MassBank Record: SM846202



 Fluoxastrobin; LC-ESI-QFT; MS2; CE: 35 NCE; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: SM846202
RECORD_TITLE: Fluoxastrobin; LC-ESI-QFT; MS2; CE: 35 NCE; R=35000; [M+H]+
DATE: 2016.12.12
AUTHORS: Krauss M, Schymanski EL, Weidauer C, Schupke H, UFZ and Eawag
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2016 UFZ/Eawag
PUBLICATION: Schymanski, EL et al. Critical Assessment of Small Molecule Identification 2016 - Automated Methods. Submitted.
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 8462

CH$NAME: Fluoxastrobin CH$NAME: (E)-1-[2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yl]oxyphenyl]-1-(5,6-dihydro-1,4,2-dioxazin-3-yl)-N-methoxymethanimine CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C21H16ClFN4O5 CH$EXACT_MASS: 458.07933 CH$SMILES: CO\N=C(\C1=NOCCO1)C1=C(OC2=C(F)C(OC3=C(Cl)C=CC=C3)=NC=N2)C=CC=C1 CH$IUPAC: InChI=1S/C21H16ClFN4O5/c1-28-26-18(21-27-30-11-10-29-21)13-6-2-4-8-15(13)31-19-17(23)20(25-12-24-19)32-16-9-5-3-7-14(16)22/h2-9,12H,10-11H2,1H3/b26-18+ CH$LINK: CAS 361377-29-9 CH$LINK: CHEBI 83253 CH$LINK: PUBCHEM CID:11048796 CH$LINK: INCHIKEY UFEODZBUAFNAEU-NLRVBDNBSA-N CH$LINK: CHEMSPIDER 9223963
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 35 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME Kinetex C18 EVO 2.6 um, 2.1x50 mm, precolumn 2.1x5 mm, Phenomenex AC$CHROMATOGRAPHY: FLOW_GRADIENT 95/5 at 0 min, 95/5 at 1 min, 0/100 at 13 min, 0/100 at 24 min AC$CHROMATOGRAPHY: FLOW_RATE 300 uL/min AC$CHROMATOGRAPHY: RETENTION_TIME 11.998 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 330.0801 MS$FOCUSED_ION: PRECURSOR_M/Z 459.0866 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 2.3.1
PK$SPLASH: splash10-0570-1921700000-748c739c23362939c457 PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 63.0231 C5H3+ 1 63.0229 2.67 65.0387 C5H5+ 2 65.0386 1.68 69.9925 C2NO2+ 1 69.9924 2.28 73.0196 C2H2FN2+ 1 73.0197 -0.09 73.0285 C3H5O2+ 1 73.0284 1.56 75.0229 C6H3+ 2 75.0229 -0.18 77.0386 C6H5+ 2 77.0386 -0.08 78.0338 C5H4N+ 2 78.0338 -0.03 79.0418 C5H5N+ 2 79.0417 1.63 79.0542 C6H7+ 2 79.0542 -0.05 80.0495 C5H6N+ 2 80.0495 0 81.0336 C5H5O+ 3 81.0335 1.04 86.0238 C3H4NO2+ 2 86.0237 1.82 86.9877 C3FO2+ 1 86.9877 -0.05 86.9997 C4H4Cl+ 1 86.9996 0.79 90.0338 C6H4N+ 2 90.0338 0.22 91.019 C3H4FO2+ 1 91.019 -0.23 91.0418 C6H5N+ 2 91.0417 1.95 91.0542 C7H7+ 2 91.0542 0 92.0256 C6H4O+ 2 92.0257 -1.01 92.0496 C6H6N+ 2 92.0495 