MassBank Record: CA000111



 7',8',9',10'-Tetrahydro-beta-cryptoxanthin; FAB-EBEB; MS2; m/z: 556.46; [M]+* 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: CA000111
RECORD_TITLE: 7',8',9',10'-Tetrahydro-beta-cryptoxanthin; FAB-EBEB; MS2; m/z: 556.46; [M]+*
DATE: 2016.01.19 (Created 2010.07.29, modified 2011.05.10)
AUTHORS: Akimoto N, Graduate School of Pharmaceutical Sciences, Kyoto University and Maoka T, Research Institute for Production Development
LICENSE: CC BY-SA
COMMENT: Profile spectrum of this record is given as a JPEG file.
COMMENT: [Profile] CA000111.jpg

CH$NAME: 7',8',9',10'-Tetrahydro-beta-cryptoxanthin CH$COMPOUND_CLASS: Natural Product CH$FORMULA: C40H60O CH$EXACT_MASS: 556.46442 CH$SMILES: C(=CC=C(C)C=CC(=C(C)2)C(C)(C)CC(C2)O)C(C)=CC=CC=C(C)C=CCC(C)CCC(=C1C)C(CCC1)(C)C CH$IUPAC: InChI=1S/C40H60O/c1-30(18-13-20-32(3)23-25-37-34(5)22-15-27-39(37,7)8)16-11-12-17-31(2)19-14-21-33(4)24-26-38-35(6)28-36(41)29-40(38,9)10/h11-14,16-19,21,24,26,32,36,41H,15,20,22-23,25,27-29H2,1-10H3/b12-11+,18-13+,19-14+,26-24+,30-16+,31-17+,33-21+/t32?,36-/m1/s1 SP$SCIENTIFIC_NAME: Silurus asotus SP$NAME: catfish SP$LINEAGE: cellular organisms; Eukaryota; Fungi/Metazoa group; Metazoa; Eumetazoa; Bilateria; Coelomata; Deuterostomia; Chordata; Craniata; Vertebrata; Gnathostomata; Teleostomi; Euteleostomi; Actinopterygii; Actinopteri; Neopterygii; Teleostei; Elopocephala; Clupeocephala; Otocephala; Ostariophysi; Otophysi; Siluriphysi; Siluriformes; Siluridae; Silurus SP$LINK: NCBI-TAXONOMY 30991
AC$INSTRUMENT: JMS-HX/HX 110A, JEOL AC$INSTRUMENT_TYPE: FAB-EBEB AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: ATOM_GUN_CURRENT 5 mA AC$MASS_SPECTROMETRY: BOMBARDMENT 6 kV xenon AC$MASS_SPECTROMETRY: COLLISION_ENERGY 3 kV AC$MASS_SPECTROMETRY: COLLISION_GAS Ar AC$MASS_SPECTROMETRY: GAS_PRESSURE adjust to attenuate the intensity of the precursor ion by 30 % AC$MASS_SPECTROMETRY: IONIZATION FAB AC$MASS_SPECTROMETRY: MATRIX 1-2 uL m-NBA AC$MASS_SPECTROMETRY: PROBE_TIP stainless-steel
MS$FOCUSED_ION: BASE_PEAK 556.5405 MS$FOCUSED_ION: PRECURSOR_M/Z 556.46 MS$FOCUSED_ION: PRECURSOR_TYPE [M]+*
PK$SPLASH: splash10-0a4i-5910020000-5bb2046f58d229ee2b2b PK$ANNOTATION: m/z InChI M-18 InChI=1/C40H58/c1-31(19-13-21-33(3)25-27-37-35(5)23-15-29-39(37,7)8)17-11-12-18-32(2)20-14-22-34(4)26-28-38-36(6)24-16-30-40(38,9)10/h11-15,17-21,25,27,29,34H,16,22-24,26,28,30H2,1-10H3/q+1/b12-11+,19-13+,20-14+,27-25+,31-17+,32-18+,33-21+ M-137 InChI=1/C30H43O/c1-23(2)13-11-16-24(3)14-9-10-15-25(4)17-12-18-26(5)19-20-29-27(6)21-28(31)22-30(29,7)8/h9-12,14-20,23,28,31H,1,13,21-22H2,2-8H3/q+1/b10-9+,16-11+,17-12+,20-19+,24-14+,25-15+,26-18+/t23?,28-/m1/s1 M-151 InChI=1/C29H41O/c1-8-9-10-14-23(2)15-11-12-16-24(3)17-13-18-25(4)19-20-28-26(5)21-27(30)22-29(28,6)7/h8,10-20,27,30H,9,21-22H2,1-7H3/q+1/b12-11+,14-10+,17-13+,20-19+,23-15+,24-16+,25-18+/t27-/m1/s1 M-179 InChI=1/C27H37O/c1-8-12-21(2)13-9-10-14-22(3)15-11-16-23(4)17-18-26-24(5)19-25(28)20-27(26,6)7/h8-18,25,28H,1,19-20H2,2-7H3/q+1/b10-9+,12-8+,15-11+,18-17+,21-13+,22-14+,23-16+/t25-/m1/s1 M-193 InChI=1/C26H35O/c1-8-20(2)12-9-10-13-21(3)14-11-15-22(4)16-17-25-23(5)18-24(27)19-26(25,6)7/h1,8-17,24,27H,18-19H2,2-7H3/q+1/b10-9+,14-11+,17-16+,20-12+,21-13+,22-15+/t24-/m1/s1 PK$NUM_PEAK: 1706 PK$PEAK: m/z int. rel.int. 4.4282 0.01 0 6.8169 0.11 1 12.9478 0.01 0 13.9539 0.03 0 14.9697 0.29 3 22.9238 0.05 0 24.9312 0.07 1 25.9475 0.54 5 26.9577 3.65 36 27.0873 0.01 0 27.9543 0.29 3 28.9661 2.79 28 29.4372 0.01 0 30.9520 0.18 2 35.9527 0.02 