MassBank Record: CA000072



 Anhydrolutein-III; FAB-EBEB; MS2; m/z: 550.42; [M]+* 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: CA000072
RECORD_TITLE: Anhydrolutein-III; FAB-EBEB; MS2; m/z: 550.42; [M]+*
DATE: 2016.01.19 (Created 2010.04.01, modified 2011.05.10)
AUTHORS: Akimoto N, Graduate School of Pharmaceutical Sciences, Kyoto University and Maoka T, Research Institute for Production Development
LICENSE: CC BY-SA
PUBLICATION: Khachik, F.; Englert, G.; Beecher, G. R.; Smith Jr. J. C. Isolation, structural elucidation, and partial synthesis of lutein dehydration products in extracts from human plasma. J. Chromatogr. B., 1995, 670, 219-233
COMMENT: Profile spectrum of this record is given as a JPEG file.
COMMENT: [Profile] CA000072.jpg

CH$NAME: Anhydrolutein-III CH$COMPOUND_CLASS: N/A CH$FORMULA: C40H54O CH$EXACT_MASS: 550.41747 CH$SMILES: C(=CC=C(C)C=CC(=C(C)2)C(C)(C)CC(C2)O)C(C)=CC=CC=C(C=CC=C(C=CC(=C1C)C(CC=C1)(C)C)C)C CH$IUPAC: InChI=1S/C40H54O/c1-30(18-13-20-32(3)23-25-37-34(5)22-15-27-39(37,7)8)16-11-12-17-31(2)19-14-21-33(4)24-26-38-35(6)28-36(41)29-40(38,9)10/h11-26,36,41H,27-29H2,1-10H3/b12-11+,18-13+,19-14+,25-23+,26-24+,30-16+,31-17+,32-20+,33-21+/t36-/m1/s1
AC$INSTRUMENT: JMS-HX/HX 110A, JEOL AC$INSTRUMENT_TYPE: FAB-EBEB AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: ATOM_GUN_CURRENT 5 mA AC$MASS_SPECTROMETRY: BOMBARDMENT 6 kV xenon AC$MASS_SPECTROMETRY: COLLISION_ENERGY 3 kV AC$MASS_SPECTROMETRY: COLLISION_GAS Ar AC$MASS_SPECTROMETRY: GAS_PRESSURE adjust to attenuate the intensity of the precursor ion by 30 % AC$MASS_SPECTROMETRY: IONIZATION FAB AC$MASS_SPECTROMETRY: MATRIX 1-2 uL m-NBA AC$MASS_SPECTROMETRY: PROBE_TIP stainless-steel
MS$FOCUSED_ION: BASE_PEAK 104.9595 MS$FOCUSED_ION: PRECURSOR_M/Z 550.42 MS$FOCUSED_ION: PRECURSOR_TYPE [M]+* MS$DATA_PROCESSING: RELATIVE_M/Z normalised by peak(m/z=104.9595). set 999 for peak(m/z=550.2652,rel=1949).
PK$SPLASH: splash10-0udl-2910010000-df74653d502154508982 PK$NUM_PEAK: 992 PK$PEAK: m/z int. rel.int. 11.9639 0.03 1 12.9708 0.02 0 13.9726 0.07 1 14.9786 0.23 4 15.9851 0.01 0 17.9892 0.02 0 22.9324 0.03 1 24.2517 0.01 0 24.9431 0.07 1 25.9555 0.51 10 26.9572 3.10 60 27.1557 0.01 0 27.9631 0.23 4 28.9652 2.91 57 29.9390 0.01 0 30.9411 0.28 5 36.9346 0.44 9 37.2665 0.01 0 37.9369 0.95 19 38.2515 0.01 0 38.5555 0.02 0 38.9433 6.89 134 39.4925 0.01 0 39.9511 0.88 17 40.9602 14.88 290 41.2322 0.02 0 41.4686 0.01 0 41.9403 0.20 4 42.4217 0.01 0 42.9600 7.59 148 43.9364 0.14 3 44.9534 0.30 6 45.9885 0.02 0 47.9362 0.02 0 48.9260 0.19 4 49.1710 0.02 0 49.9300 2.16 42 50.1491 0.02 0 50.2856 0.02 0 50.6690 0.02 0 50.9340 4.35 85 51.3072 0.01 