0.92 93.0335 C6H5O+ 3 93.0335 0.46 94.0413 C6H6O+ 2 94.0413 -0.04 95.0492 C6H7O+ 3 95.0491 0.6 96.0443 C5H6NO+ 2 96.0444 -0.89 97.0035 ClH4N3O+ 2 97.0037 -2.1 98.9996 C5H4Cl+ 2 98.9996 0.28 102.0337 C2H3FN4+ 2 102.0336 0.91 104.0141 C3H3FNO2+ 1 104.0142 -0.86 104.0495 C7H6N+ 2 104.0495 0.51 105.0336 C7H5O+ 3 105.0335 0.71 105.0448 C6H5N2+ 1 105.0447 0.46 106.0288 C6H4NO+ 3 106.0287 0.58 106.0526 C6H6N2+ 1 106.0525 0.75 106.0653 C7H8N+ 2 106.0651 1.37 107.0292 C7H4F+ 1 107.0292 0.82 107.0494 C4H10ClN+ 3 107.0496 -1.85 108.0445 C6H6NO+ 3 108.0444 0.65 110.9998 C6H4Cl+ 2 110.9996 1.69 111.0441 C6H7O2+ 3 111.0441 0.23 112.0076 C6H5Cl+ 2 112.0074 1.27 113.0398 C6H6FO+ 2 113.0397 1.02 115.0419 C8H5N+ 2 115.0417 2.28 116.037 C7H4N2+ 1 116.0369 0.52 117.0448 C7H5N2+ 1 117.0447 0.58 117.0575 C8H7N+ 2 117.0573 1.34 118.0289 C7H4NO+ 3 118.0287 1.67 118.0525 C7H6N2+ 1 118.0525 -0.06 119.0366 C7H5NO+ 3 119.0366 0.31 120.0444 C7H6NO+ 3 120.0444 0.38 121.0396 C6H5N2O+ 2 121.0396 -0.16 122.0401 C7H5FN+ 1 122.0401 0.31 123.0354 C6H4FN2+ 1 123.0353 1.01 125.0155 C7H6Cl+ 2 125.0153 1.8 125.0598 C7H9O2+ 3 125.0597 0.5 126.0107 C6H5ClN+ 3 126.0105 1.27 128.0024 C6H5ClO+ 2 128.0023 0.76 129.01 CH5ClFN3O+ 3 129.01 0.17 129.0448 C8H5N2+ 1 129.0447 0.44 130.029 C8H4NO+ 3 130.0287 1.87 130.04 C7H4N3+ 2 130.04 0.09 130.0524 C8H6N2+ 1 130.0525 -1.45 131.0605 C8H7N2+ 1 131.0604 0.76 132.0244 C8H3FN+ 1 132.0244 0.18 132.0291 C4H6NO4+ 2 132.0291 -0.17 132.0444 C8H6NO+ 3 132.0444 0.32 132.0556 C7H6N3+ 2 132.0556 -0.51 133.0324 C8H4FN+ 1 133.0322 1.54 133.0397 C7H5N2O+ 2 133.0396 0.32 133.0521 C8H7NO+ 3 133.0522 -0.62 134.0239 C7H4NO2+ 3 134.0237 1.72 134.0401 C8H5FN+ 1 134.0401 0.5 134.0474 C7H6N2O+ 2 134.0475 -0.14 134.0601 C8H8NO+ 3 134.06 0.64 136.0395 C7H6NO2+ 3 136.0393 1.3 138.0105 C7H5ClN+ 4 138.0105 0.14 138.9945 C7H4ClO+ 2 138.9945 0.15 139.0057 C6H4ClN2+ 4 139.0058 -0.09 140.9902 C7H3ClF+ 1 140.9902 0.36 141.0102 C7H6ClO+ 2 141.0102 0.17 142.0402 CH12ClFO4+ 2 142.0403 -0.81 143.0059 C7H5ClF+ 1 143.0058 0.78 143.0607 C9H7N2+ 1 143.0604 2.01 144.0318 C8H4N2O+ 2 144.0318 -0.01 144.0557 C8H6N3+ 2 144.0556 0.27 145.0397 C8H5N2O+ 2 145.0396 0.26 146.0239 C5H7ClN2O+ 3 146.0241 -1.63 147.0354 C8H4FN2+ 1 147.0353 0.43 147.0553 C8H7N2O+ 2 147.0553 0.03 149.0512 C8H6FN2+ 1 149.051 1.84 150.035 C8H5FNO+ 2 150.035 0.48 151.0057 C7H4ClN2+ 4 151.0058 -0.05 154.0401 C9H4N3+ 2 154.04 0.7 154.9896 C7H4ClO2+ 2 154.9894 0.92 156.0012 C7H4ClFN+ 2 