0 36.2667 0.01 0 36.9333 0.36 4 37.1680 0.02 0 37.2204 0.01 0 37.3184 0.01 0 37.9450 1.06 11 38.3930 0.02 0 38.6146 0.02 0 38.9457 7.55 75 39.1258 0.02 0 39.2843 0.01 0 39.3980 0.04 0 39.6033 0.04 0 39.9595 0.94 9 40.0962 0.02 0 40.7853 0.06 1 40.9649 17.38 174 41.9644 0.32 3 42.5912 0.01 0 42.9704 10.99 110 43.3221 0.01 0 43.9546 0.20 2 44.9664 0.40 4 45.9608 0.01 0 47.8855 0.03 0 48.1813 0.03 0 48.9379 0.13 1 49.1368 0.02 0 49.3071 0.04 0 49.4791 0.01 0 49.6447 0.03 0 49.9407 2.15 21 50.1747 0.02 0 50.3380 0.01 0 50.5295 0.02 0 50.9353 3.99 40 51.1581 0.01 0 51.3319 0.01 0 51.9441 1.74 17 52.9555 7.85 78 53.1691 0.06 1 53.9531 0.41 4 54.6026 0.03 0 54.9707 28.98 290 55.4108 0.01 0 55.9724 0.47 5 56.9786 9.02 90 57.9954 0.10 1 58.9659 1.14 11 59.3522 0.02 0 59.9627 0.07 1 60.2861 0.01 0 60.9239 0.21 2 61.1199 0.01 0 61.4627 0.02 0 61.6005 0.03 0 61.9219 0.73 7 62.0774 0.02 0 62.1451 0.01 0 62.5170 0.01 0 62.6014 0.04 0 62.7043 0.02 0 62.9347 3.04 30 63.1323 0.05 0 63.2556 0.03 0 63.3610 0.01 0 63.5616 0.04 0 63.9517 0.73 7 64.2195 0.04 0 64.4428 0.03 0 64.4973 0.01 0 64.6390 0.03 0 64.9563 6.13 61 65.1920 0.01 0 65.3206 0.04 0 65.5266 0.01 0 65.6366 0.02 0 65.9525 1.10 11 66.1025 0.02 0 66.2876 0.04 0 66.5040 0.01 0 66.9627 15.08 151 67.3099 0.02 0 67.5174 0.03 0 67.6851 0.01 0 67.9665 0.79 8 68.1356 0.02 0 68.6394 0.01 0 68.9762 28.45 284 69.3428 0.02 0 69.4489 0.01 0 69.9841 0.27 3 70.9648 2.00 20 71.2742 0.01 0 71.8698 0.02 0 71.9571 0.03 0 72.9273 0.06 1 73.2172 0.01 0 73.9255 0.76 8 74.9296 0.94 9 75.1292 0.06 1 75.2053 0.02 0 75.3851 0.07 1 75.6506 0.06 1 75.9530 0.82 8 76.2908 0.06 1 76.3966 0.07 1 76.9473 17.67 177 77.2687 0.25 2 77.4340 0.20 2 77.5832 0.16 2 77.9540 3.35 33 78.2826 0.13 1 78.9609 20.65 206 79.4528 0.04 0 79.6399 0.08 1 79.9690 2.94 29 80.2499 0.05 0 80.5124 0.12 1 80.9771 37.78 378 81.3198 0.08 1 81.4255 0.02 0 81.9666 0.64 6 82.2156 0.02 0 82.3091 0.02 0 82.5838 0.01 0 82.9904 7.09 71 83.3753 0.01 0 83.6082 0.05 0 83.9539 0.06 1 84.1075 0.02 0 84.2390 0.01 0 84.9734 5.33 53 85.6463 0.02 0 85.9264 0.29 3 86.4715 0.01 0 86.9360 0.56 6 87.6765 0.01 0 87.9430 0.20 2 88.0976 0.02 0 88.2303 0.01 0 88.9593 1.49 15 89.2589 0.23 2 89.4854 0.09 1 89.9619 0.64 6 90.0387 0.29 3 90.1744 0.13 1 90.9691 33.76 337 91.2567 0.07 1 91.5608 0.09 1 91.9781 4.11 41 92.2913 0.10 1 92.4172 0.03 0 92.9951 30.43 304 93.4293 0.08 1 93.5804 0.01 0 93.9985 1.88 19 94.2918 0.06 1 94.5620 0.10 1 95.0084 39.87 398 95.2708 0.11 1 95.4937 0.07 1 95.6805 0.02 0 96.0070 0.54 5 96.3360 0.03 0 96.5108 0.03 0 97.0076 2.06 21 97.4744 0.04 0 97.9757 0.16 2 98.3524 0.02 0 98.7482 0.01 0 98.9938 0.30 3 99.1643 0.03 0 99.6125 0.01 0 99.9921 0.09 1 100.3385 0.02 0 100.4334 0.01 0 100.5619 0.06 1 100.6403 0.03 0 100.9765 0.50 5 101.2479 0.10 1 101.4764 0.10 1 101.9709 1.51 15 102.1530 0.08 1 102.4168 0.07 1 102.5286 0.05 0 102.9790 5.30 53 103.2225 0.08 1 103.4240 0.08 1 103.6545 0.08 1 103.9920 1.92 19 104.1860 0.08 1 104.4407 0.12 1 105.0014 39.60 396 105.2874 0.17 2 105.4800 0.08 1 106.0109 4.31 43 106.2611 0.07 1 106.3925 0.03 0 107.0187 23.53 235 107.3734 0.11 1 107.5616 0.11 1 108.0138 2.21 22 108.2725 0.04 0 108.4347 0.04 0 108.5600 0.09 1 109.0278 13.70 137 109.3109 0.04 0 109.4315 0.04 0 109.6233 0.01 0 110.0107 0.43 4 110.2882 0.02 0 110.4025 0.02 0 111.0035 1.12 11 111.2880 0.03 0 111.5775 0.02 0 111.8060 0.01 0 111.9253 0.06 1 112.0309 0.14 1 112.6184 0.07 1 112.9632 0.28 3 113.1470 0.09 1 113.4127 0.13 1 113.9648 0.35 3 114.1387 0.15 1 114.3759 0.15 1 