0 51.9431 1.29 25 52.9473 8.27 161 53.3231 0.02 0 53.9507 0.32 6 54.9594 16.90 329 55.9748 0.22 4 56.1521 0.02 0 56.9720 5.47 107 57.3420 0.03 1 57.9781 0.23 4 58.6265 0.02 0 58.9504 0.92 18 59.9050 0.04 1 60.9209 0.25 5 61.2366 0.02 0 61.9284 1.01 20 62.1330 0.02 0 62.6238 0.03 1 62.9290 3.36 66 63.3243 0.04 1 63.6990 0.02 0 63.9391 0.84 16 64.3988 0.02 0 64.9400 6.54 128 65.3678 0.04 1 65.9458 1.11 22 66.2551 0.01 0 66.9480 9.76 190 67.1212 0.03 1 67.5191 0.04 1 67.9517 0.33 6 68.4347 0.02 0 68.9580 10.56 206 69.4612 0.04 1 69.9609 0.14 3 70.4511 0.03 1 70.9448 1.47 29 71.6723 0.03 1 71.9688 0.03 1 72.9127 0.10 2 73.0846 0.03 1 73.2500 0.01 0 73.9102 1.01 20 74.1907 0.01 0 74.5200 0.01 0 74.9242 1.20 23 75.0529 0.17 3 75.9258 1.03 20 76.1270 0.04 1 76.3067 0.03 1 76.9249 19.68 384 77.1250 0.13 3 77.9308 3.24 63 78.1238 0.14 3 78.9403 17.12 334 79.1719 0.05 1 79.3476 0.02 0 79.6411 0.05 1 79.9477 1.62 32 80.3045 0.04 1 80.9505 16.72 326 81.1952 0.06 1 81.3798 0.02 0 81.9482 0.41 8 82.3860 0.05 1 82.9594 4.22 82 83.2783 0.02 0 83.7731 0.03 1 83.9505 0.14 3 84.1699 0.02 0 84.5177 0.02 0 84.9430 4.85 95 85.3791 0.02 0 85.9215 0.48 9 86.5451 0.02 0 86.9138 0.60 12 87.9239 0.26 5 88.0350 0.04 1 88.9313 1.86 36 89.0948 0.20 4 89.9393 0.57 11 90.9393 39.27 766 91.2674 0.09 2 91.9444 2.90 57 92.1738 0.03 1 92.9593 24.39 476 93.3709 0.06 1 93.9642 1.20 23 94.1272 0.03 1 94.9694 11.45 223 95.3140 0.10 2 95.5606 0.01 0 95.9633 0.38 7 96.4293 0.01 0 96.9616 1.17 23 97.1804 0.03 1 97.4542 0.01 0 97.9192 0.27 5 98.9313 0.25 5 99.9424 0.10 2 100.2124 0.02 0 100.9226 0.50 10 101.9435 1.99 39 102.9509 7.10 138 103.4338 0.11 2 103.9496 2.76 54 104.9595 51.24 999 105.3540 0.06 1 105.9643 4.52 88 106.9733 18.54 361 107.2681 0.12 2 107.9632 0.88 17 108.1884 0.04 1 108.4267 0.03 1 108.9815 8.45 165 109.3493 0.07 1 109.9557 0.18 4 110.2281 0.01 0 110.3896 0.03 1 110.9630 0.93 18 111.2137 0.03 1 111.5087 0.01 0 111.9653 0.03 1 112.9452 0.58 11 113.9314 0.67 13 114.9287 19.29 376 115.3150 0.16 3 115.9365 7.22 141 116.9355 18.78 366 117.3066 0.04 1 117.9426 3.36 66 118.9517 50.16 978 119.3136 0.16 3 119.9562 4.01 78 120.1897 0.03 1 120.9603 14.00 273 121.3432 0.08 2 121.9391 0.65 13 122.1592 0.03 1 122.3127 0.03 1 122.9683 2.06 40 123.2416 0.05 1 123.4542 0.07 1 123.7435 0.02 0 123.9612 0.15 3 124.9273 0.45 9 125.2391 0.04 1 125.4827 0.07 1 125.9063 0.81 16 126.9133 6.99 136 127.9215 22.46 438 128.9267 25.28 493 129.9319 10.43 203 130.9376 28.97 565 131.2627 0.20 4 131.9427 4.41 86 132.2964 0.18 4 132.9478 23.72 462 133.9312 1.44 28 134.9568 9.33 182 135.2181 0.11 2 135.9508 0.30 6 136.2162 0.03 1 136.9286 1.08 21 137.3240 0.04 1 