156.0011 0.69 157.0398 C9H5N2O+ 2 157.0396 0.99 158.0171 C7H6ClFN+ 1 158.0167 2.37 159.0355 C9H4FN2+ 1 159.0353 1.01 160.0269 C8H4N2O2+ 2 160.0267 0.9 160.0432 C9H5FN2+ 1 160.0431 0.64 160.0505 C8H6N3O+ 3 160.0505 -0.28 161.0277 C6H7ClFN2+ 2 161.0276 0.61 161.0345 C8H5N2O2+ 2 161.0346 -0.41 162.035 C9H5FNO+ 2 162.035 0.24 162.0425 C8H6N2O2+ 2 162.0424 0.93 162.0551 C9H8NO2+ 3 162.055 0.92 162.9947 C9H4ClO+ 2 162.9945 0.89 163.0058 C8H4ClN2+ 4 163.0058 0.41 163.0501 C8H7N2O2+ 2 163.0502 -0.36 164.0342 C8H6NO3+ 3 164.0342 -0.02 165.0461 C8H6FN2O+ 3 165.0459 1.34 166.0056 C8H5ClNO+ 4 166.0054 0.96 167.0374 C8H6FNO2+ 3 167.0377 -1.61 168.0012 C8H4ClFN+ 2 168.0011 0.98 168.0456 C8H7FNO2+ 3 168.0455 0.6 170.035 C9H4N3O+ 3 170.0349 0.39 173.0345 C9H5N2O2+ 2 173.0346 -0.4 174.0463 C14H6+ 2 174.0464 -0.52 175.0304 C9H4FN2O+ 3 175.0302 0.94 176.0382 C9H5FN2O+ 3 176.038 0.7 177.0227 C6H7ClFN2O+ 2 177.0225 0.84 177.046 C9H6FN2O+ 3 177.0459 0.97 178.03 C9H5FNO2+ 3 178.0299 0.42 179.0008 C8H4ClN2O+ 4 179.0007 0.48 180.0454 C9H7FNO2+ 3 180.0455 -0.73 182.0352 C3H12ClFO5+ 4 182.0352 -0.01 182.0608 C9H11ClN2+ 4 182.0605 1.49 183.0121 C8H5ClFN2+ 2 183.012 0.78 183.9962 C8H4ClFNO+ 2 183.996 1.25 184.0504 C10H6N3O+ 4 184.0505 -0.53 185.0343 C10H5N2O2+ 3 185.0346 -1.47 186.0298 C9H4N3O2+ 3 186.0298 0.21 186.0464 C15H6+ 2 186.0464 0.23 187.0305 C7H7ClFN3+ 3 187.0307 -1.18 187.0547 C15H7+ 3 187.0542 2.45 188.0381 C10H5FN2O+ 3 188.038 0.54 189.0456 C10H6FN2O+ 3 189.0459 -1.38 190.0412 C9H5FN3O+ 5 190.0411 0.27 190.05 C10H8NO3+ 3 190.0499 0.78 191.0253 C9H4FN2O2+ 4 191.0251 0.96 195.0122 C9H5ClFN2+ 2 195.012 0.88 195.0568 C6H11ClFN3O+ 3 195.0569 -0.77 196.0502 C11H6N3O+ 5 196.0505 -1.84 198.0303 C7H7ClN4O+ 4 198.0303 -0.18 200.0272 C9H8ClFNO+ 2 200.0273 -0.68 200.0381 C11H5FN2O+ 3 200.038 0.36 201.0328 C6H11ClFO4+ 4 201.0324 1.59 202.0417 C12H9ClN+ 5 202.0418 -0.42 202.0525 C14H6N2+ 2 202.0525 -0.44 203.0254 C7H7ClFN3O+ 4 203.0256 -1.11 204.0331 C10H5FN2O2+ 4 204.033 0.56 204.0567 C10H7FN3O+ 5 204.0568 -0.29 204.0768 C10H10N3O2+ 3 204.0768 0.4 205.0409 C10H6FN2O2+ 4 205.0408 0.51 205.0609 C10H9N2O3+ 3 205.0608 0.59 207.1256 C12H17NO2+ 2 207.1254 1.02 211.0069 C9H5ClFN2O+ 2 211.0069 0.25 211.9908 C9H4ClFNO2+ 3 211.9909 -0.42 213.0334 C16H5O+ 5 213.0335 -0.37 214.0068 C9H6ClFNO2+ 2 214.0066 0.92 214.0407 C7H12ClFO4+ 5 214.0403 1.92 214.0612 C11H8N3O2+ 4 214.0611 0.53 215.0494 C8H9ClFN4+ 5 215.0494 -0.24 216.0569 C16H8O+ 5 216.057 -0.15 