114.9722 12.30 123 115.1970 0.17 2 115.9732 4.50 45 116.2587 0.21 2 116.9866 14.43 144 117.2242 0.15 1 117.4503 0.08 1 117.9906 3.31 33 118.2485 0.05 0 118.4265 0.02 0 118.9967 34.32 343 119.3368 0.18 2 119.4744 0.06 1 119.6746 0.12 1 119.9968 3.88 39 120.1954 0.13 1 120.3982 0.06 1 121.0075 14.33 143 121.2811 0.09 1 121.4112 0.06 1 121.5189 0.04 0 122.0019 1.79 18 122.4494 0.06 1 123.0202 10.59 106 123.4086 0.08 1 123.5506 0.06 1 123.7001 0.04 0 123.8227 0.03 0 124.0131 0.28 3 124.1986 0.02 0 124.6645 0.04 0 125.0151 0.57 6 125.2400 0.01 0 125.4289 0.06 1 125.5188 0.08 1 125.9725 0.50 5 126.2100 0.03 0 126.3152 0.02 0 126.9667 4.23 42 127.9608 13.38 134 128.2645 0.26 3 128.9642 16.05 160 129.2897 0.08 1 129.4027 0.08 1 129.5569 0.05 0 129.9816 6.37 64 130.3266 0.11 1 130.4637 0.08 1 130.9794 19.30 193 131.2952 0.12 1 131.4775 0.09 1 131.9913 3.93 39 132.3457 0.10 1 132.4782 0.12 1 132.5714 0.05 0 132.9969 16.95 169 133.3937 0.08 1 133.9902 2.16 22 134.2725 0.02 0 134.4067 0.09 1 134.5322 0.05 0 135.0024 8.09 81 135.2983 0.12 1 135.4673 0.10 1 135.6307 0.09 1 136.0172 0.67 7 136.1994 0.11 1 136.3438 0.06 1 136.6376 0.15 1 137.0258 15.79 158 137.3564 0.17 2 137.5686 0.10 1 137.9969 0.43 4 138.2310 0.08 1 138.4440 0.06 1 138.5751 0.03 0 138.9547 1.56 16 139.3439 0.04 0 139.5062 0.08 1 139.6100 0.06 1 139.9751 0.63 6 140.2010 0.17 2 140.3385 0.17 2 140.9698 10.97 110 141.3168 0.08 1 141.5355 0.10 1 141.9836 10.94 109 142.3896 0.17 2 142.9847 20.30 203 143.4610 0.18 2 143.9962 5.99 60 144.2567 0.14 1 144.5748 0.17 2 145.0080 24.37 244 145.4984 0.16 2 145.5847 0.08 1 146.0077 2.17 22 146.2631 0.05 0 146.5148 0.09 1 147.0159 8.23 82 147.2477 0.12 1 147.4106 0.06 1 147.6275 0.08 1 148.0300 0.84 8 148.2884 0.07 1 148.6108 0.08 1 149.0300 3.83 38 149.4149 0.10 1 149.5681 0.08 1 149.6566 0.05 0 150.0046 0.53 5 150.2565 0.11 1 150.5305 0.09 1 151.0077 1.56 16 151.9777 3.57 36 152.2823 0.15 1 152.4951 0.25 2 152.9920 4.99 50 153.4633 0.14 1 154.0066 2.82 28 154.4549 0.10 1 155.0163 11.26 113 155.2902 0.13 1 155.4436 0.15 1 155.5578 0.07 1 156.0238 7.28 73 156.3093 0.16 2 157.0334 20.25 202 157.5208 0.14 1 158.0496 3.60 36 158.3203 0.10 1 158.5557 0.17 2 159.0520 12.71 127 159.3667 0.19 2 159.5098 0.14 1 160.0495 1.17 12 160.5730 0.11 1 161.0663 3.79 38 161.4125 0.09 1 161.5629 0.03 0 162.0457 0.49 5 162.4278 0.05 0 162.5782 0.06 1 163.0742 1.75 17 163.3276 0.05 0 163.5360 0.08 1 163.6618 0.13 1 163.9973 0.51 5 164.1505 0.19 2 164.3056 0.09 1 164.5943 0.29 3 165.0286 7.33 73 165.3938 0.10 1 165.4962 0.08 1 166.0301 2.60 26 166.2555 0.14 1 167.0303 6.74 67 167.4689 0.16 2 168.0513 3.05 30 169.0558 11.22 112 169.4582 0.18 2 169.5873 0.10 1 169.7151 0.12 1 170.0637 5.02 50 170.3086 0.21 2 170.4810 0.11 1 171.0684 11.50 115 171.5701 0.14 1 171.6783 0.09 1 172.0713 1.92 19 172.2911 0.13 1 172.3739 0.05 0 172.6434 0.22 2 173.0825 6.23 62 173.5014 0.09 1 174.0587 0.61 6 174.3566 0.12 1 174.6310 0.21 2 175.0873 4.21 42 175.4275 0.09 1 176.0374 0.61 6 176.3612 0.06 1 177.0590 1.69 17 177.3127 0.15 1 177.5122 0.09 1 178.0275 4.03 40 178.3313 0.08 1 179.0216 5.77 58 179.6079 0.09 1 180.0286 2.50 25 180.2950 0.07 1 181.0323 7.18 72 181.4264 0.11 1 181.6417 0.08 1 182.0379 3.18 32 182.4444 0.07 1 183.0397 8.91 89 184.0645 2.03 20 184.3251 0.10 1 185.0624 5.03 50 185.3720 0.13 1 185.6084 0.05 0 186.0647 0.92 9 186.3179 0.10 1 186.4715 0.11 1 186.6458 0.11 1 187.0643 2.65 26 187.3878 0.03 0 187.6786 0.10 1 187.7892 0.06 1 188.0910 0.36 4 188.4539 0.14 1 188.6786 0.13 1 189.0339 2.15 