MassBank Record: CA000126



 Methyl hydroxy-3,4-dehydro-apo-8'-lycopenate; FAB-EBEB; MS2; m/z: 462.31; [M]*+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: CA000126
RECORD_TITLE: Methyl hydroxy-3,4-dehydro-apo-8'-lycopenate; FAB-EBEB; MS2; m/z: 462.31; [M]*+
DATE: 2016.01.19 (Created 2007.10.06, modified 2012.05.21)
AUTHORS: Akimoto N, Graduate School of Pharmaceutical Sciences, Kyoto University and Maoka T, Research Institute for Production Development
LICENSE: CC BY-SA

CH$NAME: Methyl hydroxy-3,4-dehydro-apo-8'-lycopenate CH$COMPOUND_CLASS: Natural Product; Carotenoid CH$FORMULA: C31H42O3 CH$EXACT_MASS: 462.31340 CH$SMILES: C(C)(=CC=CC=C(C)C=CC=C(C(=O)OC)C)C=CC=C(C)C=CC=C(C)C=CCC(C)(C)O CH$IUPAC: InChI=1S/C31H42O3/c1-25(15-9-10-16-26(2)21-13-23-29(5)30(32)34-8)17-11-18-27(3)19-12-20-28(4)22-14-24-31(6,7)33/h9-23,33H,24H2,1-8H3/b10-9+,17-11+,19-12+,21-13+,22-14+,25-15+,26-16+,27-18+,28-20+,29-23+
AC$INSTRUMENT: JMS-HX/HX 110A, JEOL AC$INSTRUMENT_TYPE: FAB-EBEB AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: ATOM_GUN_CURRENT 5 mA AC$MASS_SPECTROMETRY: BOMBARDMENT 6 kV xenon AC$MASS_SPECTROMETRY: COLLISION_ENERGY 3 kV AC$MASS_SPECTROMETRY: COLLISION_GAS Ar AC$MASS_SPECTROMETRY: GAS_PRESSURE adjust to attenuate the intensity of the precursor ion by 30 % AC$MASS_SPECTROMETRY: IONIZATION FAB AC$MASS_SPECTROMETRY: PROBE_TIP stainless-steel
MS$FOCUSED_ION: BASE_PEAK 462.2885 MS$FOCUSED_ION: PRECURSOR_M/Z 462.31 MS$FOCUSED_ION: PRECURSOR_TYPE [M]*+
PK$SPLASH: splash10-08fr-5920500000-df790c498b342150b683 PK$NUM_PEAK: 1561 PK$PEAK: m/z int. rel.int. 1.6671 0.01 0 9.9788 0.01 0 11.1939 0.03 0 11.9611 0.03 0 12.9680 0.01 0 13.9746 0.03 0 14.9798 0.61 6 15.9798 0.01 0 18.9338 0.01 0 22.9322 0.03 0 23.9383 0.01 0 24.8847 0.01 0 25.9619 0.18 2 26.5128 0.01 0 26.9729 1.21 12 27.9813 0.08 1 28.9766 0.66 7 29.9524 0.02 0 30.3741 0.01 0 30.8366 0.01 0 30.9582 1.41 14 31.9999 0.01 0 32.9825 0.03 0 35.9526 0.01 0 36.2164 0.01 0 36.7395 0.01 0 36.9618 0.17 2 37.2678 0.01 0 37.3390 0.01 0 37.5550 0.01 0 37.7767 0.01 0 37.9666 0.45 4 38.1040 0.01 0 38.5423 0.01 0 38.9740 2.75 27 39.3721 0.01 0 39.9753 0.37 4 40.6158 0.01 0 40.9818 3.78 38 41.9694 0.10 1 42.2440 0.01 0 42.9689 2.83 28 43.9660 0.04 0 44.9761 0.47 5 47.8717 0.01 0 48.0112 0.01 0 48.9434 0.04 0 49.0442 0.01 0 49.2156 0.01 0 49.4463 0.01 0 49.6222 0.01 0 49.9577 1.03 10 50.1513 0.01 0 50.5671 0.01 0 50.6869 0.01 0 50.9570 1.84 18 51.1034 0.01 0 51.4953 0.02 0 51.9725 0.74 7 52.3840 0.01 0 52.6285 0.01 0 52.9692 2.60 26 53.9847 0.19 2 54.9805 3.53 35 55.9706 0.09 1 56.9786 0.32 3 57.3810 0.01 0 57.4667 0.01 0 57.9624 0.13 1 58.2283 0.01 0 58.3223 0.01 0 58.9857 55.99 560 59.2379 0.01 0 59.3823 0.02 0 59.4781 0.01 0 59.5948 0.01 0 59.9720 0.07 1 60.0794 0.01 0 60.5104 0.01 0 60.9432 0.17 2 61.0804 0.01 0 61.3400 0.01 0 61.4732 0.01 0 61.9514 0.46 5 62.1841 0.01 0 62.3474 0.01 0 62.5193 0.01 0 62.6545 0.01 0 62.9453 1.37 14 63.1698 0.02 0 63.3423 0.01 0 63.9534 0.29 3 64.1509 0.01 0 64.2398 0.01 0 64.5327 0.01 0 64.9734 2.47 25 65.2087 0.01 0 65.3298 0.02 0 65.7620 0.02 0 65.9699 0.41 4 66.2114 0.03 0 66.4089 0.02 0 66.5044 0.01 0 66.9801 2.50 25 67.2350 0.01 0 67.6350 0.01 0 67.9844 0.20 2 68.3785 0.01 0 68.9925 1.57 16 69.2959 0.01 0 69.9597 0.03 0 70.5393 0.01 0 70.9794 0.30 3 71.2680 0.01 0 