 27 27
  116 18 18
  118 20 20
  119 27 27
  121 27 27
  125 143 143
  126 70 70
  127 21 21
  130 15 15
  131 18 18
  132 841 841
  133 117 117
  134 17 17
  135 5 5
  136 43 43
  138 6 6
  140 5 5
  142 5 5
  144 5 5
  145 9 9
  146 18 18
  147 10 10
  149 124 124
  150 8 8
  155 8 8
  156 5 5
  157 22 22
  158 31 31
  159 5 5
  160 725 725
  161 104 104
  164 8 8
  166 5 5
  167 41 41
  171 19 19
  172 7 7
  176 5 5
  181 5 5
  193 8 8
  205 7 7
  222 17 17
  231 19 19
  249 9 9
  279 14 14
  281 13 13
  365 5 5
  370 10 10
//