21 189.5619 0.12 1 190.0508 0.92 9 190.3580 0.11 1 191.0134 2.61 26 191.3325 0.12 1 191.4466 0.07 1 192.0191 2.20 22 193.0312 5.14 51 193.4436 0.07 1 194.0374 2.56 26 194.5863 0.14 1 195.0500 6.88 69 195.3730 0.04 0 195.6160 0.10 1 196.0502 1.95 19 196.4516 0.08 1 197.0555 7.37 74 197.6356 0.09 1 198.0690 1.14 11 198.3744 0.05 0 199.0604 3.04 30 199.4255 0.06 1 199.6372 0.08 1 200.0452 0.49 5 200.3801 0.05 0 201.0551 1.85 18 201.5146 0.17 2 202.0234 1.42 14 202.4876 0.04 0 203.0421 1.95 19 203.3262 0.11 1 203.4430 0.04 0 203.5773 0.09 1 203.6798 0.06 1 204.0159 0.89 9 204.2774 0.05 0 204.4046 0.03 0 204.5558 0.09 1 205.0284 2.32 23 205.4933 0.10 1 206.0415 1.67 17 206.3728 0.10 1 206.4780 0.04 0 206.6333 0.06 1 207.0478 4.40 44 207.3176 0.07 1 207.5158 0.06 1 208.0521 1.66 17 208.3200 0.06 1 208.5977 0.11 1 209.0633 5.64 56 209.2943 0.21 2 209.5773 0.09 1 210.0672 1.46 15 210.4707 0.12 1 211.0833 3.61 36 211.3470 0.10 1 211.5287 0.04 0 212.0842 0.90 9 212.1885 0.38 4 212.5852 0.09 1 213.0850 1.74 17 213.3691 0.01 0 214.0894 0.36 4 214.4662 0.11 1 214.5823 0.06 1 215.0479 1.66 17 215.3623 0.11 1 215.5502 0.06 1 216.0395 0.81 8 216.3364 0.05 0 217.0609 2.02 20 217.3775 0.02 0 217.5910 0.10 1 218.0560 0.60 6 218.4851 0.08 1 219.0939 2.46 25 219.5003 0.04 0 219.6552 0.06 1 220.0892 1.00 10 220.5056 0.13 1 221.0887 2.71 27 221.5230 0.10 1 221.7754 0.15 1 222.1136 1.13 11 222.5245 0.07 1 222.7149 0.14 1 223.1219 2.91 29 223.4733 0.09 1 223.7168 0.03 0 224.1194 0.71 7 224.3944 0.06 1 224.5011 0.03 0 224.6314 0.03 0 225.1246 1.71 17 225.6375 0.10 1 226.1065 0.53 5 226.5102 0.04 0 227.1188 0.81 8 227.5676 0.07 1 228.0682 0.38 4 228.4459 0.07 1 228.5375 0.02 0 229.0972 1.17 12 229.3755 0.06 1 229.4921 0.03 0 230.0887 0.54 5 230.5944 0.06 1 231.0877 1.20 12 231.4573 0.08 1 231.6591 0.02 0 231.8256 0.12 1 232.1048 0.69 7 232.4823 0.04 0 232.7164 0.09 1 233.1091 1.55 15 233.6469 0.11 1 233.8003 0.06 1 234.1257 0.78 8 234.5947 0.06 1 234.7056 0.02 0 235.1176 1.97 20 235.5173 0.07 1 235.6472 0.03 0 236.1152 0.52 5 236.4644 0.06 1 236.5603 0.05 0 237.1263 1.44 14 237.5610 0.05 0 237.6845 0.01 0 238.1173 0.35 3 238.4103 0.08 1 239.1186 0.95 9 239.5477 0.08 1 239.7646 0.06 1 240.1498 0.31 3 240.2701 0.18 2 240.4397 0.02 0 240.5811 0.04 0 241.1215 0.88 9 241.5753 0.08 1 241.6864 0.06 1 242.1041 0.43 4 242.2949 0.10 1 242.5475 0.09 1 242.6304 0.03 0 242.7547 0.01 0 243.1238 0.88 9 243.3884 0.05 0 243.7293 0.03 0 244.1209 0.42 4 244.3868 0.04 0 244.4902 0.02 0 244.6093 0.01 0 245.1117 0.83 8 245.4100 0.08 1 245.6102 0.02 0 246.1232 0.66 7 246.4908 0.04 0 246.6687 0.05 0 247.1246 1.16 12 247.3637 0.06 1 247.6273 0.06 1 248.1473 0.45 4 248.6272 0.01 0 249.1467 1.36 14 249.4856 0.02 0 249.6900 0.05 0 250.1516 0.31 3 250.5605 0.05 0 251.1846 1.16 12 251.6748 0.01 0 252.1479 0.24 2 252.3598 0.06 1 252.6097 0.04 0 252.7494 0.02 0 253.1528 0.60 6 253.4284 0.06 1 253.6875 0.07 1 254.1424 0.28 3 254.4286 0.01 0 254.6997 0.04 0 255.1502 0.88 9 255.5196 0.06 1 255.7195 0.09 1 256.1167 0.22 2 256.2691 0.08 1 257.1560 0.89 9 257.4200 0.04 0 257.5190 0.03 0 257.6992 0.04 0 258.1343 0.28 3 258.2743 0.18 2 258.3674 0.08 1 258.4691 0.06 1 258.5793 0.03 0 258.6935 0.02 0 258.8078 0.06 1 259.1796 0.88 9 259.7601 0.09 1 259.9272 0.09 1 260.1763 0.31 3 260.4511 0.07 1 261.1514 0.75 7 261.3847 0.03 0 261.6266 0.05 0 261.7911 0.03 0 262.1956 0.28 3 262.3721 0.12 1 262.5347 0.04 0 262.7092 0.04 0 263.1714 0.86 9 263.4590 0.05 0 263.7678 0.06 1 264.1897 0.45 4 264.4966 0.04 0 264.6441 0.03 0 