71.9988 0.04 0 72.9823 0.14 1 73.9393 0.34 3 74.1679 0.01 0 74.5139 0.01 0 74.9496 0.47 5 75.1495 0.02 0 75.4217 0.02 0 75.6588 0.01 0 75.9662 0.37 4 76.1717 0.04 0 76.3238 0.01 0 76.5025 0.03 0 76.5944 0.03 0 76.9691 6.32 63 77.2171 0.04 0 77.3862 0.03 0 77.4783 0.02 0 77.6155 0.03 0 77.9762 1.33 13 78.1176 0.04 0 78.3503 0.02 0 78.9783 4.81 48 79.4882 0.01 0 79.9850 0.74 7 80.2113 0.01 0 80.3086 0.01 0 80.5501 0.01 0 81.0028 3.99 40 81.3549 0.02 0 81.4778 0.01 0 81.9841 0.24 2 82.2743 0.01 0 82.4029 0.01 0 82.9875 0.24 2 83.4875 0.02 0 83.9505 0.03 0 84.0242 0.02 0 84.7088 0.01 0 84.9870 0.33 3 85.1659 0.01 0 85.3051 0.01 0 85.9660 0.12 1 86.9631 0.21 2 87.4347 0.01 0 87.5874 0.01 0 87.9801 0.17 2 88.4800 0.04 0 88.6176 0.05 0 88.9829 0.90 9 89.1490 0.03 0 89.2796 0.08 1 89.4108 0.03 0 89.6237 0.03 0 89.9775 0.38 4 90.2951 0.04 0 90.3939 0.03 0 90.5732 0.03 0 91.0030 12.56 126 91.2505 0.03 0 91.5580 0.02 0 91.6938 0.02 0 92.0072 1.58 16 92.4692 0.02 0 92.6585 0.02 0 93.0171 7.52 75 93.3479 0.02 0 93.4794 0.01 0 93.5898 0.01 0 93.7178 0.02 0 94.0179 0.38 4 94.2804 0.01 0 94.3987 0.01 0 94.5756 0.01 0 95.0201 1.97 20 95.3090 0.01 0 95.4270 0.02 0 95.5154 0.01 0 95.9742 0.12 1 96.3464 0.01 0 96.9904 0.51 5 97.3528 0.01 0 97.9744 0.10 1 98.5418 0.02 0 99.0040 0.12 1 99.9742 0.03 0 100.9915 0.32 3 101.2403 0.05 0 101.3490 0.02 0 101.4754 0.02 0 101.7301 0.03 0 101.9933 0.72 7 102.3092 0.02 0 102.5417 0.05 0 103.0043 2.38 24 103.2969 0.01 0 103.4236 0.01 0 103.5203 0.01 0 103.6954 0.02 0 104.0131 1.06 11 104.2299 0.03 0 104.3078 0.01 0 104.4484 0.02 0 104.6069 0.02 0 105.0156 12.25 122 105.3024 0.03 0 105.5881 0.01 0 106.0202 0.89 9 106.5360 0.02 0 106.6897 0.03 0 107.0226 2.85 28 107.3508 0.02 0 107.4910 0.04 0 107.5851 0.01 0 107.7280 0.01 0 108.0132 0.24 2 108.6724 0.01 0 109.0020 0.62 6 109.4898 0.01 0 109.9858 0.09 1 110.1610 0.01 0 110.3930 0.01 0 110.5242 0.01 0 110.5991 0.01 0 110.9944 0.25 2 111.1299 0.03 0 111.3527 0.01 0 111.7277 0.01 0 111.9894 0.79 8 112.2327 0.02 0 112.3860 0.02 0 112.5660 0.03 0 112.9810 0.48 5 113.1804 0.05 0 113.4357 0.04 0 113.9766 0.31 3 114.1121 0.10 1 114.2760 0.08 1 114.9825 7.10 71 115.4405 0.09 1 115.9881 2.33 23 116.2893 0.04 0 116.9928 6.03 60 117.4321 0.03 0 117.5822 0.01 0 117.6915 0.01 0 118.0020 0.95 9 118.3984 0.05 0 118.5014 0.03 0 119.0065 10.18 102 119.3550 0.03 0 119.5672 0.05 0 119.7048 0.01 0 120.0122 0.69 7 120.2090 0.02 0 120.3676 0.01 0 120.6038 0.02 0 120.9992 1.19 12 121.2985 0.01 0 121.4977 0.02 0 121.6744 0.01 0 121.9879 0.16 2 122.1549 0.01 0 122.7485 0.01 0 122.9863 0.39 4 123.2091 0.02 0 123.6214 0.01 0 123.9588 0.10 1 124.5600 0.01 0 124.9821 1.13 11 125.2103 0.05 0 125.5375 0.04 0 125.9643 0.35 3 126.0428 0.17 2 126.9595 2.20 22 127.3079 0.06 1 127.9701 6.75 67 128.2741 0.07 1 128.5222 0.08 1 128.9768 7.47 75 129.4512 0.05 0 129.9884 2.66 27 130.2941 0.03 0 130.4143 0.02 0 130.5895 0.03 0 130.9939 6.44 64 131.2552 0.03 0 131.6180 0.05 0 132.0037 1.50 15 132.2942 0.05 0 132.4675 0.04 0 132.6191 0.04 0 133.0140 2.96 30 133.3991 0.03 0 133.6190 0.03 0 133.7511 0.02 0 134.0219 0.33 3 134.1890 0.02 0 134.2966 0.01 0 134.4145 0.01 0 134.5981 0.02 0 135.0084 1.16 12 135.2986 0.01 0 135.4178 0.01 0 135.5539 0.02 0 135.9657 0.31 3 136.4959 0.01 0 136.9830 0.43 4 137.2601 0.01 0 137.3746 0.01 0 