MassBank Record: JP002716



 17ALPHA-TRIMETHYLSILOXYPROGESTERONE 3,20-BIS(O-METHYLOXIME); EI-B; MS 
Mass Spectrum
Chemical Structure

ACCESSION: JP002716
RECORD_TITLE: 17ALPHA-TRIMETHYLSILOXYPROGESTERONE 3,20-BIS(O-METHYLOXIME); EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HAYASHI A, DEPT. OF CHEMISTRY, FAC. OF SCI. AND TECHNOLOGY, KINKI UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: 17ALPHA-TRIMETHYLSILOXYPROGESTERONE 3,20-BIS(O-METHYLOXIME) CH$COMPOUND_CLASS: N/A CH$FORMULA: C31H52N2O3Si CH$EXACT_MASS: 528.37472 CH$SMILES: N/A CH$IUPAC: N/A
AC$INSTRUMENT: SHIMADZU LKB-9000B AC$INSTRUMENT_TYPE: EI-B AC$MASS_SPECTROMETRY: MS_TYPE MS AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV
MS$FOCUSED_ION: ION_TYPE [M]+*
PK$SPLASH: splash10-05i0-8931100000-451ea0c218242592294d PK$NUM_PEAK: 214 PK$PEAK: m/z int. rel.int. 50 7.3 73 51 8.5 85 53 8.5 85 54 0.37 4 55 12.1 121 56 5.9 59 57 30.4 304 58 0.13 1 59 33.9 339 60 8.8 88 61 10.6 106 63 0.45 5 65 7.9 79 67 13.8 138 68 9.8 98 69 0.55 6 70 9.5 95 71 20.2 202 72 8.2 82 73 99.99 999 74 16.6 166 75 86.4 864 76 10 100 77 1.05 11 78 5.8 58 79 19.2 192 80 2.7 27 81 2.74 27 82 7.7 77 83 1.4 14 84 8.5 85 85 0.71 7 89 44.2 442 90 8 80 91 29.6 296 92 1.26 13 93 5.5 55 94 11.6 116 95 8.9 89 97 0.05 1 98 5.3 53 100 4.4 44 103 9.7 97 104 0.21 2 105 19.7 197 106 5.2 52 108 6.8 68 110 0.57 6 111 5.4 54 112 3.5 35 113 9.4 94 114 0.65 7 115 10.3 103 116 10.5 105 117 17.3 173 118 0.7 7 119 10.6 106 120 17.8 178 121 10.3 103 122 1.45 15 123 8 80 124 5.6 56 125 14 140 126 0.6 6 127 3.3 33 128 10.6 106 129 3.2 32 130 0.64 6 131 13.4 134 132 3.3 33 134 6.4 64 135 1.54 15 136 11.7 117 137 16.9 169 138 6.3 63 139 0.58 6 141 10.7 107 142 7.7 77 143 17.2 172 144 1.66 17 145 18 180 146 8.4 84 148 5.7 57 149 1.3 13 150 7.5 75 151 5.4 54 152 9.3 93 153 1.29 13 154 3.6 36 155 7.1 71 156 29.1 291 157 1.96 20 158 27 270 159 9.8 98 160 6.3 63 161 0.31 3 162 6 60 164 4.9 49 165 6.3 63 166 0.62 6 167 8.2 82 168 6.8 68 169 5.2 52 170 2.78 28 171 16.3 163 172 19 190 173 9.5 95 174 0.82 8 175 4.5 45 176 2.8 28 177 1.5 15 178 0.2 2 179 4.5 45 181 8.4 84 182 9.7 97 183 1.06 11 184 9.6 96 185 5.2 52 186 11 110 187 1.02 10 188 15.2 152 189 2.1 21 190 7.1 71 192 0.49 5 194 3.3 33 195 2.6 26 196 7.5 75 197 0.66 7 198 8.5 85 199 4.2 42 200 14 140 202 0.55 6 203 0.4 4 205 5.6 56 210 5.6 56 211 0.73 7 212 6.4 64 214 5.4 54 217 2.9 29 218 0.71 7 219 2.9 29 220 1.8 18 221 7.6 76 222 0.09 1 223 3.7 37 224 6.1 61 225 7.8 78 226 0.73 7 227 5.4 54 230 4.4 44 233 5.9 59 234 0.56 6 235 6.7 67 236 5.3 53 237 0.3 3 238 0.57 6 239 5.2 52 241 6.9 69 242 8.8 88 243 0.53 5 247 5.2 52 248 4.4 44 249 2.7 27 250 0.34 3 252 3.5 35 258 4.9 49 262 6.2 62 266 0.79 8 268 2.2 22 272 4.3 43 273 21.2 212 274 0.62 6 279 5.3 53 283 4.7 47 284 6.8 68 285 0.53 5 286 5.1 51 295 3.4 34 298 6.5 65 300 0.57 6 307 9.2 92 308 4.5 45 309 4.7 47 315 1.57 16 317 9 90 323 1.6 16 325 0.8 8 326 0.66 7 328 1.3 13 339 20 200 342 0.7 7 343 0.25 3 344 1.6 16 358 2.9 29 369 7 70 370 0.92 9 372 7.7 77 387 5.2 52 388 4.5 45 397 0.77 8 399 16 160 400 2.3 23 401 11.4 114 413 0.45 5 415 4.6 46 416 5.9 59 428 10.1 101 429 5.48 55 430 34.3 343 431 7.2 72 445 5.5 55 459 2.99 30 460 6.8 68 461 6.1 61 //