217.0406 C11H6FN2O2+ 5 217.0408 -0.8 218.0362 C15H6O2+ 6 218.0362 -0.06 220.0279 C10H5FN2O3+ 4 220.0279 0.16 220.0521 C7H10ClFN4O+ 6 220.0522 -0.21 221.0357 C10H6FN2O3+ 4 221.0357 0.18 221.0461 C5H13ClFNO5+ 4 221.0461 -0.06 221.9995 C10H4ClFN2O+ 2 221.9991 1.73 223.0071 C10H5ClFN2O+ 2 223.0069 0.99 223.0667 C14H8FN2+ 1 223.0666 0.58 223.9911 C10H4ClFNO2+ 2 223.9909 0.63 225.0585 C14H8FNO+ 2 225.0584 0.45 228.0442 C11H5FN4O+ 4 228.0442 0.08 228.0556 C15H6N3+ 4 228.0556 -0.07 229.028 C11H4FN3O2+ 7 229.0282 -0.87 229.0522 C16H7NO+ 4 229.0522 -0.1 230.0362 C16H6O2+ 6 230.0362 -0.32 231.0202 C11H4FN2O3+ 4 231.02 0.6 232.0524 C13H11ClNO+ 6 232.0524 0 232.0625 C6H14ClFN2O4+ 4 232.0621 1.95 239.0369 C14H8ClN2+ 4 239.0371 -0.69 240.0437 C8H12ClFNO4+ 6 240.0433 1.42 241.0182 C10H7ClFN2O2+ 1 241.0175 3.08 241.0522 C17H7NO+ 5 241.0522 0.05 242.06 C17H8NO+ 5 242.06 -0.17 243.0442 C17H7O2+ 7 243.0441 0.5 244.0516 C12H7FN3O2+ 7 244.0517 -0.41 245.0224 C11H6ClN4O+ 5 245.0225 -0.16 245.0597 C17H9O2+ 7 245.0597 -0.14 246.031 C11H5FN3O3+ 5 246.0309 0.36 247.0515 C12H8FN2O3+ 4 247.0513 0.8 248.0617 C15H7FN3+ 3 248.0619 -0.51 250.0184 C16H7ClO+ 4 250.018 1.67 251.0614 C15H8FN2O+ 4 251.0615 -0.59 252.0689 C15H9FN2O+ 4 252.0693 -1.66 255.0317 C14H8ClN2O+ 4 255.032 -0.86 256.0391 C12H5FN4O2+ 5 256.0391 0 257.0469 C12H6FN4O2+ 5 257.0469 -0.16 260.0584 C13H11ClN3O+ 4 260.0585 -0.32 261.068 C15H14ClO2+ 4 261.0677 1.17 262.0542 C13H10ClFN3+ 3 262.0542 0.07 264.0323 C15H7ClN3+ 4 264.0323 -0.15 266.013 C16H7ClO2+ 4 266.0129 0.5 267.0323 C15H8ClN2O+ 5 267.032 1.13 271.0627 C18H9NO2+ 6 271.0628 -0.27 272.0346 C14H9ClN2O2+ 5 272.0347 -0.38 274.0624 C18H10O3+ 7 274.0624 -0.13 277.0647 C21H9O+ 7 277.0648 -0.19 278.0717 C12H16ClFO4+ 6 278.0716 0.48 279.0198 C15H4FN2O3+ 5 279.02 -0.81 279.0571 C18H12ClO+ 5 279.0571 -0.24 280.0646 C13H12ClFN3O+ 4 280.0647 -0.65 281.0672 C14H9N4O3+ 3 281.0669 0.87 286.0613 C17H8N3O2+ 6 286.0611 0.63 290.0578 C15H13ClNO3+ 8 290.0578 -0.01 294.0669 C16H11ClN4+ 7 294.0667 0.61 299.0571 C14H8FN4O3+ 4 299.0575 -1.21 300.0656 C19H10NO3+ 5 300.0655 0.43 301.0724 C17H9N4O2+ 6 301.072 1.3 304.0521 C14H10ClFN4O+ 7 304.0522 -0.31 304.0754 C17H9FN4O+ 6 304.0755 -0.23 306.0674 C17H9FN3O2+ 7 306.0673 0.32 308.0231 C13H8ClFN3O3+ 6 308.0233 -0.59 312.0341 C21H9ClO+ 4 312.0336 1.61 313.0416 C21H10ClO+ 5 313.0415 0.5 313.0722 C18H9N4O2+ 5 313.072 0.55 315.0332 C16H9ClFN2O2+ 3 315.0331 0.4 318.0673 C18H9FN3O2+ 7 318.0673 -0.1 320.0225 