137.5005 0.03 0 137.9766 0.37 4 138.1624 0.02 0 138.2769 0.01 0 138.5351 0.04 0 138.9716 0.89 9 139.3403 0.06 1 139.4412 0.05 0 139.6086 0.02 0 139.9917 0.42 4 140.1827 0.13 1 140.9818 5.49 55 141.3516 0.08 1 141.4857 0.04 0 141.9998 4.36 44 142.2401 0.06 1 142.4051 0.02 0 142.5261 0.12 1 143.0109 8.64 86 143.5239 0.06 1 143.5977 0.03 0 144.0201 2.56 26 144.3358 0.08 1 144.4801 0.03 0 144.5843 0.03 0 145.0291 7.50 75 145.3544 0.04 0 145.5385 0.03 0 146.0411 0.94 9 146.2623 0.03 0 146.4008 0.02 0 146.5018 0.01 0 147.0340 3.70 37 147.2643 0.08 1 147.5481 0.03 0 147.7608 0.04 0 148.0470 0.12 1 148.2935 0.01 0 148.4350 0.02 0 148.6064 0.03 0 148.7490 0.02 0 149.0183 0.37 4 149.5592 0.01 0 149.7606 0.02 0 150.0129 0.21 2 150.2243 0.05 0 150.3810 0.02 0 150.6440 0.06 1 151.0089 0.65 6 151.2232 0.09 1 151.5673 0.08 1 152.0034 2.23 22 152.3271 0.09 1 152.6071 0.10 1 153.0258 3.29 33 153.3875 0.04 0 153.5017 0.02 0 154.0234 2.48 25 154.4209 0.05 0 155.0406 5.78 58 155.4695 0.06 1 156.0480 3.80 38 156.2803 0.05 0 157.0616 6.69 67 157.4399 0.05 0 157.6563 0.05 0 158.0577 1.44 14 158.3528 0.05 0 158.5958 0.04 0 159.0697 4.07 41 159.3166 0.05 0 159.6475 0.07 1 160.0517 0.19 2 160.3605 0.02 0 160.5044 0.02 0 161.0750 0.92 9 161.3829 0.03 0 161.6358 0.03 0 161.7420 0.01 0 162.0350 0.11 1 162.2402 0.01 0 162.3464 0.02 0 162.4910 0.03 0 162.6073 0.01 0 163.0212 0.52 5 163.2399 0.02 0 163.3651 0.02 0 163.6656 0.05 0 164.0397 0.37 4 164.5303 0.08 1 165.0205 4.94 49 165.5342 0.04 0 166.0247 1.36 14 166.2644 0.06 1 167.0128 3.39 34 167.3408 0.03 0 167.6114 0.06 1 168.0405 1.50 15 168.4268 0.07 1 168.6211 0.04 0 169.0460 4.78 48 169.3365 0.05 0 169.5571 0.04 0 170.0460 1.70 17 170.3209 0.03 0 170.5188 0.04 0 171.0543 3.25 32 171.6275 0.07 1 172.0459 0.66 7 172.3094 0.02 0 172.5657 0.06 1 172.6423 0.03 0 173.0593 1.00 10 173.3107 0.02 0 173.6024 0.03 0 174.0291 0.08 1 174.2122 0.02 0 174.2957 0.02 0 174.4391 0.03 0 174.6111 0.02 0 174.7102 0.01 0 175.0234 0.25 2 175.3249 0.02 0 175.5334 0.03 0 176.0049 0.42 4 176.2516 0.04 0 176.3301 0.02 0 176.5168 0.03 0 177.0205 0.73 7 177.2741 0.06 1 178.0014 2.29 23 178.3297 0.05 0 178.5206 0.05 0 179.0141 3.50 35 179.2781 0.06 1 179.4629 0.04 0 179.5910 0.03 0 180.0162 1.28 13 180.2680 0.05 0 180.4663 0.03 0 181.0205 3.57 36 181.4259 0.07 1 181.5029 0.03 0 182.0388 1.62 16 182.5153 0.05 0 182.6570 0.06 1 183.0470 3.98 40 183.3762 0.05 0 183.6098 0.05 0 184.0562 0.74 7 184.4762 0.02 0 185.0422 1.61 16 185.3323 0.03 0 185.5712 0.02 0 186.0451 0.24 2 186.5850 0.08 1 186.6899 0.02 0 187.0298 0.64 6 187.2345 0.02 0 187.3546 0.03 0 187.4758 0.05 0 187.6213 0.04 0 187.9863 0.15 1 188.3789 0.04 0 188.9984 0.97 10 189.3596 0.03 0 189.5617 0.03 0 190.0020 0.47 5 190.1387 0.16 2 190.2008 0.08 1 190.3414 0.05 0 190.5503 0.03 0 191.0016 1.41 14 191.3948 0.05 0 191.6072 0.08 1 192.0186 1.38 14 192.3159 0.03 0 192.4730 0.07 1 193.0264 2.91 29 193.3323 0.04 0 193.5116 0.04 0 193.7547 0.03 0 194.0387 1.35 13 194.2904 0.03 0 194.4505 0.03 0 194.6123 0.05 0 195.0445 3.25 32 195.3445 0.07 1 195.5737 0.04 0 196.0452 1.10 11 196.2768 0.06 1 196.4070 0.04 0 196.5367 0.03 0 196.6431 0.04 0 197.0543 2.26 23 197.3069 0.07 1 197.4609 0.03 0 197.7011 0.06 1 198.0535 0.40 4 198.2949 0.01 0 198.5120 0.04 0 199.0668 1.07 11 199.3191 0.03 0 199.4795 0.03 0 200.0102 