265.1686 0.59 6 265.5914 0.04 0 265.8130 0.04 0 266.1630 0.21 2 266.3615 0.04 0 267.1690 0.60 6 267.5324 0.03 0 267.6495 0.05 0 268.1547 0.31 3 268.3924 0.02 0 268.5599 0.02 0 268.7287 0.05 0 269.1797 0.93 9 269.6161 0.03 0 269.7559 0.06 1 270.1990 0.42 4 270.5114 0.05 0 270.6570 0.03 0 271.1886 0.66 7 271.4176 0.14 1 271.7454 0.06 1 272.2095 0.45 4 272.6585 0.01 0 273.1559 0.71 7 273.6315 0.02 0 273.7984 0.03 0 274.1780 0.18 2 274.5735 0.11 1 274.7379 0.06 1 275.1739 0.59 6 275.5052 0.02 0 275.6278 0.04 0 275.7127 0.02 0 276.1939 0.16 2 276.5247 0.01 0 276.6844 0.04 0 277.1969 0.76 8 277.4926 0.03 0 277.6577 0.05 0 277.9170 0.07 1 278.1173 0.10 1 278.2798 0.12 1 278.4396 0.04 0 278.5550 0.04 0 278.6949 0.04 0 279.0677 0.23 2 279.2880 0.19 2 279.5706 0.04 0 279.7629 0.06 1 280.1869 0.18 2 280.5160 0.06 1 280.6660 0.03 0 281.1611 0.34 3 281.3973 0.09 1 281.5865 0.06 1 281.7372 0.03 0 282.1965 0.37 4 282.4647 0.04 0 282.7017 0.06 1 282.8909 0.08 1 283.2163 0.92 9 283.5443 0.02 0 283.7137 0.08 1 283.8969 0.04 0 284.2463 0.65 6 284.5558 0.03 0 284.8095 0.08 1 285.2048 0.48 5 285.3423 0.20 2 285.6519 0.03 0 285.9794 0.04 0 286.1973 0.22 2 286.4832 0.03 0 286.7677 0.03 0 287.1558 0.33 3 287.6799 0.05 0 287.8962 0.04 0 288.1576 0.20 2 288.3341 0.09 1 288.4635 0.04 0 288.6779 0.06 1 289.2141 0.37 4 289.5420 0.09 1 290.1195 0.16 2 290.2609 0.15 1 290.4474 0.03 0 290.7535 0.05 0 291.1910 0.28 3 291.3730 0.07 1 291.7249 0.02 0 291.9574 0.07 1 292.1991 0.11 1 292.5126 0.03 0 292.6986 0.04 0 292.9277 0.02 0 293.2300 0.35 3 293.6764 0.06 1 293.8080 0.04 0 294.0006 0.06 1 294.3109 0.10 1 294.6863 0.02 0 294.8385 0.02 0 295.2200 0.36 4 295.6121 0.07 1 295.7683 0.07 1 295.8534 0.03 0 296.2230 0.21 2 296.3858 0.11 1 296.6105 0.04 0 296.7282 0.06 1 297.1989 0.34 3 297.5161 0.02 0 298.1491 0.16 2 298.2914 0.13 1 298.4124 0.07 1 298.6439 0.05 0 298.8680 0.07 1 299.2318 0.23 2 299.6083 0.03 0 299.7294 0.02 0 299.8305 0.05 0 300.0062 0.03 0 300.2250 0.13 1 300.3521 0.07 1 300.7194 0.02 0 300.9143 0.06 1 301.1652 0.32 3 301.3276 0.06 1 301.5652 0.04 0 301.9239 0.07 1 302.1801 0.13 1 302.3498 0.05 0 302.4736 0.02 0 302.6999 0.04 0 302.9302 0.07 1 303.2371 0.33 3 303.5427 0.01 0 303.8476 0.02 0 304.1925 0.12 1 304.6080 0.05 0 305.1581 0.25 2 305.3878 0.08 1 305.6809 0.02 0 305.9227 0.04 0 306.2677 0.12 1 306.6095 0.03 0 306.9106 0.03 0 307.2097 0.26 3 307.4116 0.08 1 307.7314 0.02 0 307.9973 0.09 1 308.2212 0.14 1 308.3311 0.05 0 308.4584 0.06 1 308.9702 0.03 0 309.2435 0.29 3 309.4548 0.04 0 309.6468 0.06 1 309.8901 0.02 0 310.2061 0.09 1 310.4287 0.06 1 310.6847 0.02 0 310.9261 0.02 0 311.2741 0.20 2 311.4668 0.02 0 311.7276 0.07 1 311.9683 0.01 0 312.1524 0.03 0 312.3171 0.05 0 312.8106 0.01 0 313.1848 0.16 2 313.4950 0.05 0 314.2035 0.11 1 314.3656 0.08 1 315.2003 0.13 1 315.6006 0.02 0 315.8703 0.02 0 316.1018 0.05 0 316.3334 0.06 1 316.8053 0.01 0 317.2619 0.18 2 317.5937 0.04 0 317.7092 0.03 0 317.9348 0.06 1 318.0743 0.02 0 318.3007 0.07 1 318.5003 0.05 0 318.9711 0.05 0 319.1874 0.30 3 319.3183 0.14 1 319.6769 0.04 0 319.7904 0.03 0 320.0356 0.06 1 320.2539 0.09 1 320.4336 0.02 0 320.5485 0.01 0 320.7722 0.05 0 321.2726 0.32 3 321.5638 0.06 1 321.6474 0.02 0 321.7903 0.02 0 322.0135 0.01 0 322.2106 0.09 1 322.4003 0.06 1 322.6790 0.03 0 323.2950 0.21 2 323.5316 0.09 1 323.7949 0.02 0 324.0355 0.09 1 324.3443 0.13 1 324.6023 0.01 0 324.9506 0.03 0 325.3416 0.20 2 325.5135 0.09 1 325.8578 0.06 1 326.0022 0.06 1 326.3512 0.09 1 326.6460 0.02 0 326.8727 0.01 0 327.2097 0.19 