C17H5FN2O4+ 5 320.0228 -0.79 321.0549 C14H11ClFN4O2+ 6 321.0549 0.02 321.0778 C13H17ClFNO5+ 5 321.0774 1.22 327.0453 C21H8FO3+ 5 327.0452 0.35 331.0628 C18H8FN4O2+ 6 331.0626 0.59 339.0442 C17H9ClFN4O+ 5 339.0443 -0.49 340.0288 C17H8ClFN3O2+ 4 340.0284 1.29 340.0492 C17H9FN2O5+ 6 340.049 0.53 341.0376 C19H11ClFO3+ 2 341.0375 0.27 342.0441 C17H10ClFN3O2+ 4 342.044 0.15 343.04 C21H8FO4+ 5 343.0401 -0.33 347.0327 C21H5N3O3+ 5 347.0325 0.41 349.0491 C18H8FN3O4+ 6 349.0493 -0.74 355.0393 C17H9ClFN4O2+ 4 355.0393 0 358.039 C17H10ClFN3O3+ 4 358.0389 0.27 367.0397 C18H9ClFN4O2+ 4 367.0393 1.3 368.0244 C20H10ClFO4+ 4 368.0246 -0.71 369.0555 C18H11ClFN4O2+ 4 369.0549 1.64 383.0344 C18H9ClFN4O3+ 4 383.0342 0.71 385.0505 C20H13ClFNO4+ 4 385.0512 -1.73 391.0835 C20H12FN4O4+ 1 391.0837 -0.47 397.0507 C21H13ClFNO4+ 2 397.0512 -1.26 427.0608 C20H13ClFN4O4+ 1 427.0604 0.9 428.066 C21H9FN6O4+ 3 428.0664 -0.99 459.0869 C21H17ClFN4O5+ 1 459.0866 0.65 PK$NUM_PEAK: 256 PK$PEAK: m/z int. rel.int. 63.0231 136105.9 2 65.0387 1520976.8 33 69.9925 298883.2 6 73.0196 114807.4 2 73.0285 273522.2 5 75.0229 383002.1 8 77.0386 408667.5 8 78.0338 630851.6 13 79.0418 125551.1 2 79.0542 90031.5 1 80.0495 117443.2 2 81.0336 128286 2 86.0238 308207.1 6 86.9877 107371.4 2 86.9997 328958.1 7 90.0338 2856325 62 91.019 69339 1 91.0418 71459 1 91.0542 532790.6 11 92.0256 118945.2 2 92.0496 336645.6 7 93.0335 1068290.5 23 94.0413 95686 2 95.0492 846308.3 18 96.0443 88058.1 1 97.0035 77437.8 1 98.9996 458609.9 10 102.0337 403592.1 8 104.0141 62331.1 1 104.0495 1124428.4 24 105.0336 345903 7 105.0448 511906.7 11 106.0288 1128166.6 24 106.0526 103475.1 2 106.0653 63836.8 1 107.0292 89095.2 1 107.0494 104865.6 2 108.0445 224368.9 4 110.9998 316676.1 6 111.0441 794322.6 17 112.0076 131815 2 113.0398 73906.7 1 115.0419 75422.9 1 116.037 95305.5 2 117.0448 128717.1 2 117.0575 255868.9 5 118.0289 102626 2 118.0525 84306.5 1 119.0366 661096.3 14 120.0444 4254808.5 93 121.0396 115393.6 2 122.0401 842558.2 18 123.0354 133948.7 2 125.0155 68158.5 1 125.0598 130769.4 2 126.0107 97590.5 2 128.0024 376205.4 8 129.01 1774872.9 38 129.0448 1550190.2 33 130.029 1423588.4 31 130.04 2062753.2 45 130.0524 112031 2 131.0605 122579.1 2 132.0244 78365.5 1 132.0291 69839.1 1 132.0444 832510.4 18 132.0556 224542 4 133.0324 269955.7 5 133.0397 311892.7 6 133.0521 68218.5 1 134.0239 97477.1 2 134.0401 337860.4 7 134.0474 97386.4 2 134.0601 358892.1 7 136.0395 337442.6 7 138.0105 