0.21 2 200.3272 0.03 0 200.5711 0.05 0 200.7810 0.04 0 201.0607 0.31 3 201.6246 0.14 1 202.0151 0.97 10 202.2415 0.05 0 202.3755 0.03 0 202.5270 0.02 0 203.0289 1.14 11 203.3048 0.05 0 203.4871 0.06 1 203.5978 0.03 0 203.7483 0.03 0 204.0243 0.42 4 204.2521 0.06 1 204.3833 0.07 1 204.5208 0.05 0 205.0475 1.24 12 205.2759 0.04 0 205.3498 0.02 0 205.5260 0.03 0 206.0619 0.95 9 206.3126 0.04 0 206.4371 0.03 0 206.6407 0.04 0 207.0688 2.09 21 207.4009 0.02 0 208.0585 0.79 8 208.3372 0.03 0 208.6080 0.06 1 209.0781 2.35 23 209.3990 0.06 1 209.5687 0.02 0 210.0759 0.63 6 210.3554 0.03 0 210.4619 0.03 0 210.6481 0.05 0 211.0831 1.63 16 211.3537 0.02 0 211.5274 0.03 0 211.7849 0.02 0 212.0931 0.28 3 212.4275 0.03 0 212.7039 0.05 0 213.0760 0.53 5 213.3456 0.04 0 213.4297 0.04 0 213.5589 0.03 0 214.0829 0.12 1 214.2770 0.03 0 214.3977 0.01 0 214.6754 0.03 0 215.0625 1.14 11 215.4228 0.03 0 215.6022 0.07 1 216.0543 0.46 5 216.2701 0.06 1 217.0464 1.37 14 217.3449 0.02 0 217.4953 0.04 0 217.6492 0.04 0 218.0765 0.39 4 218.2657 0.04 0 218.4589 0.03 0 219.0637 1.26 13 219.4433 0.01 0 220.0768 0.75 7 220.4292 0.05 0 220.5233 0.02 0 221.0983 1.46 15 221.3287 0.04 0 221.4633 0.04 0 222.1098 0.49 5 222.3432 0.02 0 222.5012 0.02 0 223.0965 1.43 14 223.3386 0.02 0 223.5178 0.05 0 223.5800 0.03 0 223.7479 0.03 0 224.0950 0.40 4 224.3200 0.05 0 224.5227 0.03 0 224.5970 0.02 0 224.7237 0.02 0 225.1012 0.59 6 225.3623 0.02 0 225.4822 0.01 0 225.6056 0.03 0 225.7656 0.05 0 226.0661 0.21 2 226.3163 0.07 1 226.5729 0.03 0 227.0741 0.37 4 227.2221 0.08 1 227.4176 0.02 0 227.5679 0.04 0 228.0481 0.31 3 228.3071 0.01 0 228.5152 0.03 0 228.6765 0.03 0 229.0670 0.91 9 229.4250 0.03 0 229.5343 0.02 0 230.0771 0.33 3 230.3317 0.05 0 230.5342 0.04 0 231.0972 0.83 8 231.3868 0.01 0 231.5402 0.04 0 231.6386 0.02 0 231.8235 0.08 1 232.0913 0.37 4 232.4084 0.03 0 232.6340 0.02 0 233.0920 0.95 9 233.4419 0.04 0 234.0838 0.39 4 234.4538 0.02 0 234.6159 0.05 0 235.1223 0.92 9 235.3767 0.04 0 235.5240 0.05 0 235.6472 0.02 0 236.1050 0.30 3 236.4070 0.05 0 236.6351 0.01 0 236.7526 0.02 0 237.1172 0.55 5 237.5128 0.02 0 237.6863 0.02 0 238.1122 0.18 2 238.5188 0.02 0 238.7439 0.02 0 239.0714 0.33 3 239.2014 0.17 2 239.5537 0.04 0 239.7044 0.01 0 240.0590 0.10 1 240.4176 0.02 0 240.5752 0.01 0 241.0788 0.45 4 241.3912 0.02 0 241.4685 0.01 0 241.8348 0.04 0 242.0990 0.28 3 242.4447 0.03 0 242.6499 0.01 0 243.0994 0.82 8 243.4899 0.08 1 243.6567 0.01 0 244.1029 0.36 4 244.3896 0.02 0 244.5491 0.05 0 244.6386 0.03 0 245.1124 0.89 9 245.3878 0.04 0 245.6528 0.03 0 246.1055 0.26 3 246.3936 0.05 0 246.6783 0.05 0 247.1133 0.65 6 247.4709 0.01 0 247.6661 0.05 0 248.1115 0.25 2 248.5278 0.03 0 248.7000 0.04 0 248.7684 0.02 0 249.1319 0.50 5 249.3932 0.01 0 249.5178 0.02 0 250.0956 0.14 1 250.4845 0.02 0 250.5758 0.02 0 250.6804 0.03 0 250.7861 0.01 0 251.1584 0.30 3 251.7692 0.06 1 252.0869 0.16 2 252.3030 0.02 0 252.4105 0.01 0 252.5525 0.01 0 252.7347 0.03 0 253.1037 0.20 2 253.4534 0.02 0 253.7406 0.02 0 254.1094 0.19 2 254.5345 0.01 0 254.6632 0.02 0 255.0757 0.37 4 255.3866 0.02 0 255.5331 0.02 0 256.0871 0.26 3 256.4894 0.03 0 256.5986 0.02 0 256.6866 0.02 0 257.1194 0.64 6 257.4189 0.05 0 257.5259 0.02 0 257.6863 0.03 0 257.8668 0.04 0 258.1181 0.23 2 258.5189 0.02 0 259.1296 0.38 4 259.3769 