2 327.3074 0.09 1 327.4652 0.08 1 327.8176 0.07 1 328.0016 0.02 0 328.1387 0.05 0 328.2744 0.05 0 328.4022 0.01 0 328.4831 0.01 0 329.2190 0.19 2 329.4646 0.05 0 329.6855 0.03 0 329.9999 0.04 0 330.2729 0.22 2 330.5859 0.02 0 330.7155 0.03 0 331.0539 0.06 1 331.2742 0.09 1 331.4565 0.04 0 331.6154 0.02 0 331.7463 0.01 0 331.9406 0.06 1 332.0721 0.07 1 332.3245 0.15 1 332.6651 0.03 0 332.9215 0.04 0 333.2300 0.25 2 333.4484 0.20 2 333.5746 0.02 0 333.8198 0.02 0 334.2085 0.09 1 334.3842 0.05 0 334.5225 0.03 0 334.7616 0.03 0 334.9861 0.07 1 335.3127 0.31 3 335.4651 0.10 1 335.5466 0.03 0 335.6615 0.03 0 336.0062 0.04 0 336.3657 0.13 1 336.5214 0.04 0 337.2805 0.34 3 337.6875 0.03 0 337.9568 0.01 0 338.2409 0.23 2 338.4240 0.09 1 338.7088 0.06 1 338.9535 0.04 0 339.3111 0.11 1 339.5651 0.04 0 339.7610 0.01 0 339.9241 0.03 0 340.2384 0.07 1 340.4262 0.05 0 341.0675 0.09 1 341.1290 0.04 0 341.2387 0.05 0 341.3289 0.01 0 341.8091 0.02 0 341.8920 0.01 0 342.2652 0.02 0 342.3816 0.08 1 342.5575 0.04 0 342.6772 0.04 0 342.8157 0.06 1 343.1548 0.08 1 343.3200 0.09 1 343.4725 0.04 0 343.6732 0.03 0 343.8451 0.01 0 344.0251 0.06 1 344.1562 0.06 1 344.4205 0.05 0 344.7289 0.02 0 344.8681 0.10 1 344.9510 0.04 0 345.2501 0.31 3 345.5579 0.06 1 346.1743 0.08 1 346.6728 0.02 0 346.8596 0.06 1 347.2665 0.49 5 347.5858 0.09 1 347.9138 0.04 0 348.1139 0.14 1 348.3576 0.20 2 348.5825 0.03 0 348.7144 0.04 0 349.2399 0.56 6 349.3712 0.30 3 349.7796 0.01 0 350.0253 0.12 1 350.3367 0.32 3 350.5978 0.06 1 350.8449 0.05 0 351.0124 0.06 1 351.1289 0.09 1 351.3713 0.27 3 351.6412 0.03 0 352.2675 0.17 2 352.4088 0.15 1 352.5408 0.11 1 352.6466 0.03 0 352.7679 0.01 0 353.2830 0.15 1 353.5255 0.02 0 353.8069 0.07 1 354.0126 0.02 0 354.1854 0.04 0 354.3040 0.02 0 354.4608 0.03 0 355.2193 0.11 1 355.3520 0.09 1 355.5416 0.02 0 355.7627 0.02 0 355.8698 0.02 0 356.0566 0.02 0 356.2046 0.03 0 356.4349 0.02 0 356.7148 0.02 0 357.2184 0.05 0 357.3858 0.08 1 357.8647 0.02 0 358.2176 0.04 0 358.5605 0.05 0 358.8472 0.04 0 359.2237 0.11 1 359.3918 0.13 1 359.5901 0.06 1 359.9277 0.04 0 360.0429 0.04 0 360.3424 0.19 2 360.4235 0.09 1 360.5441 0.01 0 360.7249 0.05 0 360.9099 0.02 0 361.2864 0.49 5 361.5672 0.06 1 361.6717 0.02 0 361.7870 0.04 0 362.3063 0.79 8 363.2968 1.16 12 363.8344 0.06 1 364.2915 0.29 3 364.6200 0.04 0 364.7809 0.06 1 364.8774 0.02 0 365.0551 0.09 1 365.3031 0.13 1 365.4982 0.09 1 365.8515 0.14 1 366.3034 0.04 0 366.4241 0.04 0 366.6689 0.02 0 367.1074 0.03 0 367.2945 0.06 1 368.0241 0.03 0 368.1187 0.02 0 368.2769 0.04 0 368.5009 0.06 1 369.3152 0.05 0 369.6016 0.03 0 370.1892 0.02 0 370.2803 0.03 0 370.4063 0.03 0 370.5168 0.03 0 370.7768 0.01 0 371.3308 0.09 1 371.4247 0.05 0 372.1912 0.04 0 372.4070 0.02 0 372.5236 0.03 0 372.8198 0.02 0 372.9799 0.05 0 373.2319 0.15 1 373.3968 0.16 2 374.0007 0.02 0 374.3009 0.14 1 374.4015 0.06 1 374.5751 0.05 0 374.6998 0.03 0 374.8492 0.05 0 375.3124 0.28 3 375.6631 0.01 0 376.0418 0.14 1 376.3429 0.46 5 377.3097 4.07 41 377.7911 0.10 1 377.8763 0.04 0 378.1875 0.15 1 378.3605 0.18 2 378.5657 0.06 1 378.7300 0.03 0 378.9091 0.05 0 379.3846 0.24 2 379.5703 0.07 1 379.7407 0.03 0 379.8775 0.05 0 380.0204 0.04 0 380.2834 0.06 1 380.5013 0.10 1 381.1909 0.06 1 381.2902 0.04 0 381.4117 0.01 0 381.8249 0.02 0 381.9812 0.03 0 382.3429 0.02 0 382.4697 0.04 0 382.7656 0.03 0 383.0789 0.01 0 383.3540 0.02 0 383.5144 0.02 0 383.9405 0.02 0 384.2016 0.03 0 384.3854 0.01 0 384.6928 0.04 0 385.0049 0.06 1 385.3975 0.10 1 385.5264 0.03 0 386.0627 