ACCESSION: MSBNK-RIKEN_ReSpect-PS073804
RECORD_TITLE: N6-(gamma,gamma-Dimethylallyl)adenosine, Riboprine, Isopentenyladenosine, 2iP Riboside, N-6-(delta-2-Isopentenyl)adenosinehemihydrate, 2iPA, Dimethylallyladenosine, Isopentenyl adenine riboside, 6-(gamma,gamma-Dimethylallylamino)purine riboside , N-Isopentenyladenosine; LC-ESI-QQ; MS2
DATE: 2009.02.09
AUTHORS: Sawada Y, Matsuda F, and Hirai MY. Plant Science Center, RIKEN
LICENSE: CC BY-NC
COPYRIGHT: Copyright(C) 2008 Plant Science Center, RIKEN
PUBLICATION: Sawada, Y.; Akiyama, K.; Sakata, A.; Kuwahara, A.; Otsuki, H.; Sakurai, T.; Saito, K.; Hirai, M. Y. Widely Targeted Metabolomics Based on Large-Scale MS/MS Data for Elucidating Metabolite Accumulation Patterns in Plants. Plant and Cell Physiology 2008, 50 (1), 37–47. DOI:10.1093/pcp/pcn183
COMMENT: Build 5
COMMENT: Data acquisition and generation is financially supported in part by CREST/JST.
COMMENT: Source compound SIGMA, D7257.
COMMENT: PRIMe compound in-house ID S0136
COMMENT: This spectra was automatically generated from the raw data without manual curation of data quality.
COMMENT: The spectral data and services are available to the research and academic community only.
COMMENT: All users must cite follwing literature in publication(s).

CH$NAME: N6-(gamma,gamma-Dimethylallyl)adenosine
CH$NAME: Riboprine
CH$NAME: Isopentenyladenosine
CH$NAME: 2iP Riboside
CH$NAME: N-6-(delta-2-Isopentenyl)adenosinehemihydrate
CH$NAME: 2iPA
CH$NAME: Dimethylallyladenosine
CH$NAME: Isopentenyl adenine riboside
CH$NAME: 6-(gamma,gamma-Dimethylallylamino)purine riboside
CH$NAME: N-Isopentenyladenosine
CH$COMPOUND_CLASS: CLASS1 Other CLASS2 Nucleoside CLASS3 Adenosine
CH$FORMULA: C₁₅H₂₁N₅O₄
CH$EXACT_MASS: 335.364
CH$SMILES: CC(=CCNC1=NC=NC2=C1N=CN2C3C(C(C(O3)CO)O)O)C
CH$IUPAC: InChI=1S/C15H21N5O4/c1-8(2)3-4-16-13-10-14(18-6-17-13)20(7-19-10)15-12(23)11(22)9(5-21)24-15/h3,6-7,9,11-12,15,21-23H,4-5H2,1-2H3,(H,16,17,18)
CH$LINK: CAS 7724-76-7
CH$LINK: KEGG C16427
CH$LINK: PUBCHEM CID:24405
CH$LINK: INCHIKEY USVMJSALORZVDV-UHFFFAOYSA-N

AC$INSTRUMENT: TQD, Waters
AC$INSTRUMENT_TYPE: LC-ESI-QQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 40

MS$FOCUSED_ION: ION_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_M/Z 336.37

PK$SPLASH: splash10-000j-1910000000-87b6a17c53f2c3a1f14e
PK$NUM_PEAK: 8
PK$PEAK: m/z int. rel.int.
  68.0 20531.0 36
  69.0 122236.0 212
  135.0 63125.0 109
  136.0 576663.0 999
  147.0 70165.0 122
  148.0 307156.0 532
  203.0 48660.0 84
  204.0 149947.0 260
//