0.03 0 259.7819 0.04 0 259.9032 0.03 0 260.1425 0.23 2 260.3830 0.05 0 260.5475 0.03 0 260.7892 0.03 0 261.1103 0.50 5 261.4469 0.02 0 261.6753 0.04 0 262.1294 0.10 1 262.5133 0.02 0 262.5858 0.01 0 262.8212 0.03 0 263.1407 0.38 4 263.5650 0.01 0 263.6974 0.02 0 263.8384 0.04 0 264.1303 0.08 1 264.4401 0.03 0 264.6434 0.03 0 265.1329 0.20 2 265.2873 0.05 0 265.4197 0.02 0 265.5844 0.01 0 265.8131 0.02 0 266.0959 0.11 1 266.2284 0.05 0 266.3338 0.02 0 266.5712 0.02 0 266.6691 0.01 0 266.8074 0.01 0 267.1225 0.26 3 267.2948 0.07 1 267.4677 0.03 0 267.7154 0.03 0 268.1411 0.12 1 268.3683 0.03 0 269.1237 0.32 3 269.5057 0.02 0 269.6541 0.02 0 269.8072 0.01 0 270.1720 0.12 1 270.3188 0.05 0 270.5450 0.02 0 270.6687 0.01 0 271.1239 0.31 3 271.6184 0.02 0 271.7410 0.02 0 271.8918 0.02 0 272.1215 0.10 1 272.2954 0.05 0 272.5395 0.04 0 272.6944 0.03 0 273.1435 0.30 3 273.5304 0.02 0 273.7827 0.03 0 273.9692 0.07 1 274.1322 0.14 1 274.3200 0.02 0 274.4283 0.06 1 274.6644 0.01 0 275.1247 0.34 3 275.4582 0.03 0 275.6339 0.03 0 275.8304 0.02 0 276.1691 0.14 1 276.4976 0.02 0 276.8306 0.03 0 277.1505 0.24 2 277.6190 0.01 0 277.7821 0.02 0 278.1141 0.12 1 278.3193 0.03 0 278.5377 0.03 0 279.0825 0.13 1 279.2497 0.06 1 279.3684 0.02 0 279.5506 0.03 0 279.6844 0.03 0 279.9836 0.04 0 280.0909 0.04 0 280.2495 0.03 0 280.4876 0.02 0 280.6906 0.03 0 280.7800 0.02 0 281.1416 0.20 2 281.5182 0.01 0 281.6024 0.01 0 281.9531 0.04 0 282.1238 0.10 1 282.2940 0.03 0 282.5190 0.03 0 282.7082 0.01 0 283.1276 0.27 3 283.5067 0.02 0 283.6250 0.03 0 283.7634 0.01 0 284.1414 0.09 1 284.5044 0.02 0 284.6764 0.02 0 284.8206 0.01 0 285.1127 0.13 1 285.3372 0.06 1 285.4797 0.02 0 286.1268 0.10 1 286.4524 0.02 0 286.5846 0.02 0 286.7249 0.02 0 286.8358 0.02 0 287.1198 0.15 1 287.5309 0.02 0 287.6741 0.03 0 288.1407 0.10 1 288.6218 0.02 0 288.7997 0.03 0 289.1497 0.28 3 289.2507 0.11 1 289.3322 0.05 0 289.4413 0.01 0 289.6764 0.02 0 289.7966 0.03 0 289.9173 0.02 0 290.1166 0.10 1 290.3176 0.02 0 290.5389 0.02 0 290.8757 0.06 1 291.1172 0.24 2 291.5442 0.01 0 292.0666 0.11 1 292.2163 0.06 1 292.5018 0.02 0 292.6197 0.01 0 293.0977 0.18 2 293.5809 0.02 0 293.8774 0.02 0 294.0849 0.07 1 294.3347 0.05 0 294.4364 0.02 0 295.0903 0.27 3 295.3459 0.03 0 295.5199 0.02 0 295.7379 0.03 0 296.1155 0.14 1 296.2693 0.07 1 296.3804 0.02 0 296.6481 0.02 0 296.7459 0.01 0 296.8477 0.01 0 297.1559 0.22 2 297.4000 0.01 0 297.7679 0.04 0 298.0184 0.08 1 298.2226 0.13 1 298.4123 0.01 0 298.6900 0.01 0 299.1268 0.12 1 299.3073 0.03 0 299.4827 0.01 0 299.6464 0.02 0 300.1088 0.05 0 300.4519 0.02 0 300.6747 0.02 0 301.1470 0.15 1 301.3687 0.02 0 301.7009 0.03 0 302.0164 0.03 0 302.2068 0.03 0 302.3573 0.02 0 302.5246 0.01 0 302.6439 0.01 0 302.8036 0.02 0 303.0908 0.09 1 303.2541 0.08 1 304.1255 0.09 1 304.3050 0.03 0 304.6623 0.01 0 305.1383 0.08 1 305.5495 0.01 0 305.9347 0.01 0 306.0911 0.05 0 306.2851 0.04 0 306.5822 0.02 0 306.6854 0.02 0 307.1329 0.39 4 307.4288 0.03 0 308.1190 0.67 7 308.4306 0.04 0 308.6873 0.04 0 309.1255 1.93 19 309.6297 0.02 0 310.1391 0.11 1 310.2999 0.06 1 310.5474 0.03 0 310.6330 0.02 0 310.7920 0.03 0 310.9302 0.04 0 311.1853 0.16 2 311.3946 0.04 0 312.1830 0.09 1 312.3716 0.02 0 312.8534 0.03 0 313.0310 0.04 0 313.2185 0.14 1 313.5367 0.03 0 313.6310 0.01 0 313.7467 0.01 0 313.9746 