0.02 0 386.4789 0.07 1 386.7353 0.01 0 386.9628 0.03 0 387.2784 0.13 1 387.4442 0.15 1 387.6436 0.02 0 388.2485 0.02 0 388.4546 0.03 0 388.6218 0.02 0 388.9279 0.03 0 389.3537 0.30 3 389.6787 0.09 1 389.8009 0.03 0 390.3576 0.56 6 390.5356 0.09 1 390.6712 0.06 1 391.3375 0.23 2 391.7122 0.08 1 392.0931 0.02 0 392.2885 0.10 1 392.4632 0.08 1 392.5962 0.03 0 393.1988 0.03 0 393.3304 0.05 0 393.4722 0.07 1 394.0204 0.06 1 394.3657 0.18 2 394.5962 0.06 1 394.6909 0.04 0 395.1364 0.02 0 395.3776 0.05 0 396.2942 0.03 0 396.4017 0.05 0 396.9131 0.04 0 397.2505 0.04 0 397.3614 0.03 0 397.4777 0.02 0 397.6242 0.01 0 397.8493 0.01 0 398.2607 0.07 1 398.6573 0.01 0 399.0774 0.05 0 399.4451 0.17 2 399.5345 0.04 0 400.0427 0.02 0 400.2686 0.01 0 400.5026 0.21 2 400.5947 0.11 1 400.8132 0.05 0 401.3124 0.19 2 401.5002 0.12 1 401.7410 0.02 0 401.9798 0.04 0 402.1750 0.08 1 402.4320 0.21 2 402.7299 0.07 1 402.9016 0.03 0 403.3894 1.01 10 403.7497 0.01 0 404.3583 1.26 13 404.7951 0.07 1 405.3575 0.43 4 406.1252 0.02 0 406.4138 0.12 1 406.5709 0.02 0 406.7051 0.07 1 406.8286 0.02 0 407.0938 0.08 1 407.5911 0.03 0 408.0805 0.07 1 408.1631 0.04 0 408.2892 0.03 0 408.5947 0.08 1 409.2909 0.03 0 409.4634 0.01 0 409.6595 0.02 0 409.8461 0.01 0 410.4168 0.05 0 410.8667 0.03 0 411.3542 0.13 1 411.6711 0.05 0 411.7537 0.04 0 411.9370 0.02 0 412.1452 0.06 1 412.3695 0.07 1 412.7033 0.04 0 413.0210 0.03 0 413.2003 0.02 0 413.3763 0.05 0 413.5932 0.06 1 413.7967 0.10 1 413.9129 0.05 0 414.1043 0.01 0 414.2689 0.04 0 414.4550 0.11 1 414.6605 0.06 1 415.0864 0.05 0 415.3517 0.17 2 415.5345 0.15 1 415.7790 0.03 0 416.3722 0.25 2 417.0024 0.06 1 417.3766 0.41 4 417.5863 0.09 1 417.8990 0.06 1 418.3935 0.94 9 418.7974 0.02 0 419.0108 0.03 0 419.3335 0.38 4 419.4436 0.27 3 419.7925 0.06 1 420.2226 0.06 1 420.4052 0.14 1 420.5750 0.08 1 420.9441 0.04 0 421.1830 0.02 0 421.4031 0.01 0 421.7427 0.02 0 421.8568 0.01 0 422.5515 0.02 0 422.7690 0.02 0 423.2375 0.06 1 423.4724 0.02 0 424.0497 0.02 0 424.3558 0.07 1 424.4639 0.02 0 424.5592 0.02 0 424.7586 0.03 0 425.0124 0.02 0 425.2762 0.05 0 425.4132 0.04 0 425.6630 0.02 0 426.0826 0.02 0 426.2626 0.01 0 426.3834 0.04 0 426.5009 0.02 0 426.7628 0.02 0 427.1321 0.05 0 427.4081 0.05 0 427.7170 0.05 0 427.8775 0.04 0 428.0239 0.03 0 428.1696 0.10 1 428.3671 0.11 1 428.5551 0.02 0 428.7163 0.05 0 428.9702 0.06 1 429.1045 0.07 1 429.1965 0.05 0 429.4342 0.20 2 429.6438 0.08 1 429.7694 0.03 0 429.8742 0.04 0 429.9930 0.03 0 430.4572 0.02 0 430.7883 0.02 0 430.9307 0.02 0 431.1705 0.04 0 431.3573 0.13 1 431.6280 0.01 0 431.8672 0.03 0 432.0916 0.09 1 432.3945 0.29 3 432.6915 0.01 0 432.8547 0.07 1 432.9904 0.07 1 433.3223 0.49 5 433.6415 0.11 1 433.7799 0.04 0 433.9606 0.12 1 434.2556 0.14 1 434.3631 0.11 1 434.5049 0.07 1 434.7716 0.07 1 434.9605 0.13 1 435.1997 0.11 1 435.4154 0.10 1 435.5639 0.10 1 435.9684 0.03 0 436.0740 0.04 0 436.2749 0.05 0 436.5068 0.05 0 436.7507 0.01 0 437.0545 0.01 0 437.3065 0.05 0 437.4342 0.03 0 437.6440 0.03 0 438.1353 0.02 0 438.4593 0.03 0 439.1328 0.05 0 439.4346 0.03 0 439.6322 0.03 0 439.7263 0.02 0 439.9986 0.07 1 440.1337 0.09 1 440.4726 0.09 1 440.6272 0.02 0 440.8766 0.03 0 441.0615 0.05 0 441.2047 0.06 1 441.4326 0.08 1 441.7278 0.08 1 441.8656 0.09 1 441.9456 0.06 1 442.0599 0.05 0 442.2765 0.06 1 442.3914 0.07 1 442.5454 0.06 1 442.7270 0.03 0 442.8883 0.03 0 443.2696 0.10 1 443.4794 0.09 1 443.6152 0.03 0 443.9293 0.07 1 444.0685 0.07 1 444.3018 0.11 1 444.5204 0.10 1 444.6388 0.05 0 444.7208 0.02 0 