137.4940 0.02 0 137.9106 0.37 7 138.4066 0.06 1 138.9152 2.69 52 139.9556 1.04 20 140.9245 17.81 347 141.9310 18.24 356 142.9366 30.73 599 143.9445 9.69 189 144.9515 31.60 616 145.9607 2.19 43 146.9746 8.03 157 147.9520 0.45 9 148.9697 2.61 51 149.9345 0.40 8 150.1935 0.17 3 150.9496 1.87 36 151.9300 6.75 132 152.9375 9.45 184 153.2630 0.18 4 153.9471 4.68 91 154.9595 19.16 374 155.9696 13.04 254 156.9780 28.04 547 157.9854 5.83 114 158.9936 17.75 346 159.9881 1.64 32 160.4512 0.13 3 161.0074 2.51 49 161.2296 0.07 1 161.9561 0.27 5 162.5577 0.08 2 162.9800 1.04 20 163.1419 0.17 3 163.9586 1.08 21 164.9703 15.20 296 165.9814 4.63 90 166.9846 12.56 245 167.9888 4.87 95 168.9925 17.43 340 169.9924 6.64 129 171.0064 14.57 284 172.0192 2.21 43 173.0123 11.36 221 173.9985 0.78 15 175.0248 6.65 130 175.9678 1.36 27 176.9725 1.69 33 177.9523 7.84 153 178.9595 12.41 242 179.9668 4.97 97 180.9689 12.91 252 181.3282 0.21 4 181.9768 5.44 106 182.9776 12.68 247 183.9931 3.04 59 184.9944 7.92 154 186.0022 1.22 24 187.0009 4.29 84 187.9560 0.45 9 188.4334 0.24 5 188.9494 4.00 78 189.2495 0.22 4 189.9492 1.50 29 190.9386 5.33 104 191.3706 0.14 3 191.9542 4.98 97 192.1700 0.20 4 192.9640 11.62 227 193.9717 5.67 111 194.9749 13.21 258 195.9767 3.28 64 196.9834 10.54 205 197.9830 1.55 30 199.0089 4.70 92 199.5240 0.20 4 199.9715 0.67 13 201.0113 2.72 53 201.9496 3.74 73 202.9536 4.22 82 203.9498 1.78 35 204.3103 0.11 2 204.9599 5.77 112 205.9673 4.46 87 206.3509 0.11 2 206.9733 9.47 185 207.4004 0.07 1 207.9855 3.62 71 208.9931 9.44 184 210.0024 1.78 35 210.3763 0.13 3 211.0063 4.08 80 211.3104 0.12 2 212.0172 0.71 14 212.2585 0.14 3 212.9987 1.47 29 214.0429 0.25 5 214.9713 3.47 68 215.9749 1.94 38 216.2315 0.09 2 216.9762 3.86 75 217.9975 2.50 49 218.9965 4.78 93 220.0115 2.52 49 221.0184 6.13 120 222.0421 1.98 39 222.2401 0.12 2 223.0420 4.25 83 223.3339 0.13 3 224.0117 0.81 16 225.0510 2.15 42 226.0038 0.94 18 227.0339 1.05 20 227.9962 1.41 27 228.3739 0.13 3 228.9999 2.98 58 230.0281 1.57 31 231.0124 3.31 65 232.0107 1.65 32 233.0140 4.42 86 234.0319 1.39 27 234.3263 0.07 1 235.0281 3.79 74 236.0416 0.97 19 236.4211 0.06 1 237.0567 2.51 49 237.3573 0.14 3 237.6644 0.07 1 238.0650 0.71 14 239.0319 1.96 38 239.9905 0.52 10 241.0378 1.39 27 241.2596 0.17 3 241.4736 0.11 2 241.6653 0.13 3 242.0115 0.90 18 242.2517 0.10 2 243.0098 2.37 46 243.3646 0.15 3 244.0051 1.19 23 245.0269 2.56 50 245.4075 0.14 3 246.0268 1.14 22 247.0309 3.21 63 247.4538 0.08 2 248.0400 0.91 18 248.3698 0.10 2 249.0585 2.27 44 249.3347 0.10 2 250.0407 0.78 15 251.0271 1.63 32 252.0161 1.04 20 253.0228 1.55 30 253.3444 0.07 1 254.0193 0.76 15 255.0397 1.57 