9299776 203 138.9945 662405.1 14 139.0057 2784218 60 140.9902 102272.8 2 141.0102 91458.4 2 142.0402 264675 5 143.0059 124013.8 2 143.0607 74041.1 1 144.0318 575692.8 12 144.0557 440050.5 9 145.0397 4906326 107 146.0239 360818.6 7 147.0354 210984.6 4 147.0553 214044.9 4 149.0512 75706.4 1 150.035 4427957 96 151.0057 400468.5 8 154.0401 546512.9 11 154.9896 260796.5 5 156.0012 108462.4 2 157.0398 268241.8 5 158.0171 83874.4 1 159.0355 337106.3 7 160.0269 411067.1 8 160.0432 400564.7 8 160.0505 289608.2 6 161.0277 150029.8 3 161.0345 1225984.9 26 162.035 483897.7 10 162.0425 637277.8 13 162.0551 345307.5 7 162.9947 56328.9 1 163.0058 704758.4 15 163.0501 652861.9 14 164.0342 3366507 73 165.0461 101541.1 2 166.0056 333224.4 7 167.0374 70911.1 1 168.0012 1380878 30 168.0456 75662.8 1 170.035 999121.3 21 173.0345 69702.4 1 174.0463 244602 5 175.0304 1489433.9 32 176.0382 1217537.8 26 177.0227 71095.5 1 177.046 128047.5 2 178.03 3316814 72 179.0008 1967780.5 43 180.0454 79993.9 1 182.0352 60076.3 1 182.0608 82371.4 1 183.0121 303918.1 6 183.9962 1027074.7 22 184.0504 78102.3 1 185.0343 60651 1 186.0298 82836.4 1 186.0464 225504.1 4 187.0305 230107.6 5 187.0547 64251.1 1 188.0381 26280322 574 189.0456 374790.6 8 190.0412 434842.2 9 190.05 592526.8 12 191.0253 596925.3 13 195.0122 77688.8 1 195.0568 72152.9 1 196.0502 75305.9 1 198.0303 103340.8 2 200.0272 58346 1 200.0381 64308.4 1 201.0328 68360.1 1 202.0417 408031.3 8 202.0525 58344 1 203.0254 268432.5 5 204.0331 95671.2 2 204.0567 103971.9 2 204.0768 465381.3 10 205.0409 1775172 38 205.0609 960834.4 21 207.1256 54365.4 1 211.0069 88411.2 1 211.9908 431921 9 213.0334 108364 2 214.0068 957181.4 20 214.0407 374376.5 8 214.0612 402423.6 8 215.0494 227424.8 4 216.0569 239411.3 5 217.0406 71176.6 1 218.0362 581754.6 12 220.0279 328325.9 7 220.0521 91235.7 1 221.0357 255406.9 5 221.0461 59140.4 1 221.9995 54356.2 1 223.0071 435779 9 223.0667 87116.4 1 223.9911 381856.1 8 225.0585 219261.5 4 228.0442 359735.5 7 228.0556 70874.8 1 229.028 398693.3 8 229.0522 229977.7 5 230.0362 2797618.2 61 231.0202 1188163.1 25 232.0524 379308 8 232.0625 87748.2 1 239.0369 94318.3 2 240.0437 280691 6 241.0182 104844.9 2 241.0522 453660.8 9 242.06 500345.3 10 243.0442 207238.8 4 244.0516 450736.5 9 245.0224 66332.1 1 245.0597 64098.2 1 246.031 2398507.5 52 247.0515 79503.3 1 248.0617 65902.2 1 250.0184 101052 2 251.0614 351420.8 7 252.0689 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