0.03 0 314.1291 0.07 1 314.2281 0.04 0 314.5399 0.01 0 314.6505 0.02 0 314.7627 0.01 0 315.1904 0.12 1 315.3536 0.01 0 315.6128 0.01 0 315.8680 0.03 0 315.9902 0.01 0 316.1806 0.04 0 316.2662 0.02 0 316.4844 0.01 0 317.0679 0.05 0 317.2196 0.04 0 317.3058 0.02 0 317.3880 0.01 0 317.5947 0.04 0 318.1725 0.03 0 318.2981 0.02 0 318.4839 0.02 0 318.6414 0.02 0 319.0062 0.05 0 319.1393 0.04 0 319.2581 0.09 1 319.5638 0.01 0 319.6726 0.01 0 320.1597 0.07 1 320.2865 0.03 0 320.4394 0.01 0 320.7330 0.03 0 320.8645 0.02 0 321.1454 0.10 1 321.3823 0.02 0 321.6429 0.02 0 321.8173 0.02 0 322.1422 0.11 1 322.2453 0.08 1 322.4643 0.05 0 322.6230 0.01 0 322.8884 0.04 0 323.1937 0.14 1 323.4225 0.02 0 323.6294 0.01 0 323.7394 0.03 0 323.9689 0.07 1 324.1039 0.13 1 324.2505 0.07 1 324.5304 0.01 0 324.6468 0.02 0 324.7674 0.01 0 324.9516 0.04 0 325.1110 0.09 1 325.2194 0.05 0 325.3376 0.02 0 325.5653 0.01 0 325.8424 0.03 0 326.0794 0.03 0 326.2469 0.02 0 326.8167 0.01 0 327.2132 0.10 1 327.4317 0.02 0 327.5256 0.02 0 327.6543 0.02 0 327.9372 0.03 0 328.0966 0.05 0 328.3117 0.03 0 328.4375 0.02 0 328.5993 0.04 0 328.8868 0.02 0 329.1681 0.21 2 329.2875 0.09 1 329.8482 0.01 0 330.2309 0.08 1 330.4641 0.02 0 330.7523 0.02 0 330.8253 0.01 0 331.2336 0.08 1 331.4442 0.03 0 331.6476 0.02 0 331.7849 0.01 0 332.0208 0.04 0 332.1622 0.04 0 332.2572 0.05 0 332.3864 0.02 0 332.7151 0.02 0 332.8843 0.01 0 333.1300 0.12 1 333.3398 0.03 0 333.4302 0.01 0 333.6360 0.03 0 333.7693 0.02 0 333.8597 0.02 0 334.2527 0.08 1 334.4406 0.05 0 334.5617 0.02 0 334.8585 0.07 1 335.1652 0.15 1 335.3362 0.08 1 335.4869 0.04 0 335.6493 0.01 0 335.8319 0.03 0 336.0754 0.06 1 336.2493 0.06 1 336.3264 0.03 0 336.5758 0.03 0 336.7225 0.02 0 336.8703 0.01 0 337.0014 0.02 0 337.2090 0.06 1 337.3290 0.04 0 337.4566 0.03 0 337.7662 0.01 0 338.0272 0.03 0 338.1977 0.04 0 338.3386 0.02 0 338.4755 0.02 0 338.7829 0.03 0 338.9209 0.03 0 339.1396 0.05 0 339.2788 0.02 0 339.3792 0.02 0 339.6059 0.01 0 339.8148 0.01 0 339.9957 0.02 0 340.2022 0.04 0 340.3711 0.02 0 340.7040 0.02 0 340.8195 0.03 0 340.8990 0.02 0 341.1484 0.06 1 341.2708 0.04 0 341.7367 0.01 0 341.8354 0.01 0 342.0483 0.04 0 342.2026 0.02 0 342.3668 0.03 0 342.5061 0.02 0 342.8496 0.01 0 343.2042 0.13 1 343.3307 0.06 1 343.5674 0.01 0 343.6632 0.03 0 343.7984 0.02 0 344.0758 0.09 1 344.2366 0.12 1 344.4001 0.05 0 344.4645 0.02 0 344.5601 0.01 0 344.7108 0.01 0 344.9525 0.02 0 345.1461 0.09 1 345.2609 0.09 1 345.4266 0.01 0 345.6180 0.01 0 345.9281 0.02 0 346.0776 0.01 0 346.2000 0.02 0 346.5542 0.02 0 346.7814 0.01 0 347.1130 0.09 1 347.3160 0.06 1 347.5496 0.02 0 347.6296 0.02 0 347.7520 0.02 0 348.1318 0.09 1 348.2651 0.07 1 348.3573 0.04 0 348.6101 0.03 0 349.2359 0.07 1 349.4290 0.03 0 349.8854 0.03 0 349.9938 0.01 0 350.1336 0.03 0 350.3604 0.01 0 350.5593 0.02 0 351.0036 0.02 0 351.1451 0.01 0 351.2983 0.01 0 351.5373 0.03 0 352.3012 0.03 0 352.3802 0.02 0 352.7259 0.02 0 352.9794 0.03 0 353.1285 0.02 0 353.2945 0.02 0 353.3919 0.02 0 353.5097 0.01 0 354.0598 0.03 0 354.2849 0.01 0 354.5437 0.02 0 354.8750 0.02 0 355.0387 0.02 0 355.2801 0.03 0 355.5708 0.03 0 355.7432 0.02 0 355.8877 0.02 0 356.1459 0.04 0 356.2928 0.03 0 356.7344 0.02 0 356.9265 0.03 0 357.2417 0.07 1 357.5511 0.02 0 357.7009 0.02 0 358.1908 0.06 1 358.6401 0.02 0 