31 255.2578 0.17 3 256.0139 0.61 12 257.0409 1.77 35 257.2722 0.09 2 258.0333 1.02 20 259.0478 1.97 38 259.3055 0.13 3 260.0079 0.75 15 260.4690 0.11 2 261.0703 2.28 44 262.0843 0.58 11 262.4811 0.12 2 263.0782 1.94 38 264.0809 0.35 7 265.0549 1.33 26 265.3533 0.11 2 266.0206 0.71 14 266.3362 0.10 2 267.0393 1.39 27 267.9290 0.46 9 268.4083 0.08 2 269.0557 1.28 25 270.0507 0.72 14 270.5307 0.05 1 271.0582 1.26 25 271.5634 0.07 1 272.0825 0.67 13 273.0727 1.38 27 273.3851 0.09 2 274.0916 0.46 9 274.6143 0.33 6 275.0718 1.94 38 275.5175 0.10 2 276.0529 0.38 7 277.0634 0.97 19 278.0951 0.55 11 278.3267 0.08 2 279.0684 0.85 17 280.0498 0.57 11 280.4433 0.04 1 281.0652 0.94 18 281.2613 0.16 3 281.5380 0.07 1 282.0815 0.48 9 282.2624 0.08 2 283.0695 1.11 22 283.3377 0.06 1 283.5267 0.06 1 284.0559 0.58 11 284.6030 0.07 1 285.0728 1.21 24 285.6437 0.09 2 286.0919 0.33 6 287.0722 0.95 19 287.3687 0.06 1 288.0910 0.33 6 288.3103 0.08 2 289.0725 0.98 19 289.4437 0.06 1 290.0951 0.30 6 291.0280 0.79 15 291.3975 0.02 0 291.5938 0.06 1 292.0954 0.35 7 292.3181 0.07 1 293.0486 0.50 10 294.0741 0.39 8 294.3036 0.09 2 294.6475 0.06 1 295.0813 0.58 11 295.4722 0.06 1 296.0709 0.51 10 296.5776 0.05 1 297.0487 0.68 13 297.3346 0.04 1 297.5781 0.03 1 298.0711 0.43 8 299.0481 0.62 12 300.0352 0.35 7 300.2788 0.05 1 301.0410 0.70 14 301.3728 0.02 0 302.0602 0.23 4 302.5710 0.04 1 303.0943 0.56 11 303.5740 0.03 1 304.0835 0.28 5 304.2830 0.05 1 305.0630 0.41 8 305.5097 0.05 1 306.1249 0.23 4 306.3841 0.06 1 306.5220 0.02 0 307.0689 0.50 10 307.4655 0.09 2 307.8036 0.07 1 308.0875 0.21 4 308.4383 0.07 1 309.0511 0.44 9 309.3191 0.05 1 310.0528 0.30 6 310.5192 0.03 1 311.0699 0.59 12 311.2842 0.06 1 312.0540 0.19 4 312.5544 0.06 1 313.0914 0.61 12 313.4924 0.07 1 314.0474 0.19 4 314.3276 0.04 1 314.5374 0.05 1 315.0865 0.78 15 315.4677 0.04 1 315.7028 0.03 1 316.0169 0.20 4 316.2713 0.12 2 316.4154 0.04 1 317.1036 0.49 10 317.5301 0.06 1 318.0769 0.32 6 318.3187 0.07 1 318.7440 0.07 1 319.0975 0.41 8 319.3640 0.07 1 320.1083 0.21 4 320.5803 0.03 1 321.0908 0.26 5 321.4657 0.06 1 322.0461 0.19 4 322.5495 0.04 1 323.0761 0.37 7 323.7212 0.04 1 324.1775 0.16 3 324.5852 0.03 1 325.0961 0.45 9 325.3722 0.03 1 325.5957 0.06 1 326.0687 0.08 2 326.5398 0.02 0 327.1001 0.48 9 328.0609 0.22 4 328.4182 0.04 1 328.5570 0.01 0 328.7217 0.01 0 329.1389 0.36 7 330.0563 0.32 6 331.1141 0.55 11 332.1030 0.21 4 332.5782 0.03 1 333.1200 0.37 7 333.3187 0.06 1 333.5706 0.07 1 334.0580 0.18 4 334.4808 0.03 1 335.1085 0.37 7 336.1066 0.26 5 336.3580 0.08 2 336.6028 0.06 1 336.7211 0.02 0 337.1142 0.47 9 337.4475 0.03 1 338.1253 0.21 4 339.0993 0.20 4 