444.8741 0.02 0 445.0134 0.05 0 445.2138 0.10 1 445.3443 0.08 1 445.6126 0.10 1 445.8238 0.08 1 446.0572 0.05 0 446.1803 0.13 1 446.3444 0.14 1 446.5906 0.08 1 446.9054 0.09 1 447.1320 0.06 1 447.3184 0.13 1 447.5128 0.10 1 448.0947 0.10 1 448.1888 0.03 0 448.4458 0.11 1 448.5622 0.04 0 448.8791 0.01 0 449.0103 0.02 0 449.4953 0.15 1 449.7766 0.06 1 449.9522 0.04 0 450.1110 0.04 0 450.3922 0.10 1 451.0179 0.02 0 451.4782 0.06 1 451.6202 0.06 1 451.9768 0.11 1 452.0818 0.05 0 452.3318 0.09 1 452.7875 0.03 0 453.2822 0.05 0 453.4717 0.10 1 453.6075 0.04 0 454.1648 0.05 0 454.2911 0.05 0 454.4498 0.06 1 454.8874 0.03 0 455.1650 0.01 0 455.4306 0.14 1 455.6155 0.09 1 455.9321 0.01 0 456.1829 0.06 1 456.3765 0.25 2 456.5352 0.07 1 456.6501 0.05 0 456.8391 0.02 0 456.9487 0.04 0 457.1497 0.08 1 457.2613 0.10 1 457.3823 0.13 1 457.5343 0.11 1 457.6580 0.04 0 457.8732 0.05 0 458.0029 0.03 0 458.1320 0.05 0 458.4205 0.12 1 458.6982 0.12 1 458.7917 0.04 0 459.0345 0.07 1 459.1817 0.06 1 459.2758 0.04 0 459.3640 0.03 0 459.5939 0.03 0 459.7708 0.05 0 459.9160 0.03 0 460.0122 0.02 0 460.3801 0.13 1 460.4864 0.06 1 460.6249 0.02 0 460.7877 0.09 1 461.1797 0.04 0 461.3667 0.06 1 461.5860 0.11 1 461.8106 0.04 0 461.8806 0.02 0 462.1348 0.04 0 462.3635 0.13 1 462.5801 0.10 1 462.7402 0.04 0 462.9124 0.03 0 463.3086 0.15 1 463.4640 0.10 1 463.6846 0.14 1 464.4885 1.83 18 464.8363 0.22 2 465.3133 0.08 1 465.5266 0.04 0 465.9706 0.05 0 466.1254 0.05 0 466.4840 0.04 0 466.7679 0.06 1 466.9570 0.02 0 467.4556 0.16 2 467.5424 0.07 1 468.4932 0.04 0 468.9474 0.05 0 469.1776 0.11 1 469.3169 0.06 1 469.4986 0.10 1 470.2120 0.06 1 470.2853 0.03 0 470.5424 0.04 0 471.0849 0.01 0 471.4699 0.32 3 471.6247 0.10 1 472.1524 0.16 2 472.4567 0.32 3 472.5805 0.17 2 472.6896 0.11 1 472.7589 0.06 1 473.0598 0.07 1 473.3304 0.12 1 473.4812 0.05 0 473.7148 0.05 0 474.2641 0.12 1 474.4917 0.03 0 474.6855 0.02 0 475.0639 0.06 1 475.2814 0.10 1 475.5352 0.12 1 475.9041 0.04 0 476.4616 0.49 5 476.6771 0.19 2 476.7929 0.05 0 477.0333 0.04 0 477.1686 0.04 0 477.4885 0.35 3 477.9248 0.02 0 478.2117 0.03 0 478.4528 0.02 0 478.8171 0.01 0 479.1363 0.02 0 479.5829 0.04 0 480.4200 0.06 1 480.5302 0.01 0 481.2053 0.02 0 481.3761 0.07 1 481.5745 0.14 1 481.7184 0.03 0 481.8817 0.03 0 482.3296 0.08 1 482.4944 0.08 1 482.7747 0.02 0 483.1312 0.02 0 483.3417 0.06 1 483.5589 0.11 1 483.6799 0.05 0 484.2563 0.02 0 484.4513 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502.7366 0.03 0 502.9434 0.03 0 503.2262 0.05 0 503.9231 0.04 0 504.6450 0.02 0 504.9878 0.01 0 505.3047 0.05 0 505.5667 0.05 0 506.0477 0.02 0 506.6302 0.04 0 507.0003 0.04 0 507.1992 0.07 1 507.2919 0.05 0 507.4484 0.12 1 507.6177 0.19 2 508.0712 0.06 1 508.3474 0.06 1 508.5496 0.07 1 508.8620 0.01 0 509.1388 0.03 0 509.3054 0.09 1 509.5675 0.07 1 510.2851 0.05 0 510.5042 0.05 0 510.6298 0.06 1 510.7884 0.03 0 510.9812 0.04 0 511.3138 0.16 2 511.6169 0.10 1 511.8051 0.05 0 511.9717 0.09 1 512.3380 0.06 1 512.6666 0.13 1 513.1928 0.07 1 513.4005 0.04 0 513.5564 0.06 1 513.7379 0.09 1 514.0201 0.05 0 514.3972 0.07 1 514.6533 0.06 1 514.8831 0.05 0 515.2534 0.05 0 515.3792 0.04 0 515.4941 0.01 0 515.9196 0.02 0 516.3705 0.07 1 516.5876 0.09 1 516.9930 0.04 0 517.4535 0.04 0 517.6511 0.05 0 518.1573 0.02 0 518.4040 0.04 0 518.5942 0.03 0 518.7065 0.09 1 518.9082 0.04 0 519.0850 0.07 1 519.1644 0.03 0 519.3217 0.12 1 519.5052 0.06 1 519.7344 0.03 0 519.9280 0.03 0 520.2891 0.09 1 520.6085 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