358.8549 0.03 0 358.9455 0.03 0 359.2264 0.06 1 359.3623 0.05 0 359.7675 0.01 0 359.9777 0.02 0 360.0915 0.04 0 360.3307 0.03 0 360.5786 0.01 0 360.7917 0.01 0 361.0751 0.04 0 361.2958 0.09 1 361.4224 0.02 0 361.7325 0.03 0 361.9334 0.01 0 362.2290 0.11 1 362.3777 0.04 0 362.5269 0.02 0 362.7755 0.02 0 363.0194 0.03 0 363.1704 0.08 1 363.3604 0.05 0 363.5282 0.03 0 363.7524 0.03 0 363.8837 0.02 0 364.0294 0.02 0 364.2223 0.05 0 364.3309 0.03 0 364.4250 0.03 0 364.5290 0.02 0 364.6562 0.03 0 364.8671 0.01 0 365.1692 0.04 0 365.4747 0.02 0 366.1312 0.02 0 366.2433 0.01 0 366.4414 0.01 0 366.6454 0.02 0 366.7401 0.01 0 366.9370 0.01 0 367.0509 0.04 0 367.1799 0.02 0 367.2700 0.02 0 367.5013 0.04 0 367.6802 0.02 0 367.8865 0.01 0 368.1329 0.03 0 368.3496 0.02 0 368.8523 0.02 0 369.0179 0.03 0 369.2103 0.11 1 369.3172 0.08 1 369.4474 0.01 0 369.7234 0.04 0 370.2506 1.00 10 370.6214 0.03 0 370.7452 0.03 0 370.9626 0.03 0 371.1608 0.07 1 371.2846 0.06 1 371.4172 0.02 0 371.5282 0.02 0 371.6892 0.03 0 372.0764 0.08 1 372.2351 0.13 1 372.4513 0.04 0 372.6316 0.03 0 372.8554 0.02 0 373.2499 0.19 2 373.5892 0.05 0 373.9413 0.03 0 374.1722 0.10 1 374.3521 0.05 0 374.6241 0.07 1 374.8481 0.04 0 374.9780 0.04 0 375.1788 0.09 1 375.3847 0.04 0 375.4561 0.02 0 375.5779 0.02 0 375.6980 0.03 0 375.9742 0.05 0 376.2620 0.10 1 376.5219 0.03 0 376.6675 0.01 0 376.8109 0.02 0 376.9710 0.04 0 377.1666 0.04 0 377.3621 0.04 0 377.4898 0.01 0 377.7184 0.02 0 378.0881 0.03 0 378.3933 0.02 0 378.5094 0.05 0 378.9429 0.02 0 379.2987 0.01 0 379.5134 0.01 0 379.8698 0.01 0 380.1084 0.05 0 380.3411 0.02 0 380.7619 0.03 0 381.0957 0.02 0 381.1851 0.02 0 381.5102 0.02 0 381.6373 0.02 0 382.2022 0.04 0 382.3740 0.02 0 382.5296 0.03 0 382.6498 0.02 0 382.7491 0.02 0 382.8965 0.02 0 383.2664 0.17 2 383.9137 0.02 0 384.1326 0.04 0 384.3289 0.02 0 384.6332 0.02 0 385.1192 0.08 1 385.2301 0.07 1 385.3590 0.07 1 385.5361 0.02 0 385.6383 0.01 0 385.7748 0.04 0 386.0147 0.02 0 386.2743 0.03 0 386.4514 0.02 0 386.6889 0.02 0 387.1913 0.30 3 387.3510 0.08 1 387.6310 0.03 0 388.2357 0.68 7 388.4549 0.09 1 388.6654 0.05 0 389.2715 0.21 2 389.5471 0.04 0 390.0093 0.06 1 390.2605 0.11 1 390.6381 0.06 1 391.0883 0.10 1 391.2501 0.02 0 391.4056 0.04 0 391.5338 0.03 0 391.7409 0.04 0 391.9544 0.03 0 392.1615 0.05 0 392.3721 0.02 0 392.4481 0.02 0 392.5659 0.03 0 392.7318 0.04 0 392.9517 0.05 0 393.0997 0.02 0 393.2360 0.03 0 393.4060 0.02 0 393.5871 0.01 0 393.7745 0.01 0 394.0524 0.02 0 394.2097 0.05 0 394.6129 0.02 0 395.0250 0.02 0 396.2071 0.03 0 396.4311 0.01 0 396.7300 0.01 0 397.1264 0.02 0 397.2443 0.02 0 397.3673 0.01 0 398.1120 0.03 0 398.4556 0.02 0 398.8596 0.01 0 399.0564 0.03 0 399.2050 0.03 0 399.3461 0.02 0 399.6776 0.03 0 399.8082 0.01 0 400.0329 0.04 0 400.2924 0.03 0 400.4909 0.02 0 400.6703 0.02 0 400.9159 0.04 0 401.0808 0.11 1 401.2352 0.09 1 401.3752 0.08 1 401.4559 0.04 0 401.6684 0.05 0 402.2298 0.43 4 402.4261 0.14 1 403.2112 2.92 29 403.6246 0.10 1 404.2367 0.92 9 404.4928 0.13 1 404.5980 0.05 0 404.8349 0.04 0 405.1015 0.05 0 405.2060 0.02 0 405.2914 0.02 0 405.5667 0.04 0 405.6881 0.02 0 405.8960 0.05 0 405.9965 0.03 0 406.2561 0.03 0 406.3671 0.02 0 406.5030 0.01 0 406.6465 0.01 0 406.9613 0.02 0 407.1193 0.05 0 407.1913 0.02 0 407.3104 0.01 0 407.5677 0.02 0 407.7495 0.02 