339.6583 0.08 2 340.1174 0.22 4 340.3929 0.02 0 341.1230 0.41 8 341.7999 0.03 1 342.1634 0.21 4 342.6280 0.08 2 343.1500 0.42 8 343.5415 0.06 1 344.1314 0.53 10 344.6361 0.06 1 345.1150 0.41 8 345.5619 0.05 1 346.1020 0.21 4 347.1192 0.35 7 347.3817 0.05 1 348.0959 0.09 2 348.5716 0.02 0 349.1559 0.40 8 349.4818 0.06 1 349.7724 0.07 1 350.1929 0.32 6 350.4508 0.06 1 351.1374 0.31 6 351.4780 0.05 1 351.6046 0.01 0 352.1592 0.13 3 352.6313 0.05 1 353.0733 0.18 4 353.3200 0.05 1 354.1415 0.10 2 354.5426 0.09 2 355.1421 0.25 5 355.3873 0.03 1 355.7803 0.11 2 356.1614 0.12 2 356.5846 0.05 1 357.1290 0.52 10 357.5788 0.08 2 358.1606 0.17 3 358.5145 0.01 0 359.0204 0.13 3 359.2543 0.18 4 359.6923 0.03 1 360.2316 0.16 3 361.1396 0.28 5 361.5697 0.06 1 362.1525 0.63 12 362.4879 0.04 1 363.1648 0.86 17 363.6357 0.02 0 364.1105 0.17 3 364.2986 0.09 2 364.7495 0.03 1 365.1905 0.25 5 365.4186 0.05 1 366.2899 0.12 2 367.0679 0.17 3 367.4062 0.04 1 368.1596 0.18 4 368.4095 0.05 1 368.7487 0.06 1 369.1939 0.24 5 370.0370 0.18 4 370.4103 0.05 1 371.1642 0.15 3 371.4595 0.01 0 371.7795 0.02 0 372.2349 0.12 2 373.1510 0.21 4 373.5511 0.02 0 374.1426 0.10 2 374.7768 0.05 1 375.1743 0.43 8 375.4184 0.08 2 375.7693 0.03 1 376.1715 0.31 6 376.8472 0.05 1 377.1574 0.17 3 377.4276 0.05 1 377.8380 0.04 1 378.0314 0.05 1 378.2910 0.07 1 378.5112 0.05 1 379.1611 0.13 3 380.2822 0.09 2 381.1591 0.21 4 381.6931 0.04 1 382.0362 0.12 2 382.4882 0.04 1 383.1764 0.21 4 384.1231 0.30 6 384.4182 0.04 1 384.8015 0.03 1 385.1394 0.33 6 385.6189 0.08 2 385.9721 0.02 0 386.2379 0.11 2 386.4770 0.04 1 387.1883 0.16 3 387.7414 0.04 1 388.1862 0.17 3 388.7146 0.04 1 389.2070 0.14 3 389.4107 0.05 1 389.7040 0.03 1 390.0635 0.08 2 390.4524 0.03 1 390.7009 0.08 2 391.0464 0.10 2 391.3758 0.07 1 392.1917 0.51 10 392.4103 0.10 2 392.6736 0.04 1 393.0439 0.11 2 393.6708 0.02 0 394.1347 0.09 2 394.3867 0.08 2 394.5652 0.04 1 394.8533 0.06 1 395.2196 0.17 3 395.6581 0.03 1 396.2391 0.18 4 396.6630 0.04 1 397.1892 0.74 14 397.4814 0.04 1 397.6620 0.04 1 397.8271 0.07 1 398.1849 0.23 4 398.5768 0.02 0 399.1606 0.15 3 399.4088 0.02 0 399.7366 0.02 0 400.2346 0.05 1 400.4510 0.06 1 401.1794 0.43 8 402.2183 0.40 8 402.4527 0.07 1 402.6984 0.04 1 403.2013 0.36 7 403.6868 0.08 2 404.1890 0.12 2 405.1996 0.22 4 405.7018 0.10 2 405.8882 0.03 1 406.1735 0.05 1 406.4166 0.04 1 406.6678 0.03 1 407.1308 0.07 1 407.4702 0.02 0 407.6926 0.02 0 407.9278 0.03 1 408.3260 0.07 1 409.1626 0.08 2 409.6825 0.04 1 410.1890 0.37 7 410.5800 0.04 1 411.2022 0.25 5 411.5771 0.03 1 412.1419 0.08 2 412.5229 0.06 1 412.8558 0.08 2 413.2141 0.14 3 413.5497 0.05 1 413.7636 0.04 1 414.1754 0.23 