0 407.9685 0.01 0 408.1057 0.03 0 408.3322 0.01 0 408.7063 0.03 0 408.8574 0.02 0 409.7364 0.01 0 409.9758 0.01 0 410.2186 0.02 0 410.5266 0.01 0 410.8020 0.01 0 411.1768 0.01 0 411.4446 0.02 0 411.6027 0.01 0 411.9949 0.01 0 412.2262 0.04 0 413.1467 0.04 0 413.2792 0.03 0 413.4094 0.03 0 413.4995 0.01 0 413.9987 0.03 0 414.2062 0.05 0 414.4619 0.02 0 414.9147 0.01 0 415.2006 0.02 0 415.4424 0.02 0 416.0231 0.04 0 416.1731 0.04 0 416.2684 0.01 0 416.5439 0.02 0 417.0061 0.02 0 417.2345 0.02 0 417.6287 0.01 0 417.8536 0.02 0 418.0141 0.04 0 418.1705 0.03 0 418.4420 0.04 0 418.5507 0.02 0 418.7850 0.01 0 419.0664 0.02 0 419.3751 0.04 0 419.6112 0.01 0 419.7711 0.04 0 420.0208 0.01 0 420.2083 0.01 0 420.3739 0.02 0 420.6991 0.02 0 420.7920 0.02 0 420.9836 0.01 0 421.1085 0.02 0 421.2438 0.02 0 421.4332 0.03 0 421.7520 0.02 0 421.9454 0.03 0 422.1284 0.03 0 422.2138 0.02 0 422.4676 0.02 0 422.9561 0.04 0 423.1739 0.02 0 423.3423 0.05 0 423.5613 0.03 0 423.6938 0.02 0 423.7908 0.02 0 423.8796 0.02 0 423.9784 0.03 0 424.0754 0.02 0 424.2166 0.01 0 424.3972 0.01 0 424.6348 0.02 0 424.9572 0.02 0 425.1716 0.03 0 425.4720 0.02 0 425.8432 0.03 0 426.0854 0.02 0 426.8622 0.01 0 427.1167 0.02 0 427.2765 0.01 0 427.6786 0.03 0 427.8360 0.01 0 428.0156 0.03 0 428.2544 0.04 0 428.4398 0.03 0 428.5130 0.01 0 428.7681 0.03 0 429.2969 0.14 1 429.3986 0.09 1 429.6391 0.02 0 429.7763 0.02 0 430.1331 0.06 1 430.3336 0.03 0 430.5457 0.02 0 430.7898 0.02 0 431.2675 0.77 8 431.6924 0.02 0 431.8104 0.02 0 432.1684 0.05 0 432.3637 0.04 0 432.5363 0.03 0 432.9420 0.01 0 433.1315 0.02 0 433.2774 0.01 0 433.4733 0.02 0 433.8337 0.01 0 434.0383 0.03 0 434.3406 0.05 0 434.6731 0.04 0 434.8789 0.02 0 435.1446 0.05 0 435.3602 0.06 1 435.4945 0.07 1 435.8265 0.03 0 436.1486 0.03 0 436.3916 0.02 0 436.6753 0.06 1 436.8073 0.04 0 436.9863 0.05 0 437.0567 0.02 0 437.2235 0.03 0 437.4672 0.09 1 437.6224 0.05 0 437.8201 0.05 0 438.1858 0.06 1 438.4114 0.03 0 438.5004 0.02 0 438.8347 0.07 1 439.0139 0.04 0 439.4325 0.06 1 439.5523 0.03 0 439.7523 0.05 0 439.9384 0.05 0 440.1263 0.06 1 440.3327 0.06 1 440.5229 0.06 1 440.7904 0.06 1 440.9462 0.04 0 441.0771 0.06 1 441.2068 0.07 1 441.4830 0.06 1 441.8413 0.07 1 442.0344 0.03 0 442.2042 0.09 1 442.5573 0.08 1 442.8027 0.10 1 443.3139 0.21 2 443.5664 0.09 1 444.3231 2.80 28 445.2109 0.17 2 445.4299 0.12 1 446.2261 0.70 7 446.4276 0.35 3 446.5775 0.07 1 447.2767 0.60 6 447.7298 0.10 1 447.9365 0.10 1 448.2722 0.20 2 448.5359 0.16 2 448.7724 0.12 1 449.0744 0.09 1 449.3184 0.05 0 449.6512 0.14 1 449.9864 0.08 1 450.1613 0.09 1 450.4325 0.10 1 450.7259 0.09 1 450.8804 0.08 1 451.0193 0.10 1 451.3097 0.12 1 451.6182 0.10 1 451.9772 0.14 1 452.3851 0.14 1 453.3629 0.14 1 453.6110 0.11 1 453.8730 0.14 1 454.0683 0.13 1 454.3664 0.14 1 454.6888 0.14 1 455.0776 0.16 2 455.9428 0.19 2 462.2885 99.97 999 462.9449 5.71 57 463.5896 2.93 29 464.2419 1.40 14 464.9553 0.69 7 465.8466 0.43 4 466.0187 0.23 2 466.9787 0.18 2 467.4590 0.09 1 467.8369 0.11 1 468.3661 0.11 1 468.7919 0.04 0 469.0988 0.05 0 469.3813 0.06 1 469.5675 0.07 1 469.7253 0.03 0 469.9335 0.08 1 470.0542 0.03 0 470.2357 0.03 0 470.5258 0.03 0 470.7260 0.02 0 471.0317 0.04 0 471.2753 0.02 0 471.4842 0.02 0 471.6194 0.02 0 471.8172 0.02 0 472.0232 0.02 0 472.2506 0.02 0 472.3411 0.02 0 //