4 414.4836 0.01 0 415.2130 0.48 9 415.5072 0.05 1 415.6837 0.04 1 416.1741 0.25 5 416.6649 0.04 1 417.2820 0.11 2 417.6279 0.10 2 418.1529 0.17 3 418.3626 0.04 1 418.7927 0.06 1 419.1915 0.05 1 419.5756 0.06 1 419.8481 0.03 1 420.0178 0.02 0 420.2997 0.10 2 420.4486 0.02 0 420.7232 0.04 1 420.8728 0.04 1 421.1995 0.05 1 421.4981 0.07 1 421.7266 0.07 1 422.2899 0.12 2 422.7515 0.06 1 423.1270 0.10 2 423.5888 0.08 2 423.9763 0.10 2 424.1962 0.10 2 424.4020 0.03 1 424.6740 0.06 1 425.1712 0.05 1 425.6190 0.05 1 426.1931 0.11 2 426.4070 0.06 1 426.7011 0.05 1 427.1503 0.32 6 427.3816 0.13 3 427.5620 0.08 2 428.2105 0.55 11 428.7252 0.07 1 429.2039 0.55 11 429.4579 0.16 3 429.7455 0.05 1 430.0457 0.05 1 430.3037 0.13 3 430.4876 0.04 1 431.1636 0.22 4 431.7514 0.04 1 432.2703 0.08 2 432.7705 0.06 1 433.0166 0.04 1 433.2447 0.07 1 433.3831 0.01 0 433.7316 0.02 0 434.0660 0.05 1 434.4666 0.07 1 434.9021 0.11 2 435.2238 0.05 1 435.4245 0.13 3 435.8787 0.09 2 436.4299 0.12 2 437.0702 0.14 3 437.4957 0.14 3 437.9767 0.13 3 438.3447 0.17 3 438.6833 0.14 3 439.1985 0.19 4 439.8824 0.14 3 440.4679 0.09 2 441.0997 0.15 3 441.3459 0.09 2 441.5641 0.03 1 441.8258 0.05 1 442.2227 0.23 4 442.6872 0.07 1 443.2434 0.27 5 444.2274 0.80 16 444.4798 0.12 2 444.8667 0.06 1 445.2684 0.14 3 445.4933 0.10 2 445.7397 0.04 1 446.0805 0.04 1 446.3215 0.03 1 446.4621 0.03 1 446.6007 0.02 0 447.2047 0.07 1 447.4759 0.04 1 447.7417 0.05 1 447.8924 0.05 1 448.3062 0.07 1 448.7662 0.05 1 449.1071 0.07 1 449.4185 0.12 2 450.2434 0.26 5 450.5356 0.05 1 450.8732 0.02 0 451.1373 0.04 1 451.4877 0.09 2 451.7210 0.08 2 452.4659 0.07 1 452.6859 0.06 1 452.9802 0.09 2 453.3359 0.10 2 453.5105 0.01 0 454.0287 0.07 1 454.4026 0.14 3 455.2333 0.12 2 455.6245 0.04 1 456.2011 0.23 4 458.2501 20.92 408 459.0937 0.27 5 459.5071 0.12 2 460.3709 0.16 3 460.6867 0.03 1 461.1545 0.08 2 461.4281 0.06 1 461.9207 0.09 2 462.2566 0.07 1 462.5644 0.03 1 462.8662 0.03 1 463.0898 0.10 2 463.3541 0.12 2 463.6854 0.05 1 463.9337 0.07 1 464.1800 0.14 3 464.4363 0.10 2 464.8821 0.03 1 465.2120 0.15 3 465.5025 0.06 1 465.7194 0.05 1 465.9905 0.04 1 466.1612 0.05 1 466.5060 0.10 2 467.0957 0.04 1 467.3086 0.01 0 467.6359 0.03 1 468.2545 0.29 6 468.7185 0.02 0 469.2923 0.16 3 469.6344 0.03 1 470.2785 0.36 7 470.5946 0.04 1 471.2856 0.49 10 471.5360 0.09 2 472.0805 0.03 1 472.5312 0.03 1 473.1225 0.13 3 473.3094 0.05 1 473.4708 0.02 0 473.8144 0.04 1 474.7715 0.04 1 475.1653 0.07 1 475.3435 0.03 1 475.5042 0.07 1 476.0703 0.03 1 476.3107 0.13 3 476.4032 0.02 0 476.6309 0.03 1 477.2859 0.03 1 477.5005 0.07 1 477.6577 0.06 1 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